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Org Lett ; 15(7): 1780-3, 2013 Apr 05.
Article in English | MEDLINE | ID: mdl-23527827

ABSTRACT

A convenient method for preparing attractively functionalized 1,4-diketones has been devised by palladium-catalyzed cross-coupling of cyclopropanols and acyl chlorides. The utility of this method has been demonstrated in an enantioselective synthesis of (+)-myrmicarin 217.


Subject(s)
Ethers, Cyclic/chemistry , Heterocyclic Compounds, 3-Ring/chemical synthesis , Ketones/chemical synthesis , Palladium/chemistry , Acylation , Catalysis , Heterocyclic Compounds, 3-Ring/chemistry , Ketones/chemistry , Molecular Structure , Stereoisomerism
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