Microbial and thermal treatment techniques for degradation of PFAS in biosolids: A focus on degradation mechanisms and pathways.

Per- and polyfluoroalkyl substances (PFAS) are persistent organic chemicals detected in biosolids worldwide, which have become a significant concern for biosolids applications due to their increasing environmental risks. Hence, it is pivotal to understand the magnitude of PFAS contamination in biosolids and implement effective technologies to reduce their contamination and prevent hazardous aftermaths. Thermal techniques such as pyrolysis, incineration and gasification, and biodegradation have been regarded as impactful solutions to degrade PFAS and transform biosolids into value-added products like biochar. These techniques can mineralize PFAS compounds under specific operating parameters, which can lead to unique degradation mechanisms and pathways. Understanding PFAS degradation mechanisms can pave the way to design the technology and to optimize the process conditions. Therefore, in this review, we aim to review and compare PFAS degradation mechanisms in thermal treatment like pyrolysis, incineration, gasification, smouldering combustion, hydrothermal liquefaction (HTL), and biodegradation. For instance, in biodegradation of perfluorooctane sulfonic acid (PFOS), firstly C-S bond cleavage occurs which is followed by hydroxylation, decarboxylation and defluorination reactions to form perfluoroheptanoic acid. In HTL, PFOS degradation is carried through OH-catalyzed series of nucleophilic substitution and decarboxylation reactions. In contrast, thermal PFOS degradation involves a three-step random-chain scission pathway. The first step includes C-S bond cleavage, followed by defluorination of perfluoroalkyl radical, and radical chain propagation reactions. Finally, the termination of chain propagation reactions produces very short-fluorinated units. We also highlighted important policies and strategies employed worldwide to curb PFAS contamination in biosolids.

Thermo-catalytic co-pyrolysis of ironbark sawdust and plastic waste over strontium loaded hierarchical Y-zeolite.

The objective of this research is to synthesize hierarchical strontium loaded Y-zeolite and study its application for ironbark (IB) and plastic waste (PW) co-pyrolysis. Commercial parent Y-zeolite (Si/Al = 2.48) was modified via sequential dealumination-desilication using citric acid and NaOH. Further, strontium (8 wt %) was loaded into the modified Y-zeolite via wet and dry impregnation methods. The prepared catalyst was characterized by N2 adsorption-desorption isothermal, field emission scanning electron microscopy (FESEM) combined with energy dispersive x-ray spectroscopy (EDS), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and Thermogravimetric analyzer (TGA). After dealumination (treatment using 0.1 M of citric acid), the external surface area and Si/Al ratio increased from 53.5 to 147.4 m2/g and 2.48 to 5.36, respectively. However, the sequential desilication treatment reduced Si/Al ratio from 5.36 to 2.57. In addition, Y-zeolite enhanced the total aromatic percentage and reduced the acidic group in co-pyrolysis oil.