Wood-Poly(furfuryl Alcohol) Prepreg: A Novel, Ecofriendly Laminate Composite.

Prepregs are commonly fabricated with non-renewable petroleum-based materials. To reduce the impact of the manufacturing of these materials and to produce more sustainable prepregs, this research aims to manufacture poly(furfuryl alcohol)/wood veneer prepregs and their posterior molding in laminate composites. For this purpose, the vacuum infusion process was used to impregnate the wood veneers, and compression molding was applied to manufacture three- and four-layer laminate composites. Scanning electronic microscopy was used to evaluate the impregnation. the laminate manufacturing and differential scanning calorimetry were used to predict the shelf-life of the prepregs, Fourier-transform infrared was used to evaluate the induced hydrolysis resistance, and thermogravimetric analysis was used to determine the thermal degradation of the laminates. Moreover, water uptake and flexural, compressive, and tensile properties were evaluated. The kinetic models were effective and showed a shelf life for the laminates of approximately 30 days in storage at -7 °C, which is an interesting result for laminates with lignocellulosic materials. FTIR proved the laminates' excellent resistance to hydrolysis. The water absorption, thermal stability, and mechanical properties did not differ as the amount of wood veneer increased, but these results were up to ~40% higher compared with unidirectional wood laminates found in the literature, which is probably linked to the excellent interface observed with SEM.

Performance Analysis of Loose-Fill Thermal Insulation from Wood Scobs Coated with Liquid Glass, Tung Oil, and Expandable Graphite Mixture.

The current study presents the results of monitoring the behavior of loose-fill thermal insulating material for buildings made of wood scobs (WS), which were coated with one, two, and three component-based coatings from liquid glass (LG), tung oil (TO), and expandable graphite (EG). The thermal conductivity of samples in the dry state and under normal laboratory conditions, short-term water absorption by partial immersion, surface wettability, and water vapor permeability were evaluated, and regression equations describing the variations in numerical values of specified properties under different amounts of each coating component were presented. It was shown that LG and TO act as hydrophobic layers that, in conjunction, reduce water absorption by a maximum of 274%, have a contact angle equal to 86°, and lower thermal conductivity by 55% in the dry state due to the specifics of the layer formed on the surface of WS. The addition of EG to LG coating resulted in insignificantly changed water absorption and thermal conductivity values, indicating the potential of this material to be used to improve the fire resistance of wood-based composites in the future. The results showed that the three-component layer of LG/TO/EG reduces water absorption by a maximum of 72%, increases thermal conductivity in the dry state by a minimum of 0.4%, and increases the contact angle to 81° at 100 wt.% LG. The changes in water vapor permeability of all compositions were determined to be insignificant.

Rigid Polyurethane Biofoams Filled with Pine Seed Shell and Yerba Mate Wastes.

Pine seed shells and yerba mate are common wastes leftover from the food and beverage industry. This study presents the development of rigid polyurethane foams (RPUFs) filled with pine seed shells and yerba mate at 5, 10 and 15 wt%. The fillers were characterized for chemical properties using bench chemistry analyses, and the RPUFs were investigated in terms of chemical, morphological, mechanical, thermal and colorimetric characteristics. The main results indicated that yerba mate showed good compatibility with the polyurethane system, probably because its available hydroxyl groups reacted with isocyanate groups to form urethane bonds, producing increases in mechanical and thermal properties. However, pine seed shell did not appear to be compatible. Anisotropy increased slightly, as there was an increase in the percentage of reinforcement. The mechanical properties of the yerba mate reinforced foams proved stable, while there was a loss of overall up to ~50% for all mechanical properties in those reinforced with pine seed shell. Thermal properties were improved up to ~40% for the yerba mate reinforced foams, while those reinforced with pine nuts were stable. It was possible to observe a decrease in the glass transition temperature (Tg) of ~-5 °C for the yerba mate reinforced foams and ~-14 °C for the pine seed shell reinforced ones.

Impact of Different Ratios of Lignin Waste and Liquid Glass on the Performance Characteristics of Biopolyurethane Foams.

In the current study, biopolyurethane foam was modified with 2.5-10 wt.% lignin waste (LigW) and liquid glass (LG)-modified LigW particles at different LigW/LG ratios-1:1 and 1:2-and their impact on performance characteristics-i.e., rheology, foaming times, apparent density, thermal conductivity before and after aging, dimensional stability at ambient and elevated conditions, compressive and tensile strengths, short-term water absorption by partial immersion, and water vapor permeability-was determined and evaluated. Structural analysis was implemented and structural parameters were taken into consideration as well. During the study, it was determined that 2.5-10 wt.% particles at the LigW/LG ratio of 1:2 showed a superior impact on the physical and mechanical properties of bioPUR foams. The apparent density only insignificantly increased and was in a density range suitable for commercially available polyurethanes. For particles at 10 wt.% and LigW/LG ratio of 1:1, the thermal conductivity value improved by 3.2%, the compressive strength increased by 153%, while the tensile strength improved by 23.5%, indicating sufficient interfacial adhesion between the filler and polymer matrix. Moreover, the short-term water absorption by partial immersion remained almost unchanged, while the water vapour diffusion resistance factor improved from 43 to 48. Additionally, the incorporation of LigW/LG 1:1 and LigW/LG 1:2 particles made it possible to obtain dimensionally and structurally stable closed-cell bioPUR foams for possible application as thermal insulation in building envelopes.

Imidazolium Ionic Liquids as Compatibilizer Agents for Microcrystalline Cellulose/Epoxy Composites.

Four imidazolium-based ionic liquids (IL; 1-butyl-3-methylimidazolium chloride, 1-carboxymethyl-3-methylimidazolium chloride, 1,3-dicarboxymethylimidazolium chloride and 1-(2-hydroxyethyl) -3-methylimidazolium chloride) were tested as compatibilizers of microcrystalline cellulose (MCC). Subsequently, ethanolic IL solutions were prepared; MCC was mixed, and the mixtures were left to evaporate the ethanol at ambient conditions. These modified MCC were characterized and applied as reinforcements (5.0 and 10 phr) in an epoxy resin aiming to manufacture biobased composites with enhanced performances. The IL did not significantly modify the morphological and structural characteristics of such reinforcements. Regarding the thermal stability, the slight increase was associated with the MCC-IL affinity. The IL-modified MCC-epoxy composites presented improved mechanical responses, such as flexural strength (≈22.5%) and toughness behavior (≈18.6%), compared with pure epoxy. Such improvement was also obtained for the viscoelastic response, where the storage modulus at the glassy state depended on the MCC amount and IL type. These differences were associated with stronger hydrogen bonding between IL and epoxy hardener or the IL with MCC, causing a "bridging" effect between MCC and epoxy matrix.

Analysis of Active and Passive Deformation of Expanded Polystyrene Foam under Short-Term Compression.

In this paper, we undertake a detailed analysis of the active and passive deformation of expanded polystyrene (EPS), which is used as a thermal insulating layer in building partitions, under short-term compressive loading. The values of residual strain in 10-40 kg/m3 density EPS after monotonically increasing loading under active deformations of 20%, 30%, 40%, 50%, and 60% with the following complete removal are determined. These values are a physical sign of the elastic-plastic state of EPS. It has been shown that the final destruction of cells takes place in EPS when the active strain reaches 50%. Empirical equations are proposed to estimate the residual strain of EPS based on density with determination coefficients varying from 0.744 to 0.986 at a confidence level of 90%. Moreover, graphical interpretations with regression equations for residual strain dependence on density and compressive strength, as well as density and active strain, were proposed with determination coefficients equal to 0.779 and 0.717, respectively.

Impact of Sunflower Press Cake and Its Modification with Liquid Glass on Polyurethane Foam Composites: Thermal Stability, Ignitability, and Fire Resistance.

Polyurethane (PUR) foams are some of the most promising thermal insulating materials because of their high flammability, but further applications are limited. Therefore, the development of flame-retardant materials with sufficient strength characteristics, water resistance, and low thermal insulating properties is of great importance to the modern building industry. This study evaluates the possibility of a vacuum-based liquid glass (LG) infusion into bio-based fillers, in this case, sunflower press cake (SFP) particles, to improve the mechanical performance, water absorption, thermal insulation, ignitability, thermal stability, and flame retardancy of the resulting polyurethane (PUR) foam composites. The main findings show that LG slightly improves the thermal stability and highly contributes to the ignitability and flame retardancy of the resulting products. Most importantly, from 10 wt.% to 30 wt.%, the SFP/LG filler reduces the thermal conductivity and water absorption values by up to 20% and 50%, respectively, and increases the compressive strength by up to 110%. The results obtained indicate that the proposed SFP/LG filler-modified PUR foam composites are suitable for applications as thermal insulation materials in building structures.

Natural Additives Improving Polyurethane Antimicrobial Activity.

In recent years, there has been a growing interest in using polymers with antibacterial and antifungal properties; therefore, the present review is focused on the effect of natural compounds on the antibacterial and antifungal properties of polyurethane (PUR). This topic is important because materials and objects made with this polymer can be used as antibacterial and antifungal ones in places where hygiene and sterile conditions are particularly required (e.g., in healthcare, construction industries, cosmetology, pharmacology, or food industries) and thus can become another possibility in comparison to commonly used disinfectants, which mostly show high toxicity to the environment and the human health. The review presents the possibilities of using natural extracts as antibacterial, antifungal, and antiviral additives, which, in contrast to the currently used antibiotics, have a much wider effect. Antibiotics fight bacterial infections by killing bacteria (bactericidal effect) or slowing and stopping their growth (bacteriostatic effect) and effect on different kinds of fungi, but they do not fight viruses; therefore, compounds of natural origin can find wide use as biocidal substances. Fungi grow in almost any environment, and they reproduce easily in dirt and wet spaces; thus, the development of antifungal PUR foams is focused on avoiding fungal infections and inhibiting growth. Polymers are susceptible to microorganism adhesion and, consequently, are treated and modified to inhibit fungal and bacterial growth. The ability of micro-organisms to grow on polyurethanes can cause human health problems during the use and storage of polymers, making it necessary to use additives that eliminate bacteria, viruses, and fungi.

Optimization of Pin Position and Angle for Z-Pin-Reinforced Foam Core Sandwich Structures.

Sandwich panels (SP) are very promising components for structures as they ally high levels of specific stiffness and strength. Civil, marine and automotive industries are some examples of the sectors that use SPs frequently. This work demonstrates the potential of manufacturing Z-pin-reinforced foam core SPs, using a design strategy that indicated optimal values for both pin position and angle, keeping the same pin diameter as determined in a previous study. A simple search algorithm was applied to optimize each design, ensuring maximum flexural stiffness. Designs using optimal pin position, optimal pin angle and optimal values for both parameters are herein investigated using numerical and experimental approaches. The optimal pin position yielded an increase in flexural stiffness of around 8.0% when compared to the non-optimized design. In this same comparison, the optimal pin angle by itself increased the flexural stiffness by about 63.0%. Besides, the highest increase in the maximum load was found for those composites, molded with optimized levels of pin position and pin angle, which synergistically contributed to this result. All results were demonstrated with numerical and experimental results and there was a good agreement between them.

Vermiculite Filler Modified with Casein, Chitosan, and Potato Protein as a Flame Retardant for Polyurethane Foams.

In this study, polyurethane (PU) composite foams were modified with 2 wt.% of vermiculite fillers, which were themselves modified with casein, chitosan, and potato protein. The impact of the fillers on selected properties of the obtained composites, including their rheological (foaming behavior, dynamic viscosity), thermal (temperature of thermal decomposition stages), flame-retardant (e.g., limiting oxygen index, ignition time, heat peak release), and mechanical properties (toughness, compressive strength (parallel and perpendicular), flexural strength) were investigated. Among all the modified polyurethane composites, the greatest improvement was noticed in the PU foams filled with vermiculite modified with casein and chitosan. For example, after the addition of modified vermiculite fillers, the foams' compressive strength was enhanced by ~6-18%, their flexural strength by ~2-10%, and their toughness by ~1-5%. Most importantly, the polyurethane composites filled with vermiculite filler and modified vermiculite fillers exhibited improved flame resistance characteristics (the value of total smoke release was reduced by ~34%, the value of peak heat release was reduced by ~25%).

Evaluation of the Performance of Bio-Based Rigid Polyurethane Foam with High Amounts of Sunflower Press Cake Particles.

In the current study, rigid polyurethane foam (PUR) was modified with 10-30 wt.% sunflower press cake (SFP) filler, and its effect on performance characteristics-i.e., rheology, characteristic foaming times, apparent density, thermal conductivity, compressive strength parallel and perpendicular to the foaming directions, tensile strength, and short-term water absorption by partial immersion-was evaluated. Microstructural and statistical analyses were implemented as well. During the study, it was determined that 10-20 wt.% SFP filler showed the greatest positive impact. For instance, the thermal conductivity value improved by 9% and 17%, respectively, while mechanical performance, i.e., compressive strength, increased by 11% and 28% in the perpendicular direction and by 43% and 67% in the parallel direction. Moreover, tensile strength showed 49% and 61% increments, respectively, at 10 wt.% and 20 wt.% SFP filler. Most importantly, SFP filler-modified PUR foams were characterised by two times lower water absorption values and improved microstructures with a reduced average cell size and increased content in closed cells.

Bio-Based Rigid Polyurethane Foam Composites Reinforced with Bleached Curauá Fiber.

This study aims to evaluate the influence of using a bleached Curauá fiber (CF) as filler in a novel rigid polyurethane foam (RPUF) composite. The influence of 0.1, 0.5 and 1 wt.% of the reinforcements on the processing characteristics, cellular structure, mechanical, dynamic-mechanical, thermal, and flame behaviors were assessed and discussed for RPUF freely expanded. The results showed that the use of 0.5 wt.% of CF resulted in RPUF with smoother cell structure with low differences on the processing times and viscosity for the filled pre-polyol. These morphological features were responsible for the gains in mechanical properties, in both parallel and perpendicular rise directions, and better viscoelastic characteristics. Despite the gains, higher thermal conductivity and lower flammability were reported for the developed RPUF composites, related to the high content of cellulose and hemicellulose on the bleached CF chemical composition. This work shows the possibility of using a Brazilian vegetable fiber, with low exploration for the manufacturing of composite materials with improved properties. The developed RPUF presents high applicability as enhanced cores for the manufacturing of structural sandwich panels, mainly used in civil, aircraft, and marine industries.

Vacuum-Based Impregnation of Liquid Glass into Sunflower Press Cake Particles and Their Use in Bio-Based Rigid Polyurethane Foam.

The study analyses rigid polyurethane (PUR) foam modified with 10-30 wt.% sunflower press cake (SFP) and liquid glass-impregnated sunflower press cake (LG-SFP) particles and their impact on performance characteristics of PUR foams-foaming behaviour, rheology, thermal conductivity, compressive strength parallel and perpendicular to the foaming directions, tensile strength, dimensional stability, short-term water absorption by partial immersion, and thermal stability. Even though the dynamic viscosity and apparent density were increased for SFP and LG-SFP formulations, thermal conductivity values improved by 17% and 10%, respectively, when 30 wt.% of particles were incorporated. The addition of SFP and LG-SFP particles resulted in the formation of more structurally and dimensionally stable PUR foams with a smaller average cell size and a greater content of closed cells. At 30 wt.% of SFP and LG-SFP particles, compressive strength increased by 114% and 46% in the perpendicular direction, respectively, and by 71% and 67% in the parallel direction, respectively, while tensile strength showed an 89% and 85% higher performance at 30 wt.% SFP and LG-SFP particles loading. Furthermore, short-term water absorption for all SFP and LG-SFP modified PUR foam formulations was almost two times lower compared to the control foam. SFP particles reduced the thermal stability of modified PUR foams, but LG-SFP particles shifted the thermal decomposition temperatures towards higher ones.

Casein/Apricot Filler in the Production of Flame-Retardant Polyurethane Composites.

Polyurethane (PUR) composites reinforced with 1, 2, and 5 wt.% of apricot filler modified with casein were synthesized in the following study. The impact of 1, 2, and 5 wt.% of casein/apricot filler on the cellular structure and physico-mechanical performances of reinforced PUR composites were determined. It was found that the incorporation of 1 and 2 wt.% of casein/apricot filler resulted in the production of PUR composites with improved selected physical, thermal, and mechanical properties, while the addition of 5 wt.% of casein/apricot filler led to some deterioration of their physico-mechanical performance. The best results were obtained for PUR composites reinforced with 2 wt.% of casein/apricot filler. Those composites were characterized by a uniform structure and a high content of closed cells. Compared with the reference foam, the incorporation of 2 wt.% of casein/apricot filler resulted in improvement in compressive strength, flexural strength, impact strength, and dynamic mechanical properties-such as glass transition temperature and storage modulus. Most importantly, PUR composites showed better fire resistance and thermal stability due to the good thermal performance of casein. The main aim of this article is to determine the influence of the natural combination of the apricot filler and casein on the mechanical properties and flammability of the obtained composites.

Chlorine-Functional Silsesquioxanes (POSS-Cl) as Effective Flame Retardants and Reinforcing Additives for Rigid Polyurethane Foams.

The subject of the research was the production of silsesquioxane modified rigid polyurethane (PUR) foams (POSS-Cl) with chlorine functional groups (chlorobenzyl, chloropropyl, chlorobenzylethyl) characterized by reduced flammability. The foams were prepared in a one-step additive polymerization reaction of isocyanates with polyols, and the POSS modifier was added to the reaction system in an amount of 2 wt.% polyol. The influence of POSS was analyzed by performing a series of tests, such as determination of the kinetics of foam growth, determination of apparent density, and structure analysis. Compressive strength, three-point bending strength, hardness, and shape stability at reduced and elevated temperatures were tested, and the hydrophobicity of the surface was determined. The most important measurement was the determination of the thermal stability (TGA) and the flammability of the modified systems using a cone calorimeter. The obtained results, after comparing with the results for unmodified foam, showed a large influence of POSS modifiers on the functional properties, especially thermal and fire-retardant, of the obtained PUR-POSS-Cl systems.

Polyurethane Composites Reinforced with Walnut Shell Filler Treated with Perlite, Montmorillonite and Halloysite.

In the following study, polyurethane (PUR) composites were modified with 2 wt.% of walnut shell filler modified with selected mineral compounds-perlite, montmorillonite, and halloysite. The impact of modified walnut shell fillers on selected properties of PUR composites, such as rheological properties (dynamic viscosity, foaming behavior), mechanical properties (compressive strength, flexural strength, impact strength), dynamic-mechanical behavior (glass transition temperature, storage modulus), insulation properties (thermal conductivity), thermal characteristic (temperature of thermal decomposition stages), and flame retardant properties (e.g., ignition time, limiting oxygen index, heat peak release) was investigated. Among all modified types of PUR composites, the greatest improvement was observed for PUR composites filled with walnut shell filler functionalized with halloysite. For example, on the addition of such modified walnut shell filler, the compressive strength was enhanced by ~13%, flexural strength by ~12%, and impact strength by ~14%. Due to the functionalization of walnut shell filler with thermally stable flame retardant compounds, such modified PUR composites were characterized by higher temperatures of thermal decomposition. Most importantly, PUR composites filled with flame retardant compounds exhibited improved flame resistance characteristics-in all cases, the value of peak heat release was reduced by ~12%, while the value of total smoke release was reduced by ~23%.

Biobased Polyurethane Composite Foams Reinforced with Plum Stones and Silanized Plum Stones.

In the following study, ground plum stones and silanized ground plum stones were used as natural fillers for novel polyurethane (PUR) composite foams. The impact of 1, 2, and 5 wt.% of fillers on the cellular structure, foaming parameters, and mechanical, thermomechanical, and thermal properties of produced foams were assessed. The results showed that the silanization process leads to acquiring fillers with a smoother surface compared to unmodified filler. The results also showed that the morphology of the obtained materials is affected by the type and content of filler. Moreover, the modified PUR foams showed improved properties. For example, compared with the reference foam (PUR_REF), the foam with the addition of 1 wt.% of unmodified plum filler showed better mechanical properties, such as higher compressive strength (~8% improvement) and better flexural strength (~6% improvement). The addition of silanized plum filler improved the thermal stability and hydrophobic character of PUR foams. This work shows the relationship between the mechanical, thermal, and application properties of the obtained PUR composites depending on the modification of the filler used during synthesis.

Effects of Physical and Chemical Modification of Sunflower Cake on Polyurethane Composite Foam Properties.

Sunflower cake (SC), which is waste during the production of sunflower oil, was selected as a modifier of properties in polyurethane (PUR) foams. The SC was chemically modified with triphenylsilanol (SC_S) and physically modified with rapeseed oil (SC_O). The influence of SC on the rheological properties of the polyol and the kinetics of foam growth were investigated. PUR foams were characterized by morphological, mechanical, and thermal analysis. The results show that the physical and chemical modification of SC contributes to the changes in the properties of the foams in different ways. Too high hydrophobicity of SC_O affects the structure deterioration, and thus the mechanical properties, and in turn, reduces the affinity for water. In turn, chemical modification with silane allows for obtaining foams with the best mechanical properties.

Mechanically Strong Polyurethane Composites Reinforced with Montmorillonite-Modified Sage Filler (Salvia officinalis L.).

Rigid polyurethane (PUR) foams reinforced with 1, 2, and 5 wt.% of salvia filler (SO filler) and montmorillonite-modified salvia filler (MMT-modified SO filler) were produced in the following study. The impact of 1, 2, and 5 wt.% of SO filler and MMT-modified SO filler on the morphological, chemical, and mechanical properties of PUR composites were examined. In both cases, the addition of 1 and 2 wt.% of SO fillers resulted in the synthesis of PUR composites with improved physicomechanical properties, while the addition of 5 wt.% of SO fillers resulted in the formation of PUR composites with a less uniform structure and, therefore, some deterioration in their physicomechanical performances. Moreover, the results showed that the modification of SO filler with MMT improved the interphase compatibility between filler surface and PUR matrix. Therefore, such reinforced PUR composites were characterized by a well-developed closed-cell structure and improved mechanical, thermal, and flame-retardant performances. For example, when compared with reference foam, the addition of 2 wt.% of MMT-modified SO filler resulted in the formation of PUR composites with greater mechanical properties (compressive strength, flexural strength) and improved dynamic-mechanical properties (storage modulus). The PUR composites were characterized by better thermal stability as well as improved flame retardancy-e.g., decreased peak rate of heat release (pHRR), reduced total smoke release (TSR), and increased limiting oxygen index (LOI).

Coir Fibers Treated with Henna as a Potential Reinforcing Filler in the Synthesis of Polyurethane Composites.

In this study, coir fibers were successfully modified with henna (derived from the Lawsonia inermis plant) using a high-energy ball-milling process. In the next step, such developed filler was used as a reinforcing filler in the production of rigid polyurethane (PUR) foams. The impact of 1, 2, and 5 wt % of coir-fiber filler on structural and physico-mechanical properties was evaluated. Among all modified series of PUR composites, the greatest improvement in physico-mechanical performances was observed for PUR composites reinforced with 1 wt % of the coir-fiber filler. For example, on the addition of 1 wt % of coir-fiber filler, the compression strength was improved by 23%, while the flexural strength increased by 9%. Similar dependence was observed in the case of dynamic-mechanical properties-on the addition of 1 wt % of the filler, the value of glass transition temperature increased from 149 °C to 178 °C, while the value of storage modulus increased by ~80%. It was found that PUR composites reinforced with coir-fiber filler were characterized by better mechanical performances after the UV-aging.