Photoelectrocatalysis on TiO2 meshes: different applications in the integrated urban water management.

Recently, among AOPs, photoelectrocatalysis (PEC) on TiO2 is gaining interest. In this study, five different real waters sampled in four different points of the integrated urban water management (IUWM) system were tested with PEC and UV alone, for comparison. This work aims to verify the effect of the PEC suggesting the optimal position in IUWM system where the PEC should be located to obtain the best performance. In groundwaters (GWs), PEC effectively removed atrazine-based compounds (> 99%), trichloroethylene, and perchloroethylene (96%), after 15 min of reaction time. However, given the low concentrations of emerging compounds, the synergistic effect of UV radiation with the catalyst and with the polarization of the mesh was not visible, with very few differences compared with the results obtained with UV alone. Pharmaceutical industrial wastewater (IWW) showed a significant increase in biodegradability after 2 h, both if subjected to PEC or UV (200%), despite the absence of COD removal. The PEC applied on IWW from a sewage sludge treatment plant allowed to effectively remove the COD (39.6%) and increase the biodegradability (300%). Good results in terms of COD removal (33.9%) and biodegradability increase (+900%) were also achieved testing PEC on wastewater treatment plant effluent. Except for GWs, PEC allowed significant EEO savings respect to UV alone (76.2-99.1%).

Treatments for color removal from wastewater: State of the art.

It is evident from many recent papers that release of colored wastewater into the environment is source of pollution and this is a problem that particularly affect textile, dyeing and food industries. The review: (i) presents an analysis of various mechanisms involved in the different processes for color removal; (ii) describes conveniences and disadvantages that may exist in adopting one type of treatment in spite of another; (iii) reports the results of approximately 180 experimental tests. Both examples of treatments already widely applied to the real scale and still in the experimental phase are reported. This work focuses on different types of chemical/physical, chemical, electrochemical and biological processes applied in the field of color removal from industrial wastewater. Common chemical/physical treatments such as coagulation/flocculation, adsorption and membrane filtration as well as chemical-type processes are discussed, both those that exploit the traditional oxidizing chemical agents such as Ozone, H2O2 and reactive based on chlorine and those based on the principle of advanced chemical oxidation. In particular, both Hydroxyl radical based Advanced Oxidation Processes (AOPs) and Sulfate radical based AOPs are reported. The most commonly used Electrochemical processes for the removal of color are also presented as well as biological treatments. Based on more than 200 papers, this review provides important information on the use, effectiveness, advantages and downsides of the various treatments aimed at removing the color from the wastewater with a look at the technologies still under development.

Process auditing and performance improvement in a mixed wastewater-aqueous waste treatment plant.

The wastewater treatment process is based on complex chemical, physical and biological mechanisms that are closely interconnected. The efficiency of the system (which depends on compliance with national regulations on wastewater quality) can be achieved through the use of tools such as monitoring, that is the detection of parameters that allow the continuous interpretation of the current situation, and experimental tests, which allow the measurement of real performance (of a sector, a single treatment or equipment) and comparison with the following ones. Experimental tests have a particular relevance in the case of municipal wastewater treatment plants fed with a strong industrial component and especially in the case of plants authorized to treat aqueous waste. In this paper a case study is presented where the application of management tools such as careful monitoring and experimental tests led to the technical and economic optimization of the plant: the main results obtained were the reduction of sludge production (from 4,000 t/year w.w. (wet weight) to about 2,200 t/year w.w.) and operating costs (e.g. from 600,000 €/year down to about 350,000 €/year for reagents), the increase of resource recovery and the improvement of the overall process performance.