ABSTRACT
High quality lidar measurements of PollyXT operating at the University of Warsaw in the years 2013-2022 were analyzed to present a comprehensive optical characterization of biomass burning aerosols over Warsaw. The directions of the aerosol inflows were analyzed by dividing advection cases into four types, according to the area of origin: Western Europe, Eastern Europe, the Iberian Peninsula, and North America. It was shown that optical properties of smoke vary in each of these types, and emphasized that aerosol aging processes are important. It was found that as aerosol's age increases, there is more backscattering and less extinction at 355â nm in relation to 532â nm. The analysis of the lidar ratio demonstrated that the main changes of the aging process were observed in the UV spectra.
ABSTRACT
The effects of air pollution on the general public received much attention recently. Personal exposure and deposition fraction of aerosol particles were studied in Vilnius, Lithuania, focusing on individuals working in an office and driving to work. Aerosol monitoring in the urban background was found to give an indication of the minimum concentrations of particulate matter (PM) expected at urban roads, as these correspond to the lowest PM concentrations measured there. In March 2021, PM2.5 concentrations at the urban background monitoring station reached values above the annual limit of 5 µg/m3 the World Health Organization in 50% of cases. Our study shows significant differences in exposure to air pollution in a car cabin and in a modern office. According to the multiple-path particle dosimetry model, the exposure of the person in the office is about 14 times lower than driving a car, where the minute deposition dose for PM1 is 0.072 µg/min for the period when the PM2.5 concentration in the urban background reaches 10 µg/m³. Compared to the PM2.5 mass concentration at the urban background station, the mean PM2.5 concentration in the vehicle reaches values that are 2-3 times higher. During the working day, when driving takes less than 10% of the time considered (commuting plus working), PM exposure during driving accounts for about 80% of the PM exposure caused by PM concentration in the office.
ABSTRACT
This study investigates potential influence of urban trees on black carbon (BC) removal by Norway spruce and silver birch along with the BC formation, mass concentration in air, and source apportionment. The main sources of BC in urban areas are transport, household and industry. BC concentrations monitored in urban background station in Vilnius (Lithuania) showed that biomass burning was a significant contributor to BC emissions even during warm period of the year. Therefore, BC emission levels were determined for the most common biomass fuels (mixed wood pellets, oak, ash, birch and spruce firewood) and two types of agro-biomass (triticale and rapeseed straw pellets) burned in modern and old heating systems. The highest emissions were obtained for biomass fuels especially birch firewood. BC aerosol particles produced by the condensation mechanism during the combustion processes were found in all samples taken from the leaf surface. The short-term effect of BC exposure on photosynthetic pigments (chlorophyll a and b; and carotenoids) in the foliage of one-year-old Norway spruce and silver birch seedlings was evaluated by the experiment carried out in the phytotron greenhouse. The seedlings showed different short-term responses to BC exposure. All treatments applied in the phytotron greenhouse resulted in lower chlorophyll content in spruce foliage compared to natural conditions but not differed for birch seedlings. However, the exposure of BC particles on the spruce and birch seedlings in the phytotron increased the content of photosynthetic pigments compared to the control seedlings in the phytotron. Overall, urban trees can help improve air quality by reducing BC levels through dry deposition on tree foliage, and needle-like trees are more efficient than broad-leaved trees in capturing BC. Nevertheless, a further study could assess the longer-term effects of BC particles on tree biochemical and chemical reactions.
