Using a multi-method approach based on soil radon deficit, resistivity, and induced polarization measurements to monitor non-aqueous phase liquid contamination in two study areas in Italy and India.

Geochemical and geophysical surveys employing radon deficit, resistivity, and induced polarization (IP) measurements were undertaken on soil contaminated with non-aqueous phase liquids (NAPLs) in two different sites in India and in Italy. Radon deficit, validated through the comparison with average soil radon in reference unpolluted areas, shows the extension of contamination in the upper part of the unsaturated aquifers. In site 1 (Italy), the spill is not recent. A residual film of kerosene covers soil grains, inhibiting their chargeability and reducing electrical resistivity difference with background unpolluted areas. No correlation between the two parameters is observed. Soil volatile organic compounds (VOCs) concentration is not linked with radon deficit, supporting the old age of the spillage. NAPL pollution in sites 2a and 2b (India) is more recent and probably still active, as demonstrated by higher values of electrical resistivity. A good correlation with IP values suggests that NAPL is still distributed as droplets or as a continuous phase in the pores, strengthening the scenario of a fresh spill or leakage. Residual fraction of gasoline in the pore space of sites 2a and 2b is respectively 1.5 and 11.8 kg per cubic meter of terrain. This estimation is referred to the shallower portion of the unsaturated aquifer. Electrical resistivity is still very high indicating that the gasoline has not been strongly degraded yet. Temperature and soil water content influence differently radon deficit in the three areas, reducing soil radon concentration and partly masking the deficit in sites 2a and 2b.

Soil radon survey to assess NAPL contamination from an ancient spill. Do kerosene vapors affect radon partition ?

A soil radon-deficit survey was carried out in a site polluted with kerosene (Rome, Italy) in winter 2016 to assess the contamination due to the NAPL residual component in the vadose zone and to investigate the role of the vapor plume. Radon is indeed more soluble in the residual NAPL than in air or water, but laboratory experiments demonstrated that it is also preferentially partitioned in the NAPL vapors that transport it and may influence soil radon distribution patterns. Specific experimental configurations were designed and applied to a 31-station grid to test this hypothesis; two RAD7 radon monitors were placed in-series and connected to the top of a hollow probe driven up to 80-cm depth; the first instrument was directly attached to the probe and received humid soil gas, which was counted and then conveyed to the second monitor through a desiccant (drierite) cylinder capturing moisture and eventually the NAPL volatile component plus the radon dissolved in vapors. The values from the two instruments were cross-calibrated through specifically designed laboratory experiments and compared. The results are in agreement within the error range, so the presence of significant NAPL vapors, eventually absorbed by drierite, was ruled out. This is in agreement with low concentrations of soil VOCs. Accordingly, the radon-deficit is ascribed to the residual NAPL in the soil pores, as shown very well also by the obtained maps. Preferential areas of radon-deficit were recognised, as in previous surveys. An average estimate of 21 L (17 Kg) of residual NAPL per cubic meter of terrain is provided on the basis of original calculations, developed from published equations. A comparison with direct determination of total hydrocarbon concentration (23 kg per cubic meter of terrain) is provided.