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1.
Sci Rep ; 13(1): 19324, 2023 11 07.
Article in English | MEDLINE | ID: mdl-37935778

ABSTRACT

Urban parks became critical for maintaining the well-being of urban residents during the COVID-19 global pandemic. To examine the impact of COVID-19 on urban park usage, we selected New York City (NYC) and used SafeGraph mobility data, which was collected from a large sample of mobile phone users, to assess the change in park visits and travel distance to a park based on 1) park type, 2) the income level of the visitor census block group (visitor CBG) and 3) that of the park census block group (park CBG). All analyses were adjusted for the impact of temperature on park visitation, and we focused primarily on visits made by NYC residents. Overall, for the eight most popular park types in NYC, visits dropped by 49.2% from 2019 to 2020. The peak reduction in visits occurred in April 2020. Visits to all park types, excluding Nature Areas, decreased from March to December 2020 as compared to 2019. Parks located in higher-income CBGs tended to have lower reductions in visits, with this pattern being primarily driven by large parks, including Flagship Parks, Community Parks and Nature Areas. All types of parks saw significant decreases in distance traveled to visit them, with the exception of the Jointly Operated Playground, Playground, and Nature Area park types. Visitors originating from lower-income CBGs traveled shorter distances to parks and had less reduction in travel distances compared to those from higher-income CBGs. Furthermore, both before and during the pandemic, people tended to travel a greater distance to parks located in high-income CBGs compared to those in low-income CBGs. Finally, multiple types of parks proved crucial destinations for NYC residents during the pandemic. This included Nature Areas to which the visits remained stable, along with Recreation Field/Courts which had relatively small decreases in visits, especially for lower-income communities. Results from this study can support future park planning by shedding light on the different uses of certain park types before and during a global crisis, when access to these facilities can help alleviate the human well-being consequences of "lockdown" policies.


Subject(s)
COVID-19 , Recreation , Humans , Parks, Recreational , Pandemics , Public Facilities , COVID-19/epidemiology
2.
PLoS One ; 17(4): e0266593, 2022.
Article in English | MEDLINE | ID: mdl-35443016

ABSTRACT

The objective of this study was to compare the hydrological performance of an irrigated, 127 mm deep green roof, planted with vegetation native to the New York City area, to a conventional, non-irrigated, 100 mm deep green roof, planted with drought-tolerant Sedum spp. Four years of climate and runoff data from both green roofs were analyzed to determine seasonal stormwater retention. Empirical relationships between rainfall and runoff were developed for both roofs, and applied to historical rainfall data in order to compare stormwater retention values for different rainfall depths. Crop coefficients for the vegetation on each green roof were estimated using the soil moisture extraction function. This function was also used to estimate monthly evapotranspiration. Despite being irrigated, the green roof with native vegetation retained more stormwater per annum (64%) than the non-irrigated green roof planted with Sedum spp. (54%). The green roof planted with native vegetation also had approximately twice the crop coefficient (1.13) than the green roof planted with Sedum spp. (0.57), indicating that the New York City native plants transpire more stormwater than the Sedum spp. plants given certain climate and substrate moisture conditions. Overall, the results of the study indicate that, for the New York City climate region, irrigated green roofs of native vegetation have the capacity to better manage stormwater than non-irrigated green roofs planted with drought-tolerant succulents.


Subject(s)
Sedum , Conservation of Natural Resources/methods , Hydrology , New York City , Plants , Rain
3.
Energy Build ; 251: 111330, 2021 Nov 15.
Article in English | MEDLINE | ID: mdl-35431417

ABSTRACT

"Stay-at-home" orders and other health precautions enacted during the COVID-19 pandemic have led to substantial changes in residential electricity usage. We conduct a case study to analyze data from 390 apartments in New York City (NYC) to examine the impacts of two key drivers of residential electricity usage: COVID-19 case-loads and the outdoor temperature. We develop a series of regression models to predict two characteristics of residential electricity usage on weekdays: The average occupied apartment's consumption (kWh) over a 9am-5pm window and the hourly peak demand (Watt) over a 12pm-5pm window. Via a Monte Carlo simulation, we forecast the two usage characteristics under a possible scenario in which stay-at-home orders in NYC, or a similar metropolitan region, coincide with warm summer weather. Under the scenario, the 9am-5pm residential electricity usage on weekdays is predicted to be 15% - 24% higher than under prior, pre-pandemic conditions. This could lead to substantially higher utility costs for residents. Additionally, we predict that the residential hourly peak demand between 12pm and 5pm on weekdays could be 35% - 53% higher than that under pre-pandemic conditions. We conclude that the projected increase in peak demand - which might arise if stay-at-home guidelines coincided with hot weather conditions - could pose grid management challenges, especially for residential feeders. We also note that, if there is a longer lasting shift towards work and study-from-home, utilities will have to rethink load profile considerations. The applications of our predictive models to managing future smart-grid technology are also highlighted.

4.
Sci Data ; 7(1): 375, 2020 11 09.
Article in English | MEDLINE | ID: mdl-33168826

ABSTRACT

Building electricity is a major component of global energy use and its environmental impacts. Detailed data on residential electricity use have many interrelated research applications, from energy conservation to non-intrusive load monitoring, energy storage, integration of renewables, and electric vs. fossil-based heating. The dataset presented here, Multifamily Residential Electricity Dataset (MFRED), contains the electricity use of 390 apartments, ranging from studios to four-bedroom units. All apartments are located in the Northeastern United States (IECC-climate-zone 4 A), but differ in their heating/cooling system and construction year (early to late 20th century). To adhere to privacy guidelines, data were averaged across 15 apartments each, based on annual electricity use. MFRED includes real and reactive power, at 10-second resolution, for January to December 2019 (246 million data points). The annual average real power per apartment is 343 W (3.27 W/m2 of floor area), with strong variation between seasons and apartment size. Considering its large number of apartments, high time resolution, real and reactive power, and 12-month duration, MFRED is currently unique for the multifamily-sector.

5.
Sci Total Environ ; 722: 137834, 2020 Jun 20.
Article in English | MEDLINE | ID: mdl-32199373

ABSTRACT

The objective of this study was to quantify the seasonal risk of salt damage to bioswale plants, soil, microbes, and downstream waterbodies. To do so, we measured sodium, chloride, and electrical conductivity levels at seven bioswales located in the Bronx, New York City, over 42 storm events during a three-year monitoring period. The bioswale with the greatest salt contamination (median 206 mg/L chloride) had a unique inlet design without any possibility of inlet bypass. The most severe effects at all sites were found during the winter season, as infiltrate concentrations frequently (40% of winter samples) exceeded 1000 mg/L chloride, a level lethal to aquatic plants and invertebrates, and electrical conductivity exceeded 1500 µS cm-1 (50% of winter samples), a level that may displace bound metals from bioswale soils and into the subsurface. However, low levels of permanent salt contamination may be expected all year, as concentrations frequently (87% of all samples) exceeded the United States Environmental Protection Agency drinking water standard of 20 mg/L sodium. A regression of chloride washout over the year yielded concentrations greater than those damaging to soil structure and soil microbes (90 mg/L) until August 20th, and above those damaging to roadside vegetation (30 mg/L) for the entire year. Today, the vast majority of bioswales in cold climates are built with salt-tolerant vegetation, but prior to this study, it was unclear to what degree this was, in fact, necessary. Our findings confirm salt-tolerant vegetation to be optimal, as winter de-icing salts are not sufficiently flushed from soils by the spring growing season. Our findings also demonstrate how bioswale inlet design and site location can influence soil contamination.


Subject(s)
Soil , Environmental Monitoring , New York City , Plants , Seasons , Soil Pollutants
6.
Ambio ; 49(2): 569-583, 2020 Feb.
Article in English | MEDLINE | ID: mdl-31473977

ABSTRACT

Stormwater green infrastructure (GI) has the potential to provide ecosystem services (ES) that are currently lacking in many urban environments. Nevertheless, while stormwater GI presents a major opportunity for cities to enhance urban ES, there is insufficient evidence to link the complex social and ecological benefits of ES to different GI types for holistic urban planning. This study used an expert opinion methodology to identify linkages between 22 ES and 14 GI types within a New York City context. An analysis of results from five interdisciplinary workshops engaging 46 academic experts reveals that expert judgement of ES benefits is highest for larger green spaces, which are not universally considered for stormwater management, and lowest for vacant land and non-vegetated GI types. Overall, cultural services were identified as those most universally provided by GI. The results of this study highlight potential significant variations in ES benefits between different GI types, and indicate the importance of considering cultural services in future GI research and planning efforts. In the current absence of robust quantitive measurements linking ES and stormwater GI, increased qualitative insight could be obtained by expanding the methodology used in this work to include non-academic experts and other urban stakeholders. We therefore offer recommendations and learnings based on our experience with the approach.


Subject(s)
Ecosystem , Expert Testimony , Cities , Ecology
7.
Sci Total Environ ; 665: 944-958, 2019 May 15.
Article in English | MEDLINE | ID: mdl-30790764

ABSTRACT

The objective of this study was to evaluate the impact of bioswales on nutrient pollution in an urban combined sewershed. This evaluation was based on two criteria: the ability of bioswales to (1) remove nutrient pollution from stormwater runoff directly and (2) decrease sewer overflow volumes, which indirectly reduces total sewershed nutrient pollution during a storm event. Bioswales' direct nutrient removal was determined by analyzing nitrogen and phosphorus levels in water samples at seven bioswales located in the Bronx, New York City (NYC) over 42 storm events, while a bioswale's indirect nutrient removal through combined sewer overflow reduction was estimated by quantifying water retention at one of the bioswales. The study results indicated that: 1) the bioswale retained about 40% of stormwater conveyed to it from a drainage area 231 times its size, 2) bioswales leach nutrients into the subsurface, and 3) nitrogen leaching from bioswales varied seasonally, while phosphorus leaching decreased steadily over the study period. Although the studied bioswales leached a median 1.3 kg nitrogen per year into the subsurface, they provided an aggregate decrease in watershed nutrient pollution, from 7.7 to 6 kg nitrogen per year, due to their reduction of combined sewer overflow via stormwater retention.


Subject(s)
Nitrogen/analysis , Phosphorus/analysis , Waste Disposal, Fluid/instrumentation , Water Pollutants, Chemical/analysis , Water Pollution, Chemical/prevention & control , Wetlands , Biodegradation, Environmental , New York City
8.
Sci Total Environ ; 580: 168-177, 2017 Feb 15.
Article in English | MEDLINE | ID: mdl-28024746

ABSTRACT

To protect recreational water users from waterborne pathogen exposure, it is crucial that waterways are monitored for the presence of harmful bacteria. In NYC, a citizen science campaign is monitoring waterways impacted by inputs of storm water and untreated sewage during periods of rainfall. However, the spatial and temporal scales over which the monitoring program can sample are constrained by cost and time, thus hindering the construction of databases that benefit both scientists and citizens. In this study, we first illustrate the scientific value of a citizen scientist monitoring campaign by using the data collected through the campaign to characterize the seasonal variability of sampled bacterial concentration as well as its response to antecedent rainfall. Second, we examine the efficacy of the HyServe Compact Dry ETC method, a lower cost and time-efficient alternative to the EPA-approved IDEXX Enterolert method for fecal indicator monitoring, through a paired sample comparison of IDEXX and HyServe (total of 424 paired samples). The HyServe and IDEXX methods return the same result for over 80% of the samples with regard to whether a water sample is above or below the EPA's recreational water quality criteria for a single sample of 110 enterococci per 100mL. The HyServe method classified as unsafe 90% of the 119 water samples that were classified as having unsafe enterococci concentrations by the more established IDEXX method. This study seeks to encourage other scientists to engage with citizen scientist communities and to also pursue the development of cost- and time-efficient methodologies to sample environmental variables that are not easily collected or analyzed in an automated manner.

9.
Science ; 352(6288): 940-3, 2016 May 20.
Article in English | MEDLINE | ID: mdl-27199418

ABSTRACT

Policy directives in several nations are focusing on the development of smart cities, linking innovations in the data sciences with the goal of advancing human well-being and sustainability on a highly urbanized planet. To achieve this goal, smart initiatives must move beyond city-level data to a higher-order understanding of cities as transboundary, multisectoral, multiscalar, social-ecological-infrastructural systems with diverse actors, priorities, and solutions. We identify five key dimensions of cities and present eight principles to focus attention on the systems-level decisions that society faces to transition toward a smart, sustainable, and healthy urban future.


Subject(s)
Cities , Urban Health , Urban Renewal/methods , Disasters/statistics & numerical data , Ecosystem , Greenhouse Effect , Human Activities/statistics & numerical data , Humans , Mortality/trends , Urbanization
10.
Environ Sci Technol ; 48(17): 10273-81, 2014 Sep 02.
Article in English | MEDLINE | ID: mdl-25072298

ABSTRACT

Quantifying green roof evapotranspiration (ET) in urban climates is important for assessing environmental benefits, including stormwater runoff attenuation and urban heat island mitigation. In this study, a dynamic chamber method was developed to quantify ET on two extensive green roofs located in New York City, NY. Hourly chamber measurements taken from July 2009 to December 2009 and April 2012 to October 2013 illustrate both diurnal and seasonal variations in ET. Observed monthly total ET depth ranged from 0.22 cm in winter to 15.36 cm in summer. Chamber results were compared to two predictive methods for estimating ET; namely the Penman-based ASCE Standardized Reference Evapotranspiration (ASCE RET) equation, and an energy balance model, both parametrized using on-site environmental conditions. Dynamic chamber ET results were similar to ASCE RET estimates; however, the ASCE RET equation overestimated bottommost ET values during the winter months, and underestimated peak ET values during the summer months. The energy balance method was shown to underestimate ET compared the ASCE RET equation. The work highlights the utility of the chamber method for quantifying green roof evapotranspiration and indicates green roof ET might be better estimated by Penman-based evapotranspiration equations than energy balance methods.


Subject(s)
Cities , Environmental Restoration and Remediation/methods , Humidity , Least-Squares Analysis , Models, Theoretical , New York City , Reference Standards , Thermodynamics , Volatilization
11.
Water Resour Res ; 49(7): 3897-3911, 2013 Jul 01.
Article in English | MEDLINE | ID: mdl-24653543

ABSTRACT

Fecal bacteria are frequently found at much greater distances than would be predicted by laboratory studies, indicating that improved models that incorporate more complexity are might be needed to explain the widespread contamination of many shallow aquifers. In this study, laboratory measurements of breakthrough and retained bacteria in columns of intact and repacked sediment cores from Bangladesh were fit using a two-population model with separate reversible and irreversible attachment sites that also incorporated bacterial decay rates. Separate microcosms indicated an average first order decay rate of 0.03 log10 / day for free bacteria in both the liquid phase and bacteria attached to the solid phase. Although two-thirds of the column results could be well fit with a dual deposition site, single population model, fitting of one third of the results required a two-population model with a high irreversible attachment rate (between 5 and 60 hr-1) for one population of bacteria and a much lower rate (from 5 hr-1 to essentially zero) for the second. Inferred attachment rates for the reversible sites varied inversely with grain size (varying from 1 - 20 hr-1 for grain sizes between 0.1 and 0.3 mm) while reversible detachment rates were found to be nearly constant (approximately 0.5 hr-1). Field simulations based on the fitted two-population model parameters predict only a two-fold reduction in fecal source concentration over a distance of 10 m, determined primarily by the decay rate of the bacteria. The existence of a secondary population of bacteria with a low attachment rate might help explain the observed widespread contamination of tubewell water with E. coli at the field site where the cores were collected, as well as other similar sites.

12.
J Water Health ; 10(4): 565-78, 2012 Dec.
Article in English | MEDLINE | ID: mdl-23165714

ABSTRACT

Bangladesh is underlain by shallow aquifers in which millions of drinking water wells are emplaced without annular seals. Fecal contamination has been widely detected in private tubewells. To evaluate the impact of well construction on microbial water quality 35 private tubewells (11 with intact cement platforms, 19 without) and 17 monitoring wells (11 with the annulus sealed with cement, six unsealed) were monitored for culturable Escherichia coli over 18 months. Additionally, two 'snapshot' sampling events were performed on a subset of wells during late-dry and early-wet seasons, wherein the fecal indicator bacteria (FIB) E. coli, Bacteroidales and the pathogenicity genes eltA (enterotoxigenic E. coli; ETEC), ipaH (Shigella) and 40/41 hexon (adenovirus) were detected using quantitative polymerase chain reaction (qPCR). No difference in E. coli detection frequency was found between tubewells with and without platforms. Unsealed private wells, however, contained culturable E. coli more frequently and higher concentrations of FIB than sealed monitoring wells (p < 0.05), suggestive of rapid downward flow along unsealed annuli. As a group the pathogens ETEC, Shigella and adenovirus were detected more frequently (10/22) during the wet season than the dry season (2/20). This suggests proper sealing of private tubewell annuli may lead to substantial improvements in microbial drinking water quality.


Subject(s)
Environmental Monitoring/methods , Feces/microbiology , Water Wells/microbiology , Adenoviridae/genetics , Adenoviridae/isolation & purification , Bacterial Proteins/genetics , Bangladesh , Capsid Proteins/genetics , Drinking Water/microbiology , Enterotoxigenic Escherichia coli/genetics , Enterotoxigenic Escherichia coli/isolation & purification , Escherichia coli Proteins/genetics , Polymerase Chain Reaction , Sequence Analysis, DNA , Shigella/genetics , Shigella/isolation & purification , Water Quality
13.
Sci Total Environ ; 431: 314-22, 2012 Aug 01.
Article in English | MEDLINE | ID: mdl-22705866

ABSTRACT

Groundwater is routinely analyzed for fecal indicators but direct comparisons of fecal indicators to the presence of bacterial and viral pathogens are rare. This study was conducted in rural Bangladesh where the human population density is high, sanitation is poor, and groundwater pumped from shallow tubewells is often contaminated with fecal bacteria. Five indicator microorganisms (E. coli, total coliform, F+RNA coliphage, Bacteroides and human-associated Bacteroides) and various environmental parameters were compared to the direct detection of waterborne pathogens by quantitative PCR in groundwater pumped from 50 tubewells. Rotavirus was detected in groundwater filtrate from the largest proportion of tubewells (40%), followed by Shigella (10%), Vibrio (10%), and pathogenic E. coli (8%). Spearman rank correlations and sensitivity-specificity calculations indicate that some, but not all, combinations of indicators and environmental parameters can predict the presence of pathogens. Culture-dependent fecal indicator bacteria measured on a single date did not predict total bacterial pathogens, but annually averaged monthly measurements of culturable E. coli did improve prediction for total bacterial pathogens. A qPCR-based E. coli assay was the best indicator for the bacterial pathogens. F+RNA coliphage were neither correlated nor sufficiently sensitive towards rotavirus, but were predictive of bacterial pathogens. Since groundwater cannot be excluded as a significant source of diarrheal disease in Bangladesh and neighboring countries with similar characteristics, the need to develop more effective methods for screening tubewells with respect to microbial contamination is necessary.


Subject(s)
Feces/microbiology , Groundwater/microbiology , Rotavirus/pathogenicity , Bacteroides/pathogenicity , Bangladesh , Coliphages/pathogenicity , Drinking Water/microbiology , Enterobacteriaceae/pathogenicity , Escherichia coli/genetics , Escherichia coli/pathogenicity , Feces/virology , Groundwater/virology , Humans , Shigella/pathogenicity , Vibrio/pathogenicity , Water Microbiology
14.
Environ Sci Technol ; 46(3): 1361-70, 2012 Feb 07.
Article in English | MEDLINE | ID: mdl-22191430

ABSTRACT

Ponds receiving latrine effluents may serve as sources of fecal contamination to shallow aquifers tapped by millions of tube-wells in Bangladesh. To test this hypothesis, transects of monitoring wells radiating away from four ponds were installed in a shallow sandy aquifer underlying a densely populated village and monitored for 14 months. Two of the ponds extended to medium sand. Another pond was sited within silty sand and the last in silt. The fecal indicator bacterium E. coli was rarely detected along the transects during the dry season and was only detected near the ponds extending to medium sand up to 7 m away during the monsoon. A log-linear decline in E. coli and Bacteroidales concentrations with distance along the transects in the early monsoon indicates that ponds excavated in medium sand were the likely source of contamination. Spatial removal rates ranged from 0.5 to 1.3 log(10)/m. After the ponds were artificially filled with groundwater to simulate the impact of a rain storm, E. coli levels increased near a pond recently excavated in medium sand, but no others. These observations show that adjacent sediment grain-size and how recently a pond was excavated influence the how much fecal contamination ponds receiving latrine effluents contribute to neighboring groundwater.


Subject(s)
Environmental Monitoring/statistics & numerical data , Escherichia coli/isolation & purification , Sewage/microbiology , Toilet Facilities , Water Supply , Water Wells/microbiology , Bangladesh , Environmental Monitoring/methods , Geologic Sediments , Particle Size
15.
J Water Health ; 9(4): 708-17, 2011 Dec.
Article in English | MEDLINE | ID: mdl-22048430

ABSTRACT

The retention and release of total coliforms and Escherichia coli was investigated in hand-pumps removed from tubewells tapping a faecally contaminated aquifer in Matlab, Bangladesh, and from a new hand-pump deliberately spiked with E. coli. All hand-pumps were connected to reservoirs of sterile water and flushed. Faecal coliforms were observed in the discharge from all three of the previously used hand-pumps, at concentrations comparable to levels measured in discharge when they were attached to the tubewells. During daily flushing of one of the previously used hand-pumps, the concentration of total coliforms in the discharge remained relatively constant (approximately 10³ MPN/100 mL). Concentrations of E. coli in the pump discharge declined over time, but E. coli was still detectable up to 29 days after the start of flushing. In the deliberately spiked hand-pump, E. coli was observed in the discharge over 125 days (t50 = 8 days) and found to attach preferentially to elastomeric materials within the hand-pump. Attempts to disinfect both the village and new hand-pumps using shock chlorination were shown to be unsuccessful. These results demonstrate that hand-pumps can act as persistent reservoirs for microbial indicator bacteria. This could potentially influence drinking water quality and bias testing of water quality.


Subject(s)
Equipment Contamination , Water Microbiology/standards , Water Supply/standards , Environmental Monitoring , Equipment Design , Halogenation , Humans , Time Factors , Water Purification
16.
Environ Sci Technol ; 45(4): 1199-205, 2011 Feb 15.
Article in English | MEDLINE | ID: mdl-21226536

ABSTRACT

The health risks of As exposure due to the installation of millions of shallow tubewells in the Bengal Basin are known, but fecal contamination of shallow aquifers has not systematically been examined. This could be a source of concern in densely populated areas with poor sanitation because the hydraulic travel time from surface water bodies to shallow wells that are low in As was previously shown to be considerably shorter than for shallow wells that are high in As. In this study, 125 tubewells 6-36 m deep were sampled in duplicate for 18 months to quantify the presence of the fecal indicator Escherichia coli. On any given month, E. coli was detected at levels exceeding 1 most probable number per 100 mL in 19-64% of all shallow tubewells, with a higher proportion typically following periods of heavy rainfall. The frequency of E. coli detection averaged over a year was found to increase with population surrounding a well and decrease with the As content of a well, most likely because of downward transport of E. coli associated with local recharge. The health implications of higher fecal contamination of shallow tubewells, to which millions of households in Bangladesh have switched in order to reduce their exposure to As, need to be evaluated.


Subject(s)
Arsenic/analysis , Escherichia coli/isolation & purification , Water Supply/standards , Bangladesh , Environmental Monitoring , Feces/microbiology , Groundwater , Humans , Water Pollution/analysis
17.
PLoS One ; 6(12): e29593, 2011.
Article in English | MEDLINE | ID: mdl-22216326

ABSTRACT

BACKGROUND: Millions of households throughout Bangladesh have been exposed to high levels of arsenic (As) causing various deadly diseases by drinking groundwater from shallow tubewells for the past 30 years. Well testing has been the most effective form of mitigation because it has induced massive switching from tubewells that are high (>50 µg/L) in As to neighboring wells that are low in As. A recent study has shown, however, that shallow low-As wells are more likely to be contaminated with the fecal indicator E. coli than shallow high-As wells, suggesting that well switching might lead to an increase in diarrheal disease. METHODS: Approximately 60,000 episodes of childhood diarrhea were collected monthly by community health workers between 2000 and 2006 in 142 villages of Matlab, Bangladesh. In this cross-sectional study, associations between childhood diarrhea and As levels in tubewell water were evaluated using logistic regression models. RESULTS: Adjusting for wealth, population density, and flood control by multivariate logistic regression, the model indicates an 11% (95% confidence intervals (CIs) of 4-19%) increase in the likelihood of diarrhea in children drinking from shallow wells with 10-50 µg/L As compared to shallow wells with >50 µg/L As. The same model indicates a 26% (95%CI: 9-42%) increase in diarrhea for children drinking from shallow wells with ≤10 µg/L As compared to shallow wells with >50 µg/L As. CONCLUSION: Children drinking water from shallow low As wells had a higher prevalence of diarrhea than children drinking water from high As wells. This suggests that the health benefits of reducing As exposure may to some extent be countered by an increase in childhood diarrhea.


Subject(s)
Arsenic/isolation & purification , Diarrhea/epidemiology , Water Pollutants, Chemical/isolation & purification , Water Supply , Bangladesh/epidemiology , Child , Humans
18.
J Phys Condens Matter ; 22(31): 315301, 2010 Aug 11.
Article in English | MEDLINE | ID: mdl-21399357

ABSTRACT

Electrolyte transport in nanochannels plays an important role in a number of emerging areas. Using non-equilibrium molecular dynamics (NEMD) simulations, the fundamental transport behavior of an electrolyte/water solution in a confined model nanoenvironment is systematically investigated by varying the nanochannel dimension, solid phase, electrolyte phase, ion concentration and transport rate. It is found that the shear resistance encountered by the nanofluid strongly depends on these material/system parameters; furthermore, several effects are coupled. The mechanisms of the nanofluidic transport characteristics are explained by considering the unique molecular/ion structure formed inside the nanochannel. The lower shear resistance observed in some of the systems studies could be beneficial for nanoconductors, while the higher shear resistance (or higher effective viscosity) observed in other systems might enhance the performance of energy dissipation devices.


Subject(s)
Electrolytes/chemistry , Molecular Dynamics Simulation , Nanotubes/chemistry , Absorption , Ion Transport , Kinetics , Molecular Conformation , Nanopores , Silicon Dioxide/chemistry , Solutions , Surface Properties
19.
Langmuir ; 25(21): 12687-96, 2009 Nov 03.
Article in English | MEDLINE | ID: mdl-19791780

ABSTRACT

When a nonwetting fluid is forced to infiltrate a hydrophobic nanoporous solid, the external mechanical work is partially dissipated into thermal energy and partially converted to the liquid-solid interface energy to increase its enthalpy, resulting in a system with a superior energy absorption performance. To clarify the energy dissipation and conversion mechanisms, experimental infiltration and defiltration tests of liquid/ion solutions into nanopores of a hydrophobic ZSM-5 zeolite were conducted. The characteristics of energy dissipation were quantified by measuring the temperature variation of the immersed liquid environment and compared against that estimated from pressure-infiltration volume isotherms during infiltration and defiltration stages of the test. Both stages were observed to be endothermic, with the temperature of the liquid phase showing a steady increase with changes in liquid saturation. The confinement of the molecular-sized pore space causes the liquid molecules/ions to transit between statuses of orderly and disorderly motions, resulting in dissipation behaviors that vary with liquid infiltration/defiltration rates and the types and concentrations of additive electrolytes in the liquid-both factors of which alter the characteristics of the nanofluidic transport behavior.

20.
Phys Chem Chem Phys ; 11(30): 6520-4, 2009 Aug 14.
Article in English | MEDLINE | ID: mdl-19809685

ABSTRACT

Fluid channels with inclined solid walls (e.g. cone- and slit-shaped pores) have wide and promising applications in micro- and nano-engineering and science. In this paper, we use molecular dynamics (MD) simulations to investigate the mechanisms of water infiltration (adsorption) into cone-shaped nanopores made of a hydrophobic graphene sheet. When the apex angle is relatively small, an external pressure is required to initiate infiltration and the pressure should keep increasing in order to further advance the water front inside the nanopore. By enlarging the apex angle, the pressure required for sustaining infiltration can be effectively lowered. When the apex angle is sufficiently large, under ambient condition water can spontaneously infiltrate to a certain depth of the nanopore, after which an external pressure is still required to infiltrate more water molecules. The unusual involvement of both spontaneous and pressure-assisted infiltration mechanisms in the case of blunt nanocones, as well as other unique nanofluid characteristics, is explained by the Young's relation enriched with the size effects of surface tension and contact angle in the nanoscale confinement.


Subject(s)
Carbon/chemistry , Nanotechnology/methods , Water/chemistry , Adsorption , Biological Transport , Chemistry, Physical/methods , Computer Simulation , Hydrophobic and Hydrophilic Interactions , Nanoparticles/chemistry , Nanotubes, Carbon/chemistry , Pressure , Surface Properties
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