Modifying the Silver-Titania Nanocomposites with Carbonaceous Materials to Remove the Pollutants from Domestic Waste Water.

The aim of this study was to prepare and characterize nanostructured composites based of TiO2, carbonaceus materials (GN or GO) and Ag and the test their capacity to remove the pollutants from domestic wastewater. The composites were characterized by IR and UV-Vis spectroscopy, X-ray diffraction, electron microscopy and nitrogen adsorption-desorption measurements. The photocatalytic activity was measured from the experiment of salicylic acid (SA) degradation. The capacity to remove the pollutants from domestic wastewater was performed by considering the absorbance of residual solution at 200 nm. The non-calcined composites have high specific surface area (˜300 m²/g), but nitrogen adsorption-desorption isotherms showed a porous structure with closed pores. The porosity of the thermal treated composites is about 10 times less, but the pores are open. The salicylic acid was 94% degraded over all composites, showing their efficient photoactivity. A percent of 70% of pollutants were removed over the calcined composites with GN and ˜67% on those with GO. It was no statistically significant difference between the photocatalytical efficiency of GN- and GO-based composites. Even if the calcined composites have the specific surface area about 10 times lower, their lower gap energy, higher degree of crystallinity and photocatalytic activity make them efficient candidates for removal of pollutants from domestic waste water. The photodegradation mechanism occurred mostly by π-π interactions between GN/GO and pollutant molecules.