ABSTRACT
Among microplastics (MPs), fibers are one of the most abundant shapes encountered in the aquatic environment. Growing attention is being focused on this typology of particles since they are considered an important form of marine contamination. Information about microfibers distribution in the Mediterranean Sea is still limited and the increasing evidence of the high amount of fibers in the aquatic environment should lead to a different classification from MPs which, by definition, are composed only of synthetic materials and not natural. In the past, cellulosic fibers (natural and regenerated) have been likely included in the synthetic realm by hundreds of studies, inflating "micro-plastic" counts in both environmental matrices and organisms. Comparisons are often hampered because many of the available studies have explicitly excluded the micro-fibers (MFs) content due, for example, to methodological problems. Considering the abundance of micro-fibers in the environment, a chemical composition analysis is fundamental for toxicological assessments. Overall, the results of this review work provide the basis to monitor and mitigate the impacts of microfiber pollution on the sea ecosystems in the Mediterranean Sea, which can be used to investigate other basins of the world for future risk assessment.
ABSTRACT
The terrestrial environment is an important contributor of microplastics (MPs) to the oceans. Urban streams, strictly interwoven in the city network and to the MPs' terrestrial source, have a relevant impact on the MP budget of large rivers and, in turn, marine areas. We investigated the fluxes (items/day) of MPs and natural fibers of Mugnone Creek, a small stream crossing the highly urbanized landscape of Florence (Italy) and ending in the Arno River (and eventually to the Tyrrhenian Sea). Measurements were done in dry and wet seasons for two years (2019-2020); stream sediments were also collected in 2019. The highest loads of anthropogenic particles were observed in the 2019 wet season (109 items/day) at the creek outlet. The number of items in sediments increased from upstream (500 items/kg) to urban sites (1540 items/kg). Fibers were the dominant shape class; they were mostly cellulosic in composition. Among synthetic items, fragments of butadiene-styrene (SBR), indicative of tire wear, were observed. Domestic wastewater discharge and vehicular traffic are important sources of pollution for Mugnone Creek, especially during rain events. The study of small creeks is of pivotal importance to limit the availability of MPs in the environment.
ABSTRACT
The presence of various heavy metal ions in the industrial waste waters has recently been a challenging issue for human health. Since heavy metals are highly soluble in the aquatic environments and they can be absorbed easily by living organisms, their removal is essential from the environmental point of view. Many studies have been devoted to investigating the environmental behaviour of graphene-based nanomaterials as sorbent agents to remove metals from wastewaters arising by galvanic industries. Among the graphene derivates, especially graphene oxide (GO), due to its abundant oxygen functional groups, high specific area and hydrophilicity, is a high-efficient adsorbent for the removal of heavy and precious metals in aquatic environment. This paper reviews the main graphene, GO, functionalized GO and their composites and its applications in the metals removal process. The influencing factors, adsorption capacities and reuse capability are highlighted for the most extensively used heavy metals, including copper, zinc, nickel, chromium, cobalt and precious metals (i.e., gold, silver, platinum, palladium, rhodium, and ruthenium) in the electroplating process.
