ABSTRACT
A composite material, referred to as micropolymer inclusion beads (µPIBs), was fabricated for the first time using a microfluidic technique and applied successfully for the recovery of Au(III) from simulated digests of electronic scrap. Best results for the extraction of Au(III) were achieved with µPIBs consisting of 55% (m/m) poly(vinyl chloride) as the base polymer, 35% (m/m) Aliquat 336 as the extractant, and 10% (m/m) 1-tetradecanol as a modifier. The size and surface morphology of the µPIBs were examined using optical microscopy and scanning electron microscopy, respectively. A batch of 200 mg µPIBs allowed the complete and selective extraction of Au(III) (2.85 mg) from 50 mL of a simulated digest of electronic scrap containing other metal ions, including 1365 mg Cu(II). The extracted Au(III) was quantitatively stripped from the µPIBs into 50 mL of 0.1 mol L-1 solution of thiourea. No Cu(II) and only sub-microgram levels of Cd(II) and Zn(II) were detected in this solution, thus confirming the suitability of the µPIBs for the efficient recovery of Au(III) from digests of electronic scrap. The microfluidic method used in this study is expected to be applicable for the fabrication of µPIBs for the selective separation of other chemical species by varying the composition of the beads.
ABSTRACT
A bi-parametric sequential injection method for the determination of copper(II) and zinc(II) when present together in aqueous samples was developed. This was achieved by using a non-specific colorimetric reagent (4-(2-pyridylazo)resorcinol, PAR) together with two ion-exchange polymeric materials to discriminate between the two metal ions. A polymer inclusion membrane (PIM) and a chelating resin (Chelex 100) were the chosen materials to retain zinc(II) and copper(II), respectively. The influence of the flow system parameters, such as composition of the reagent solutions, flow rates and standard/sample volume, on the method sensitivity were studied. The interference of several common metal ions was assessed, and no significant interferences were observed (<10% signal deviation). The limits of detection were 3.1 and 5.6 µg L-1 for copper(II) and zinc(II), respectively; the dynamic working range was from 10 to 40 µg L-1 for both analytes. The newly developed sequential injection analysis (SIA) system was applied to natural waters and soil leachates, and the results were in agreement with those obtained with the reference procedure.
