Electron Beam Induced Circularly Polarized Light Emission of Chiral Gold Nanohelices.

Chiral plasmonic nanostructures possess a chiroptical response orders of magnitude stronger than that of natural biomolecular systems, making them highly promising for a wide range of biochemical, medical, and physical applications. Despite extensive efforts to artificially create and tune the chiroptical properties of chiral nanostructures through compositional and geometrical modifications, a fundamental understanding of their underlying mechanisms remains limited. In this study, we present a comprehensive investigation of individual gold nanohelices by using advanced analytical electron microscopy techniques. Our results, as determined by angle-resolved cathodoluminescence polarimetry measurements, reveal a strong correlation between the circular polarization state of the emitted far-field radiation and the handedness of the chiral nanostructure in terms of both its dominant circularity and directional intensity distribution. Further analyses, including electron energy-loss measurements and numerical simulations, demonstrate that this correlation is driven by longitudinal plasmonic modes that oscillate along the helical windings, much like straight nanorods of equal strength and length. However, due to the three-dimensional shape of the structures, these longitudinal modes induce dipolar transverse modes with charge oscillations along the short axis of the helices for certain resonance energies. Their radiative decay leads to observed emission in the visible range. Our findings provide insight into the radiative properties and underlying mechanisms of chiral plasmonic nanostructures and enable their future development and application in a wide range of fields, such as nano-optics, metamaterials, molecular physics, biochemistry, and, most promising, chiral sensing via plasmonically enhanced chiral optical spectroscopy techniques.

Spin-orbit interactions in plasmonic crystals probed by site-selective cathodoluminescence spectroscopy.

The study of spin-orbit coupling (SOC) of light is crucial to explore the light-matter interactions in sub-wavelength structures. By designing a plasmonic lattice with chiral configuration that provides parallel angular momentum and spin components, one can trigger the strength of the SOC phenomena in photonic or plasmonic crystals. Herein, we explore the SOC in a plasmonic crystal, both theoretically and experimentally. Cathodoluminescence (CL) spectroscopy combined with the numerically calculated photonic band structure reveals an energy band splitting that is ascribed to the peculiar spin-orbit interaction of light in the proposed plasmonic crystal. Moreover, we exploit angle-resolved CL and dark-field polarimetry to demonstrate circular-polarization-dependent scattering of surface plasmon waves interacting with the plasmonic crystal. This further confirms that the scattering direction of a given polarization is determined by the transverse spin angular momentum inherently carried by the SP wave, which is in turn locked to the direction of SP propagation. We further propose an interaction Hamiltonian based on axion electrodynamics that underpins the degeneracy breaking of the surface plasmons due to the spin-orbit interaction of light. Our study gives insight into the design of novel plasmonic devices with polarization-dependent directionality of the Bloch plasmons. We expect spin-orbit interactions in plasmonics will find much more scientific interests and potential applications with the continuous development of nanofabrication methodologies and uncovering new aspects of spin-orbit interactions.

Using type-2 fuzzy ontology to improve semantic interoperability for healthcare and diagnosis of depression.

Ontology enhances semantic interoperability through integrating health data from heterogeneous sources and sharing information in a meaningful way. In the field of smart health services, semantic interoperability means the exchange and interpretation of data without ambiguity and uncertainty. However, existing classical ontologies are not able to represent vague and uncertain knowledge, especially in contexts of mental health disorders which are associated with varying degrees of uncertainty and inaccuracy of diagnosis, and in this case, the treatment is a complex and common mental process necessitating to share information accurately and unambiguously. Type-2 fuzzy set theory can offer a fruitful solution in order to control uncertainty or express ambiguous concepts in a dynamic and complex environment such as healthcare systems. Herein, a semantic framework for healthcare, and also monitoring mental health disorders using type-2 fuzzy set theory based on the Internet of Thing (IoT) is suggested, in which all depression-related concepts are semantically annotated to share detailed information with the treatment staff. This framework not only paved the way to increasing the accuracy of medical diagnosis and decision-making but also provides the possibility of inference and semantic reasoning using the languages of SPARQL query and DL query.

Topological photonics by breaking the degeneracy of line node singularities in semimetal-like photonic crystals.

Degeneracy is an omnipresent phenomenon in various physical systems, which has its roots in the preservation of geometrical symmetry. In electronic and photonic crystal systems, very often this degeneracy can be broken by virtue of strong interactions between photonic modes of the same energy, where the level repulsion and the hybridization between modes causes the emergence of photonic bandgaps. However, most often this phenomenon does not lead to a complete and inverted bandgap formation over the entire Brillouin zone. Here, by systematically breaking the symmetry of a two-dimensional square photonic crystal, we investigate the formation of Dirac points, line node singularities, and inverted bandgaps. The formation of this complete bandgap is due to the level repulsion between degenerate modes along the line nodes of a semimetal-like photonic crystal, over the entire Brillouin zone. Our numerical experiments are performed by a home-build numerical framework based on a multigrid finite element method. The developed numerical toolbox and our observations pave the way towards designing complete bandgap photonic crystals and exploring the role of symmetry on the optical behaviour of even more complicated orders in photonic crystal systems.

Mapping optical Bloch modes of a plasmonic square lattice in real and reciprocal spaces using cathodoluminescence spectroscopy.

Strong electron-light interactions supported by the surface plasmon polaritons excited in metallic thin films can lead to faster optoelectronic devices. Merging surface polaritons with photonic crystals leads to the formation of Bloch plasmons, allowing for the molding of the flow of polaritons and the controlling of the optical density of states for even stronger electron-light interactions. Here, we use a two-dimensional square lattice of holes incorporated inside a plasmonic gold layer to investigate the interaction of surface plasmon polaritons with the square lattice and the formation of plasmonic Bloch modes. Cathodoluminescence spectroscopy and hyperspectral imaging are used for imaging the spatio-spectral near-field distribution of the optical Bloch modes in the visible to near infrared spectral ranges. In addition, the higher-order Brillouin zones of the plasmonic lattice are demonstrated by using angle-resolved cathodoluminescence mapping. We further complement our experimental results with numerical simulations of the optical modes supported by the plasmonic lattice that helps to better resolve the superposition of the various modes excited by the electron beam. Next to previous works in this context, our results thus place cathodoluminescence scanning spectroscopy and angle-resolved mapping as complementary techniques to uncover the spatio-spectral distribution of optical Bloch modes in real and reciprocal spaces.

Near-infrared absorbers based on the heterostructures of two-dimensional materials.

Although the conductance and dielectric function of graphene can be tuned by applying external voltage, the tunability is less than 3%. Hybridizing graphene with other two-dimensional transition metal dichalcogenides (TMDs) can improve the adjustability and tunability of the optical properties of graphene-based structures at near-infrared frequencies. In this paper, we theoretically compute the dielectric function of graphene-MoTe2-graphene and graphene-MoTe2-graphene heterostructures utilizing the quantum electrostatic heterostructure (QEH) model, which is an ab-initio method. Utilizing the QEH results, we propose a hyper crystal (HC) absorber at near-infrared frequencies. Hence, we use the transfer matrix method to investigate our proposed absorber analytically. Moreover, we simulate the graphene-TMD-graphene (G-TMD-G) absorbers by the numerical finite difference time domain method. The results of the numerical solution are consistent with those of the analytical method. Due to the dependency of the Fermi level of graphene on the direct bandgap of the TMDs, the dielectric function of the G-TMD-G heterostructure can be tuned and enhanced further by changing the number of TMD layers. Finally, we demonstrate that the full absorption of the heterostructures can be achieved at different frequencies for transverse magnetic polarization. Since the thicknesses of the layers in the HC are lower than the wavelength of the light, no diffracted bands are ubiquitous, and the absorption can be observed for a wide range of incidence angles and bandwidths at near-infrared frequencies. Because of utilizing graphene-based HCs, in addition to the feasibility of design compared to the complex metasurfaces, the absorption bandwidth is significant for a wide range of incidence angles. This kind of HC absorber can be used in the design of sensitive optical devices, such as tunable filters, detectors, and photovoltaic applications.