ABSTRACT
Redox flow batteries (RFB) are one of the most interesting technologies in the field of energy storage, since they allow the decoupling of power and capacity. Zinc-bromine flow batteries (ZBFB) are a type of hybrid RFB, as the capacity depends on the effective area of the negative electrode (anode), on which metallic zinc is deposited during the charging process. Gaseous bromine is generated at the positive electrode (cathode) during the charging process, so the use of bromine complexing agents (BCA) is very important. These BCAs are quaternary amines capable of complexation with bromine and generating an organic phase, immiscible with the aqueous electrolyte. One of the most commonly used BCAs in RFB technology is 4-methylethylmorpholinium bromide (MEM-Br). In this work, an alternative quaternary amine 4-methylpropylmorpholinium bromide (MPM-Br) was studied. MPM-Br was integrated into the electrolyte, and 200 charge-discharge cycles were performed on the resulting ZBFBs. The obtained results were compared with those when MEM-Br was used, and it was observed that the electrolyte with MPM-Br displays a higher resistance in voltage and higher energy efficiency, making it a promising alternative to MEM-Br.
Subject(s)
Bromides/chemistry , Electric Power Supplies , Electrodes , Hydrocarbons, Brominated/chemistry , Zinc/chemistry , Oxidation-ReductionABSTRACT
This paper presents a software platform to compute the total water level, one of the key variables for the environmental management of coastal zones. The platform integrates six modules: (1) simulation of deep-water wave variables, storm surge and river flow; (2) wave downscaling; (3) wave propagation; (4) contribution of the river discharge; (5) astronomical tide; and (6) total water level. It was applied to three case studies in southern Spain. The first case study consisted of designing the extension of a fluvial marina in a highly dynamic area (Guadalete estuary, Cádiz), and the maximum number of floating docks to avoid flooding events was obtained. The second case study involved calculating the operation conditions for navigation purposes in an inlet with sedimentation problems (Punta Umbría, Huelva), and a relationship between the percentage of operation hours and the dredged volume was obtained. The third case study consisted of estimating the number of overwash events as a function of the height of the berm on a deltaic beach with erosion issues (Guadalfeo, Granada), and a simple design curve to help managers during the decision-making process of artificial nourishment projects was provided. These results highlight the potential of the developed software, whose methodology is feasibly extensible to other coastal areas worldwide, to help managers handle a wide range of environmental problems related to the total water level. This is especially relevant due to the expected sea level rise in the coming years.
ABSTRACT
Three different lignin-rich fractions have been used as binder material for electrodes in rechargeable lithium batteries. Lignin samples were obtained through three different pulping processes; kraft, soda and organosolv pulping processes, using wheat straw as raw material. Physico-chemical characterization of three types of lignins was evaluated. Characterization has been performed using Fourier transform infrared spectroscopy (FTIR) and 31P NMR Spectroscopy to analyse the functional groups; gel permeation chromatography (GPC) for determining molar mass distribution (MWD), and thermogravimetric analysis (TGA) to follow the thermal behaviour. Electrodes containing lignin or poly vinylidene fluoride (PVDF) were tested electrochemically. The three different lignin samples exhibited excellent performance as binder, retaining the specific capacity after 50 cycles at a current density of 100mAg-1. These results show that lignin could be used as a low-cost and environmental binder, replacing the PVDF polymer in electrodes for energy storage applications.
