Methylene blue adsorption on thermo plasma expanded graphite in a multilayer column system.

The removal of dyes from wastewater is an important topic in environmental applications. Methylene blue (MB) is one of the most worrisome compounds, as it is widespread and used in many industrial activities. Adsorption represents an effective technique for the removal of this contaminant. Thermo plasma expanded graphite (TPEG) is an industrial material characterized by a fibrous morphology, a very low density and overlapped graphene layers. TPEG has a higher specific surface compared to conventional thermo-expanded graphite and it can establish effective attractive forces with charged pollutants. These properties make TPEG a very promising adsorbent material. In the present work, TPEG was tested in an innovative multilayer column system to treat MB contaminated solutions. Several batch experiments were carried out by varying pH, initial MB concentration and temperature. The optimal adsorption performance was assessed at pH 11, around which the TPEG assumed the maximum negative charge. Based on these results, the adsorption mechanism appeared to be related mainly to electrostatic interactions. At room temperature, the greatest amount of MB adsorbed on TPEG was detected by treating solutions with an initial concentration of 30 mgMB/L. The temperature increase from 20 to 40 °C caused an enhanced adsorption capacity when concentrations higher than 10 mgMB/L were treated. The adsorption trends were accurately described by a pseudo-second order kinetic law and the adsorption isotherms at 20 and 40 °C were found to follow both the features of Freundlich and Langmuir models. The adsorption capacity was estimated to reach threshold values around 95 mgMB/gTPEG and 265 mgMB/gTPEG at 20 and 40°C, respectively. The Gibbs energy change (ΔG°) was calculated to about -7.80 kJ/mol, which proved that the process is spontaneous from a thermodynamic point of view. Finally, it was verified that TPEG can be efficiently reused 5 times after a simple chemical regeneration phase with HCl.

Hexavalent chromium reduction by zero-valent magnesium particles in column systems.

The discharge of hexavalent chromium in aquatic environments represents an issue of great concern. The chemical reduction of Cr6+ to Cr3+, which is less mobile and harmful, is a suitable approach for chromium removal. In this regard, in comparison to other reactive metals, the use of zero-valent magnesium (ZVM) has several advantages. Nevertheless, this element has been scarcely investigated in the decontamination of water and wastewater. In particular, no studies have been conducted by applying Mg0 particles fixed in column systems for Cr6+ reduction. In the present study, a wide experimental investigation was carried out to analyse the chromium abatement through zero valent magnesium particles in a packed batch column. The effects of pH, initial Cr6+ concentration and temperature were investigated. The experimental results proved that the process performances were mainly affected by pH values. High efficiencies were detected at pH 3, while unsatisfactory abatements were observed at pH 5 and under uncontrolled pH conditions. At pH 3, the process performance worsened with the rise in the initial chromium concentration. In particular, a complete abatement was detected in 180 min by treating solutions with initial Cr6+ concentrations up to 40 mg/L. The effect of temperature was negligible at pH 3 and under uncontrolled pH, while the increase from 20 to 30 and 40 °C produced a significant improvement in the removal yields at pH 5. By means of a kinetic analysis a theoretical law able to accurately describe the experimental removal trends was identified. Furthermore, a mathematical relation between the observed kinetic constants and the magnesium to initial chromium amount ratio was defined. Finally, the reaction pathways were proposed, and the reaction products identified.