Effects of remediation agents on rice and soil in toxic metal(loid)s contaminated paddy fields: A global meta-analysis.

Toxic metal(loid)s contamination of paddy soil is a nonnegligible issue and threatens food safety considering that it is transmitted via the soil-plant system. Applying remediation agents could effectively inhibit the soil available toxic metal(loid)s and reduce their accumulation in rice. To comprehensively quantify how remediation agents impact the accumulation of Cd/Pb/As in rice, rice growth and yield, the accumulation of available Cd/Pb/As in paddy soil, and soil characteristics, 50 peer-reviewed publications were selected for meta-analysis. Overall, the application of remediation agents exhibited significant positive effects on rice plant length (ES = 0.05, CI = 0.01-0.08), yield (ES = 0.20, CI = 0.13-0.27), peroxidase (ES = 0.56, CI = 0.18-0.31), photosynthetic rate (ES = 0.47, CI = 0.34-0.61), and respiration rate (ES = 0.68, CI = 0.47-0.88). Among the different types of remediation agents, biochar was the most effective in controlling the accumulation of Cd/Pb/As in all portions of rice, and was also superior in inhibiting the accumulation of Pb in rice grains (ES = -0.59, 95 % CI = -1.04-0.13). This study offers an essential contribution for the remediation strategies of toxic metal(loid)s contaminated paddy fields.

The effects of iron-based nanomaterials (Fe NMs) on plants under stressful environments: Machine learning-assisted meta-analysis.

Mitigating the adverse effects of stressful environments on crops and promoting plant recovery in contaminated sites are critical to agricultural development and environmental remediation. Iron-based nanomaterials (Fe NMs) can be used as environmentally friendly nano-fertilizer and as a means of ecological remediation. A meta-analysis was conducted on 58 independent studies from around the world to evaluate the effects of Fe NMs on plant development and antioxidant defense systems in stressful environments. The application of Fe NMs significantly enhanced plant biomass (mean = 25%, CI = 20%-30%), while promoting antioxidant enzyme activity (mean = 14%, CI = 10%-18%) and increasing antioxidant metabolite content (mean = 10%, CI = 6%-14%), reducing plant oxidative stress (mean = -15%, CI = -20%∼-10%), and alleviating the toxic effects of stressful environments. The observed response was dependent on a number of factors, which were ranked in terms of a Random Forest Importance Analysis. Plant species was the most significant factor, followed by Fe NM particle size, duration of application, dose level, and Fe NM type. The meta-analysis has demonstrated the potential of Fe NMs in achieving sustainable agriculture and the future development of phytoremediation.

Enhanced fertilizer utilization and heavy metals immobilization by ball-milling bentonite with NH4Cl: Experiments and DFT calculations.

Over-application of nitrogen fertilizer induces soil acidification, which activates heavy metals availability and poses significant challenge to crop production and food safety. In this study, we prepared a clay-based material by ball-milling bentonite with NH4Cl (NH4Cl@bentonite) and assessed its synergistic performance in enhancing nitrogen fertilizer utilization efficiency, immobilizing heavy metals, and improving crop yield and safety. The results showed that the optimal performance of NH4Cl@bentonite was achieved by milling bentonite with NH4Cl at a 4:1 mass ratio for 9 h. NH4Cl@bentonite significantly improved soil water holding and retention capacity by 1.6 and 4.3 times, respectively. In comparison to NH4Cl alone, NH4Cl@bentonite led to a 22.3% increase in N-use efficiency and a 1.5 times enhancement in crop yield. The Pb and Cd content in water spinach shoots decreased by 55.3% and 57.5%, respectively, attributed to the transformation of heavy metals into lower bioavailability states by NH4Cl@bentonite. Experiments and Density Functional Theory (DFT) calculations indicated that NH4Cl@bentonite could immobilize Pb and Cd through processes such as cation exchange, surface adsorption, complexation, and enhancement of soil pH. This work proposes a simple and efficient method for improving cropland fertilizer utilization while ensuring healthy and sustainable development. ENVIRONMENTAL IMPLICATION: Soil acidification, caused using chemical fertilizers, especially nitrogen-based ones, threatens crop production and food safety by damaging soil structure, speeding up nutrient loss, and increasing the solubility of heavy metals. To tackle this problem, we made a clay material by mixing bentonite with NH4Cl (NH4Cl@bentonite) in a ball mill. NH4Cl@bentonite increased N-use efficiency by 22.3%, boosted crop yield by 1.5 times, and reduced the Pb and Cd levels in water spinach shoots by 55.3% and 57.5%, respectively. This work suggests a simple and effective way to enhance fertilizer use in croplands while ensuring healthy and sustainable development.

Internal Electric Field-Modulated Charge Migration Behavior in MoS2 /MIL-53(Fe) S-Scheme Heterojunction for Boosting Visible-Light-Driven Photocatalytic Chlorinated Antibiotics Degradation.

Inadequate photo-generated charge separation, migration, and utilization efficiency limit the photocatalytic efficiency. Herein, a MoS2 /MIL-53(Fe) photocatalyst/activator with the S-scheme heterojunction structure is designed and the charge migration behavior is modulated by the internal electric field (IEF). The IEF intensity is enhanced to 40 mV by modulating band bending potential and the depletion layer length of MoS2 . The photo-generated electron migration process is boosted by constructing the electron migration bridge (Fe-O-S) and modulating the IEF as the driving force, confirmed by the density functional theory calculation. Compared with the pristine materials, the photocurrent density of MoS2 /MIL-53(Fe) is significantly enhanced 27.5 times. Contributed by the visible-light-driven cooperative catalytic degradation and the high-efficiency direct photo-generated electron reduction dichlorination process, satisfactory chlorinated antibiotics removal and detoxification performances are achieved. This study opens up new insights into the application of heterojunctions in photocatalytic activation of PDS in environmental remediation.

Effects of the application of nanoscale zero-valent iron on plants: Meta analysis, mechanism, and prospects.

In order to determine the ideal conditions for the application of nanoscale zero-valent iron (nZVI) in agricultural production, this review studies the effects of nZVI application on plant physiological parameters, presents its mechanism and prospective outcomes. In this research, it was observed that the application of nZVI had both favorable and unfavorable effects on plant growth, photosynthesis, oxidative stress, and nutrient absorption levels. Specifically, the application of nZVI significantly increased the biomass and length of plants, and greatly reduced the germination rate of seeds. In terms of photosynthesis, there was no significant effect for the application of nZVI on the synthesis of photosynthetic pigments (chlorophyll and carotenoids). In terms of oxidative stress, plants respond by increasing the activity of antioxidant enzyme under mild nZVI stress and trigger oxidative burst under severe stress. In addition, the application of nZVI significantly increased the absorption of nutrients (B, K, P, S, Mg, Zn, and Fe). In summary, the application of nZVI can affect the plant physiological parameters, and the degree of influence varies depending on the concentration, preparation method, application method, particle size, and action time of nZVI. These findings are important for evaluating nZVI-related risks and enhancing nZVI safety in agricultural production.

The association between fear of future workplace violence and depressive symptoms among nurses based on different experiences of workplace violence: a cross-sectional study.

BACKGROUND: Fear of future workplace violence (FFWV) has a negative impact on individuals' health. However, no study has investigated the association between FFWV and depressive symptoms. Nurses with different experiences of workplace violence may have different levels of FFWV and differences in mental health. This study explored the association between FFWV and depressive symptoms among Chinese nurses with different experiences of workplace violence. METHODS: A cross-sectional study was conducted involving 1888 Chinese nurses from 12 tertiary hospitals in Shandong Province. The Fear of Future Violence at Work scale was used to measure FFWV. Depressive symptoms were assessed using the 10-item Center for Epidemiologic Studies Depression scale. Multiple logistic regression analysis was used to examine the association between FFWV and depressive symptoms. RESULTS: The prevalence of depressive symptoms was 45.9% (no aggression group: 24.3%; non-physical violence group: 46.1%; physical violence group: 63.7%), and 72.8% of nurses had high levels of fear of future workplace violence (no aggression group: 60.2%; non-physical violence group: 75.6%; physical violence group: 70.8%). Compared with low levels of FFWV, high levels of FFWV were associated with more depressive symptoms among nurses in the no aggression group (odds ratio [OR] = 3.269, 95% confidence interval [CI]: 1.102-9.695) and in the non-physical violence group (OR = 2.338, 95% CI: 1.385-3.945). CONCLUSION: Nurses who had experienced physical violence had the most depressive symptoms and nurses with experience of non-physical violence had the greatest FFWV. Our findings suggested that there was a significant association between FFWV and depressive symptoms among Chinese nurses in the no aggression and non-physical violence groups. Hospital administrators need to address FFWV needs when developing strategies to reduce depressive symptoms among nurses.

Association between social support and depressive symptoms among Chinese nurses with formal employment versus contract-based employment.

Background: Inequalities may exist in social and health status among nurses with different employment types. Few studies have investigated the relationship between social support and depressive symptoms among formally employed nurses compared with those in contract-based employment. This study aimed to examine the associations between social support and depressive symptoms among Chinese nurses with different forms of employment. Methods: The present cross-sectional study was performed with 1,892 nurses from 12 tertiary hospitals in Shandong Province, China. The Social Support Rating Scale and the 10-item Center for Epidemiologic Studies Depression Scale were used to measure social support and depressive symptoms, respectively. The association between social support and depressive symptoms among participants was explored using multiple linear regression analysis. Results: The prevalence of depressive symptoms was 45.7%. The mean score for total social support was 40.16 (SD = 7.47), which was lower than the norms in the general Chinese population. Formally employed participants' total social support scores were statistically significantly higher than those of contract-based employees (p ≤ 0.05). After controlling for confounding factors, the multiple linear regression analysis showed that subjective support and support utilization scores were inversely associated with depressive symptoms. Objective support scores were negatively associated with depressive symptoms only among contract-employment nurses. Conclusion: Chinese nurses have a higher prevalence of depressive symptoms and lower social support than the Chinese general population. Compared with contract-employment nurses, formally employed nurses had higher social support. Inverse associations exist between social support and depressive symptoms among nurses with different types of employment. It is suggested that improving Chinese nurses' social support levels and reducing their depressive symptoms, especially for nurses employed through contracts, are critical.

Mitigating soil salinity stress with titanium gypsum and biochar composite materials: Improvement effects and mechanism.

Titanium gypsum and biochar are considered effective amendments for mitigating soil salinity stress. However, the knowledge is inadequate regarding their efficiency and application as an improvement. In this study, TG-B composite was prepared by using industrial by-products titanium gypsum and biochar as raw materials and then modified by ball milling method, to characterize its microscopic characteristics and explore the improvement effect on saline-alkali soil and plant growth. Besides, we explored the mechanism of TG-B in improving saline-alkali soil and the dynamic balance of the solution reaction process. Our results showed that the CaSO4·2H2O particles in TG-B were finer, dispersed evenly, and contacted fully with soil gelatinous particles, which was more conducive to the improvement of saline-alkali soil. The results of TG-B with different ball milling ratios and different materials dosages indicated that the application rate of TG-B was 5%, and the optimum ratio of TG-B was TG: B (mass ratio) = 10:1, with the best soil improvement effect. The pot experiment proved that the indicators of indicating soil salinity such as pH, EC, SAR, and soluble Na+ decreased by 20.74%, 77.24%, 68.77%, and 44.70%, respectively, thus playing a good role in improving saline-alkali soil. In addition, pot experiments demonstrated that compared with the control group, the soil porosity and soil moisture content in the TG-B group increased by 15.95% and 38.71%, respectively, and further improve the structure and diversity of soil bacterial community when compared with titanium gypsum and biochar alone. Finally, the application of TG-B promoted the germination and growth of rice significantly through the synergistic effects of composite material components. These results all suggested that the application of TG-B was an effective strategy to improve soil salinity and promote plant growth. Therefore, it might provide new insights into the utilization of solid waste resources to improve saline-alkali lands.

Immobilization on anionic metal(loid)s in soil by biochar: A meta-analysis assisted by machine learning.

Metal pollution in soil has become one of the most serious environmental problems in China. Biochar is one of the most widely used remediation agents for soil metal pollution. However, the literature does not provide a consistent picture of the performance of biochar on the immobilization of anionic metal(loid)s, especially arsenic, in soil. To obtain a baseline understanding on the interactions of metals and biochar, 597 data records on four metal(loid)s (As, Cr, Sb and V) were collected from 70 publications for this meta-analysis, and the results are highlighted below. Biochar has a significant immobilization effect on anionic metal(loid)s in soil and reduces the bioavailability of these metals to plants. Subgroup analysis found that biochar could decrease the potential mobility of Cr, Sb and V, but the immobilization effect on As was not always consistent. Meanwhile, biochar pH and soil pH are the most key factors affecting the immobilization effect. To summarize, biochar can effectively immobilize Cr, Sb and V in soil, but more attention should be given to As immobilization in future applications. By regulating the properties of biochar and appropriate modification, anionic metal(loid)s in soil can be immobilized more effectively. Hence, both of the soil quality and crop quality can be improved.