ABSTRACT
An update of spectroscopic line parameters for the 3.45-3.92 microm ozone bands is reported. The line list includes the parameters of 15 bands of the main isotopic species and of the v1+v2+v3 band of 16O16O18O and 16O18O16O. The results are based on previous high resolution laboratory studies. Comparisons of experimental spectra with an absorptance simulation of ozone based on the reported line list shows that the latter one is accurate enough for strong, medium, and weak transmittance in the 2550-2900 cm(-1) spectral range. The data are available on the Web in the Spectroscopy and Molecular Properties of Ozone (S&MPO, http://smpo.iao.ru and http://ozone.univ-reims.fr) and HITRAN (http://cfa-www.harvard.edu/hitran/) databanks.
ABSTRACT
Infrared spectra (0.003 cm(-1) resolution) of 16O16O18O and 16O18O18O ozone isotopologues have been recorded and analyzed in the range 600-5000 cm(-1). Several thousand rovibrational lines belonging to 32 absorption bands have been measured and assigned. An accurate determination of band centers through the rovibrational analysis has been done, 12 bands being observed for the first time to our knowledge. In addition to atmospheric retrieval applications, these results are also useful for a validation of potential energy surfaces and for the study of isotope effects in dynamic processes of ozone.
