ABSTRACT
Current climate projections suggest that the UK will experience warmer and wetter winters and warmer and dryer summers. This change in the climate could affect the incidence or severity of microbiological attack on exposed timber and have significant impact on buildings and construction. One method of assessing the geographical climate based hazard is to use the Scheffer Climate index, which relates temperature and rain variables. There was a considerable increase in the Scheffer climate indices for various locations of the UK from 1990 to 2019. The highest index values are seen in the Northern and western areas of the United Kingdom, but increases are seen across the country. The paper also uses representative concentration pathway (RCP) scenarios to project future climate decay indices for the United Kingdom until the end of the twenty-first century. The projections show an increase in the Scheffer index even in the lowest RCP scenario, with indices in all regions of the UK increasing to indicate very high hazard of decay. The major implication is that to ensure serviceability of wood and wooden structures exposed to the environment the use of good design, durable woods and properly treated or modified woods will be paramount.
ABSTRACT
In this study, we investigated the physicochemical properties of the cellulosic preparations obtained from both untreated perennial ryegrass leaves and de-juiced leaves. It was found that treatment at 22 degrees C with 18% NaOH and 18% KOH for 2h, and 10% NaOH and 10% KOH for 16 h yielded 28.2%, 28.8%, 22.7%, 23.4%, respectively, of 'cellulose' residue from untreated ryegrass leaves and 35.7%, 36.8%, 32.8% and 34.6%, respectively, from the de-juiced leaves. For each cellulosic fraction, the glucose content was 71.6%, 69.6%, 67.8%, 66.7%, 69.7%, 68.6%, 63.9% and 61.7%, respectively. The structure of the cellulose samples was examined using FTIR and CP/MAS (13)C NMR spectroscopy and X-ray diffraction. The cellulosic preparations were free of bound lignin except for noticeable amounts of residual hemicelluloses (28.4-38.3%), and had intrinsic viscosities between 275.1 and 361.0 mL/g, along with molecular weights from 144,130 to 194,930 g/mol. This study found that the cellulose samples isolated from both de-juiced ryegrass leaves and the untreated leaves had a much lower percent crystallinity (33.0-38.6%) than that from wood-based fibres (60-70%) and had much shorter fibres (0.35-0.49 mm) than those of either cereal straws, bagasse or wood. In addition, a partial disruption of the hydrogen bonds and microfibrils may occur during the de-juicing process by mechanical activity, which results in a decreased cellulose crystallinity and fibre length. These findings are significant in relation to hydrolysing ryegrass cellulose for bio-ethanol production.
