Aethalometer measurements in a road tunnel: A step forward in the characterization of black carbon emissions from traffic.

A sampling campaign was conducted in the Liberdade Avenue tunnel (Braga, Portugal) during a week (with 56,000 vehicles) to monitor black carbon (eBC-equivalent black carbon) by means of an Aethalometer AE-31, and gaseous pollutants (CO2, CO, NOx). Inside the tunnel, the mean eBC mass concentration was 21 ±â€¯10 µg m-3, reaching a maximum hourly value of 49.0 µg m-3. An hourly and weekday-weekend study was carried out. Regarding the Absorption Ångström exponent (AAE), a mean value of 0.97 ±â€¯0.10 was obtained, for a source of practically pure traffic. There was a positive significant correlation between eBC and the number of light vehicles (r = 0.47; p < 0.001) and between eBC and the gaseous emissions: CO (r = 0.67; p < 0.001), CO2 (r = 0.71; p < 0.001), NO (r = 0.63; p < 0.001) and NO2 (r = 0.70; p < 0.001). The mean black carbon emission factors (EFBC) inside the tunnel were 0.31 ±â€¯0.08 g (kg fuel)-1 and 0.11 ±â€¯0.08 mg veh-1 km-1, similar to those found in other studies for gasoline and diesel vehicles in road tunnels.

Unusual winter Saharan dust intrusions at Northwest Spain: Air quality, radiative and health impacts.

Saharan air masses can transport high amounts of mineral dust particles and biological material to the Iberian Peninsula. During winter, this kind of events is not very frequent and usually does not reach the northwest of the Peninsula. However, between 21 and 22 February 2016 and between 22 and 23 February 2017, two exceptional events were registered in León (Spain), which severely affected air quality. An integrative approach including: i) typical synoptic conditions; ii) aerosol chemical composition; iii) particle size distributions; iv) pollen concentration; v) aerosol optical depth (AOD); vi) radiative forcing and vii) estimation of the impact of aerosols in the respiratory tract, was carried out. In the global characterization of these events, the exceedance of the PM10 daily limit value, an increase in the coarse mode and a rise in the iron concentration were observed. On the 2016 event, an AOD and extinction-related Ångström exponent clearly characteristic of desert aerosol (1.1 and 0.05, respectively) were registered. Furthermore, pollen grains not typical of flowering plants in this period were identified. The chemical analysis of the aerosol from the 2017 event allowed us to confirm the presence of the main elements associated with mineral sources (aluminum, calcium, and silica concentrations). An increase in the SO42-, NO3- and Cl- concentrations during the Saharan dust intrusion was also noted. However, in this event, there was no presence of atypical pollen types. The estimated dust radiative forcing traduced a cooling effect for surface and atmosphere during both events, corroborated by trends of radiative flux measurements. The estimated impact on the respiratory tract regions of the high levels of particulate matter during both Saharan dust intrusions showed high levels for the respirable fraction.

Urban vegetation and particle air pollution: Experimental campaigns in a traffic hotspot.

This work presents the main results of two experimental campaigns carried out in summer and winter seasons in a complex pollution hotspot near a large park, El Retiro, in Madrid (Spain). These campaigns were aimed at understanding the microscale spatio-temporal variation of ambient concentration levels in areas with high pollution values to obtain data to validate models on the effect of urban trees on particulate matter concentrations. Two different measuring approaches have been used. The first one was static, with instruments continuously characterizing the meteorological variables and the particulate matter concentration outside and inside the park. During the summer campaign, the particulate matter concentration was clearly influenced by a Saharan dust outbreak during the period 23 June to 10 July 2016, when most of the particulate matter was in the fraction PM2.5-10. During the winter campaign, the mass concentrations were related to the meteorological conditions and the high atmospheric stability. The second approach was a dynamic case with mobile measurements by portable instruments. During the summer campaign, a DustTrak instrument was used to measure PM10 and PM2.5 in different transects close to and inside the park at different distances from the traffic lane. It was observed a decrease in the concentrations up to 25% at 20 m and 50% at 200 m. High PM10 values were linked to dust resuspension caused by recreational activities and to a Saharan dust outbreak. The highest PM values were measured at the Independencia square, an area with many bus stops and high traffic density. During the winter campaign, three microaethalometers were used for Black Carbon measurement. Both pollutants also showed a reduction in their concentrations when moving towards inside the park. For PM10 and PM2.5, reductions up to 50% were observed, while for BC this reduction was smaller, about 20%.

Quantification of source specific black carbon scavenging using an aethalometer and a disdrometer.

Aerosol black carbon (BC) is the second strongest contributor to global warming, after CO2, and it is linked to many adverse health effects. A sampling campaign of 15 months was carried out in León (Spain) in order to evaluate the scavenging of BC with an ensemble aethalometer-disdrometer. The aethalometer provides the concentration of equivalent black carbon (eBC), and the disdrometer, the raindrop size distribution. A total of seventy-five rain events were studied and in 73% of them there was an effective (eBCinitial > eBCfinal) scavenging, with a mean decrease of 48 ±â€¯37% in long rain events (>8 h) and 39 ±â€¯38% in short rain events. The scavenging of BC is strongly related to its source. Thus, the scavenging coefficient (SC) mean value of the BC from fossil fuel (eBCff) for short and long rain events was 5.1 10-5 and 1.3 10-5 s-1, respectively. For the BC from biomass burning (eBCbb), the SC values were 1.6 10-4 and 2.8 10-5 s-1 in short and long events, respectively. There was a significant positive correlation between the SC and the number of drops with diameters between 0.375 and 2.5 mm. Rain scavenging of eBC was analyzed depending on the air mass origin obtaining an effective scavenging for air masses from Atlantic, Arctic and Africa. A linear model (R2 = 0.72) was built to estimate the ΔeBC values with variables from an aethalometer, a disdrometer and a weather station: eBC concentration before rain, swept volume and precipitation accumulated. A Kolmogorov-Smirnov statistical test confirmed the goodness of fit of the model to the measured data.

Impact of the wood combustion in an open fireplace on the air quality of a living room: Estimation of the respirable fraction.

Presently, both in rural areas and in cities open fireplaces are still present and large quantities of wood are combusted every year. The present study aims to characterize aerosol size distribution, chemical composition and deposition in the human respiratory tract of particles emitted during the combustion of logs of oak in an open fireplace installed in the living room of a typical village house. CO2 and CO levels and aerosol size distribution have been continuously monitored and a PM10 sampler with two types of filters for chemical and microscopic analysis was also installed. The increment, between the operating periods and the indoor background, in the organic carbon and PM10 concentration due to the use of the fireplace is 15.7±0.6 (mean±standard deviation) and 58.5±6.2µgm-3, respectively. The two main polluting processes during the operation of the fireplace are the ignition with the subsequent refueling and the final cleaning of the residual ashes. In both phases mean values around 1800 particles cm-3 with CMD of 0.15µm were measured. However, while PM10 levels of 130±120µgm-3 were estimated for the ignition stage, values of 200±200µgm-3 were obtained during the final cleaning step. Assessment conducted according to ISO standard 7708:1995, demonstrated that a person who stays in a living room when an open fireplace is lit will inhale, on average, 217µgm-3 and 283µgm-3 during the ignition and the refueling stages, respectively. Subsequent refueling proved to be much less polluting. The ashes removal can also be very polluting and dangerous to health if there are hidden small incandescent embers among the ashes (estimated PM10 of 132µgm-3), reaching a CO2 level of 1940ppm and a dangerous level of CO of 132ppm.

Outdoor and indoor particle characterization from a large and uncontrolled combustion of a tire landfill.

A large and uncontrolled fire of a tire landfill started in Seseña (Toledo, Spain) on May 13, 2016. An experimental deployment was immediately launched in the area for measuring regulated and non-standard air quality parameters to assess the potential impact of the plume at local and regional levels. Outdoor and indoor measurements of different parameters were carried out at a near school, approximately 700m downwind the burning tires. Real time measurements of ambient black carbon (BC) and total number particle concentrations were identified as good tracers of the smoke plume. Simultaneous peaks allowed us to characterize situations of the plume impact on the site. Outdoor total particle number concentrations reached in these occasions 3.8×105particlescm-3 (on a 10min resolution) whereas the indoor concentration was one order of magnitude lower. BC mass concentrations in ambient air were in the range of 2 to 7µgm-3, whereas concentrations<2µgm-3 were measured indoor. Indoor and outdoor deposited inhalable dust was sampled and chemically characterized. Both indoor and outdoor dust was enriched in tire components (Zn, sulfate) and PAHs associated to the tire combustion process. Infiltration processes have been documented for BC and particle number concentrations causing increases in indoor concentrations.