ABSTRACT
Efficient and reliable energy storage systems are necessary to address the intermittency and variability of renewable energy sources. Thermochemical energy storage (TCES) has emerged as a promising solution for long-term renewable energy storage, with limestone being a widely studied material due to its abundance and high energy density. However, the practical implementation of limestone-based TCES systems faces challenges related to performance degradation upon multiple energy storage/release cycles, impacting their long-term viability and efficiency. In this study, we investigate the activity of Ca2Fe2O5 additives on the thermochemical energy storage performance of limestone waste. Ca2Fe2O5 additives were synthesized by a wet precipitation method using three different Ca/Fe molar ratios and added to limestone waste in a 5, 10, and 20 weight concentration. The synthesized samples were characterized using XRD, SEM, EDS, BET, and XPS techniques. The thermal properties and heat storage performance of the samples were evaluated through thermogravimetric analysis of calcination/carbonation cycling experiments. The results demonstrate the potential of Ca2Fe2O5 additives to improve the cycling stability and energy storage density of limestone-based TCES systems. The sample with 5 wt% of Ca2Fe2O5 additive having Ca : Fe molar ratio of 1 : 1 outperformed all samples with an effective conversion rate of 0.21 after 40 cycles, 1.31 times higher than limestone waste.
ABSTRACT
C. vulgaris microalgae biomass was employed for the extraction of valuable bioactive compounds with deep eutectic-based solvents (DESs). Particularly, the Choline Chloride (ChCl) based DESs, ChCl:1,2 butanediol (1:4), ChCl:ethylene glycol (1:2), and ChCl:glycerol (1:2) mixed with water at 70/30 w/w ratio were used for that purpose. The extracts' total carotenoid (TCC) and phenolic contents (TPC), as well as their antioxidant activity (IC50), were determined within the process of identification of the most efficient solvent. This screening procedure revealed ChCl:1,2 butanediol (1:4)/H2O 70/30 w/w as the most compelling solvent; thus, it was employed thereafter for the extraction process optimization. Three extraction parameters, i.e., solvent-to-biomass ratio, temperature, and time were studied regarding their impact on the extract's TCC, TPC, and IC50. For the experimental design and process optimization, the statistical tool Response Surface Methodology was used. The resulting models' predictive capacity was confirmed experimentally by carrying out two additional extractions under conditions different from the experimental design.
Subject(s)
Deep Eutectic Solvents , Water , Biomass , Solvents , Butylene Glycols , CholineABSTRACT
Harvesting of microalgae is a crucial step in microalgae-based mass production of different high value-added products. In the present work, magnetic harvesting of Chlorella vulgaris was investigated using microwave-synthesized naked magnetite (Fe3O4) particles with an average crystallite diameter of 20 nm. Optimization of the most important parameters of the magnetic harvesting process, namely pH, mass ratio (mr) of magnetite particles to biomass (g/g), and agitation speed (rpm) of the C. vulgaris biomass-Fe3O4 particles mixture, was performed using the response surface methodology (RSM) statistical tool. Harvesting efficiencies higher than 99% were obtained for pH 3.0 and mixing speed greater or equal to 350 rpm. Recovery of magnetic particles via detachment was shown to be feasible and the recovery particles could be reused at least five times with high harvesting efficiency. Consequently, the described harvesting approach of C. vulgaris cells leads to an efficient, simple, and quick process, that does not impair the quality of the harvested biomass.
