Combustion and toxic gas production from disposable barbecues in enclosures.

The production of carbon monoxide from disposable barbecues in an enclosed room has been investigated. Hazard calculations have shown that lethal concentrations of CO and CO2 can be produced easily. Burning rates and the relative formation of CO and CO2 depend on the ambient oxygen concentration. Smoke does not correlate with CO concentration as it is mostly produced by the combustion of volatile hydrocarbons added to facilitate ignition. In a typical room, this results in smoke clearing before the maximum CO concentration is reached. Smoke obscuration is therefore a poor indicator of the danger posed by CO. This is an important observation for those discovering or attempting to resuscitate or rescue comatose victims. Dilution caused by ventilation is described numerically and has allowed total volumes of CO and CO2 produced to be estimated.

Experimental results of a residential house fire test on tenability: temperature, smoke, and gas analyses.

A fire experiment conducted in a British 1950s-style house is described. Measurements of temperature, smoke, CO, CO2 , and O2 were taken in the Lounge, stairwell, and front and back bedrooms. The front bedroom door was wedged open, while the door to the back bedroom was wedged closed. Contrary to expectations and despite the relatively small fire load, analysis and hazard calculations show permeation of toxic fire gases throughout the property with lethal concentrations of effluent being measured at each sampling point. A generally poor state of repair and missing carpets in the upper story contributed to a high degree of gas and smoke permeation. The available egress time was calculated as the time before the main escape route became impassable. Given known human responses to fire, such an incident could have caused fatalities to sleeping or otherwise immobile occupants.