ABSTRACT
Over the last decade, there has been increased interest in applying biomass as a raw material for producing biofuels used for thermochemical conversions. Extensive use of biomass could lead to controversial competition for arable land, water, and food; therefore, only waste materials and agricultural by-products and residues should be used to produce biofuels. One suitable by-product of agricultural production is crop residue from the harvest of maize for grain (corn stover). The harvest residues of corn stover consist of four fractions, i.e., husks, leaves, cobs, and stalks, which are structurally and morphologically distinct. The aim of the study was to determine the effect of selected maize cultivars with distinct FAO (Food and Agriculture Organization of the United Nations) earliness classifications on the chemical and energetic properties of their corn cob cores. We determined the chemical properties based on elemental analysis, and the energy properties based on the heat of combustion and calorific values. The content of ash and volatile compounds in the corn cobs were also determined. The results indicated that the heat of combustion of fresh and seasoned corn cob cores ranged from 7.62-10.79 MJ/kg and 16.19-16.53 MJ/kg, respectively. The heat of combustion and calorific value of corn cob cores in the fresh state differed significantly and were strongly correlated with maize cultivars with distinct FAO earliness.
ABSTRACT
Cereal straw is an environmentally friendly, rapidly renewable, and sustainable raw material for manufacturing insulating panels for building engineering. Credible data on thermal properties of insulating panels are crucial for appropriate and accurate design of building envelopes. The objective of the study was to determine and validate thermal properties of the panels made of cereal straw. Specific heat was measured with the calorimetric method. Thermal conductivity was determined with the inverse method and Isomet 2114 instrument, respectively. Both approaches accounted for the temperature influence. The specific heat of the panels was as high as 1600 J/(kg·K), while the thermal conductivity varied in the range from 0.025 to 0.075 W/(m·K) depending on the applied experimental method. The studied properties were validated and their credibility was assessed. High accuracy of heat transfer modeling was obtained for the properties measured with the calorimetric method and identified with inverse modeling.
