Preparation of bio-based porous material with high oil adsorption capacity from bio-polyurethane and sugarcane bagasse.

This work presents the fabrication of bio-based porous material for highly efficient removing of oil from oil/water system. The sunflower oil-based polyol was synthesized and then used to replace the petro-polyol in the simultaneous preparation of a sugarcane bagasse-polyurethane composite (SC-PU composite) by inserting sugarcane fiber filler into the PU matrix. The bio-polyol was obtained from sunflower oil with a hydroxyl number of 182 mg KOH g-1, and functionality of 3.5 OH groups per mol. The bio-polyol and the newly designed bio-based SC-PU composite were characterized by NMR, FT-IR and SEM analysis. The effect of several parameters such as bio-polyol/petro-polyol ratio, dosage of adding sugarcane fiber and size of filler particles on oil adsorption capacity of a new sorbent material were also investigated. Oil sorption capacity of the newly designed sorbent was relatively high, up to 15.2 g g-1 when 20% sugarcane bagasse with a particle size of 1 mm was added into the bio-polyurethane matrix. This is nearly four times higher than that of neat PU foam without the biomass filler and lignocellulosic materials. This finding demonstrated the importance of selecting the right components to fabricate a cost-effective, highly renewable and biodegradable sorbent with high oil-water separation efficiency, reducing the use of chemicals from fossil sources.

Preparation of Metal-Loaded ZSM-5 Zeolite Catalyst and Its Catalytic Effect on HMF Production from Biomass.

This research work presented the preparation of metal-loading ZSM-5 zeolite catalyst by loading Cu and Cr ions into the ZSM-5 zeolite particles using ion exchange method. Technical conditions of ion exchange processes were investigated to find suitable process for preparation of modified zeolite. The as-obtained zeolite catalyst was then applied for the transformation reaction of biomass-derived glucose into 5-hydroxymethyl furfural (HMF). Glucose hydrolysate that achieved from enzymatic hydrolysis of rice straw was used as feedstock for transformation reaction using Cu-Cr/ZSM-5 catalyst. This metal-loading zeolite exhibited good catalytic activity for lignocellulosic conversion to HMF, a valuable renewable green chemical. The content of loading metals in the zeolite catalyst affected significantly on the HMF yield. Moreover, the influence of transformation conditions such as solvent, temperature, catalyst dosage, and reaction time was investigated. According to the results, the optimum condition leading to the highest yield of HMF of 49.5 ± 0.5% was established. The as-prepared Cu-Cr/ZSM-5 zeolite catalyst showed impressive performance and can be considered a promising catalyst for the transformation of biomass-derived glucose to HMF.

Pretreatment of coir lignocellulose for preparation of a porous coir-polyurethane composite with high oil adsorption capacity.

In this present work, different treatment methods of coir biomass were investigated to improve the oil sorption capacity. The treated coir material was then used to fabricate an efficient porous coir-polyurethane composite sorbent by incorporating coir into a polyurethane matrix. The new composite possessed an open cell structure with high porosity and high oil sorption efficiency. The suitable technical parameters of the coir treatment process were selected as: hot water treatment at 170 °C for 120 minutes. After treatment under this suitable condition, treated coconut fiber exhibited an oil adsorption capacity of 4.1 g g-1, with an increase of 78.3% compared to that of the original coconut fiber. Furthermore, the application of the as-fabricated porous composite sorbent for oil treatment was examined under various conditions. It was observed that the oil uptake capacity of the new composite sorbent was high, up to 15.2 g g-1 when 20% treated coir material with a particle size of 1 mm was added into the polyurethane matrix. Several advantages of the new porous composite sorbent obtained from coir biomass and polyurethane such as low cost, being eco-friendly, ready availability and high buoyancy make it an efficient sorbent material for oil spill treatment.

Production of 5-hydroxymethylfurfural (HMF) from rice-straw biomass using a HSO3-ZSM-5 zeolite catalyst under assistance of sonication.

This work studied the application of sulfonated ZSM-5 zeolite, a bi-functional catalyst for conversion of biomass-derived glucose to HMF. Glucose hydrolysate was obtained by enzymatic hydrolysis of rice straw, that was pretreated by sodium hydroxide. Glucose hydrolysate was then subjected to a transformation reaction to achieve HMF using HSO3-ZSM-5 zeolite under the assistance of sonication. The reaction conditions including solvent, temperature, catalyst dosage and reaction time were studied. Suitable conditions, which gave the highest yield of HMF of 54.1% have been found. The HSO3-ZSM-5 zeolite presented a high catalytic efficiency for conversion of glucose to HMF, an important and useful intermediate in the chemical industry.

Influence of the acidity of solid catalyst HSO3-ZSM-5 on the hydrolysis of pretreated corncob.

This work aimed to investigate the application of a solid acid catalyst, a replacement for mineral acids or enzymes, to biomass conversion for further applications. Sulfonated zeolite, HSO3-ZSM-5, was successfully synthesized and characterized by several analysis techniques. The obtained catalyst showed high activity and efficiency in the hydrolysis of pretreated corn cob. Moreover, the acidity of the zeolite product positively influenced the biomass conversion. The influences of reaction parameters such as catalyst loading, reaction time and temperature on the hydrolysis were also established. Under suitable conditions, a hydrolysis yield of ∼54% was achieved. This recyclable solid acid catalyst provided a promising potential for applications in many industrially important hydrolysis processes of biomass.