How groundwater temperature is affected by climate change: A systematic review.

Groundwater (GW) is sensitive to climate change (CC), and the effects have become progressively more evident in recent years. Many studies have examined the effects of CC on GW quantity. Still, there is growing interest in assessing the qualitative impacts of CC, especially on GW temperature (GWT), and the consequences of these impacts. This study aimed to systematically review recently published papers on CC and GWT, determine the impacts of CC on GWT, and highlight the possible consequences. The Scopus and Web of Science databases were consulted, from which 144 papers were obtained. After an initial screening for duplicate papers, a second screening based on the titles and abstracts, and following an analysis of topic applicability to this subject after examining the full text, 44 studies were included in this review. The analysed scientific literature, published in 29 different journals, covered all five continents from 1995 to 2023. This review indicated that the subject of GWT variations due to CC is of global interest and has attracted significant attention, especially over the past two decades, with many studies adopting a multidisciplinary approach. A general increase in GWT was noted as a primary effect of CC (especially in urban areas); furthermore, the implications of this temperature increase for contaminants and GW-dependent ecosystems were analysed, and various applications for this increase (e.g. geothermal) were evaluated. This review highlights that GWT is vulnerable to CC and that the consequences can be serious and worthy of further investigation.

Mobility of crocidolite asbestos in sandy porous media mimicking aquifer systems.

Asbestos is widely recognized as being a carcinogen when dispersed in air, but very little is known about its exposure pathways in water and its subsequent effects on human health. Several studies have proved asbestos presence in groundwater but failed to assess its mobility in aquifer systems. This paper aims to fill this gap by studying the transport of crocidolite, an amphibole asbestos, through sandy porous media mimicking different aquifer systems. To this purpose, two sets of column test were performed varying the crocidolite suspension concentration, the quartz sand grain size distribution, and the physicochemical water parameters (i.e., pH). The results proved that crocidolite is mobile in quartz sand due to the repulsive interactions between fibres and porous media. The concentration of fibres at the outlet of the column were found to decrease when decreasing the grain size distribution of the porous medium, with a bigger impact on highly concentrated suspensions. In particular, 5-to-10-µm-long fibres were able to flow through all the tested sands while fibres longer than 10 µm were mobile only through the coarser medium. These results confirm that groundwater migration should be considered a potential exposure pathway while implementing human health risk assessment.

Application and comparison of different statistical methods for the analysis of groundwater levels over time: Response to rainfall and resource evolution in the Piedmont Plain (NW Italy).

Monitoring and analysis of groundwater level (GWL) in space and time is one of the tools used to evaluate the quantitative status of groundwater (GW) resources and identify possible alterations and critical cases due to climate change and variability, anthropogenic influences and other driving factors. In this study, four statistical methodologies (trend, change-point, percentile and non-standardized anomaly analyses) were applied for GWL and rainfall (R) analysis in the Piedmont Plain (western Po Plain, NW Italy). To detect the interannual variations in the GW maximum annual amplitude, the coefficient of variation was also used. The aims of the study were 1) to compare the results of different statistical methods, highlighting their applicability and differences to evaluate the quantitative evolution of GW, 2) to identify the relationship between GWL and R, 3) to investigate the spatiotemporal variation in the GWL of shallow aquifers in the Piedmont Plain, and 4) to describe critical situations of GW depletion. The study highlights that the application of a single method for assessing the shallow GW resource status does not always guarantee a reliable evaluation. For this reason, it is advisable to apply different analysis methods at the same time. Completeness of data and medium to long time series are prerequisites for meaningful analyses. The use of the same time interval is always necessary for comparisons between different monitoring wells and between the results of different statistical analyses. Last, by spatializing the results, it was possible to identify areas characterized by similar GWL behaviour due to hydrological structure, climate variability, land use and the evolution of anthropogenic activities over time. These factors influence vary locally in the Piedmont plain and require local assessments to determine the impact of changes in GWL.

Temperature and discharge variations in natural mineral water springs due to climate variability: a case study in the Piedmont Alps (NW Italy).

In the context of global climate change, understanding the relationships between climate and groundwater is increasingly important. This study in the NW Alps represents the first regional-scale investigation of the groundwater feature variation in mountain aquifers due to climate variability. The analysis of groundwater temperature and discharge in 28 natural mineral water springs and meteorological parameters (rainfall and air temperature) permitted us to evaluate the annual behaviour and possible trends of these parameters during the period from 2001 to 2018. The air temperature showed a positive trend almost everywhere, with a rise of up to 0.03 °C/year. In contrast, only ten springs showed a positive trend for groundwater temperature, but with the smallest rates of increase. Moreover, despite the substantial stability of the rainfall amount, 50% of the analysed springs showed a trend (29 and 21% for positive and negative trends, respectively) with low discharge variations. Finally, cross-correlation analyses proved the close relationship between air and groundwater temperatures, with a time lag between 0 and 3 months, and between spring discharge and air temperature, with a time lag between 1 and 3 months. In particular, spring discharge is closely connected to snow melting in spring and subordinate to rainfall. These results highlight the existing correlations between spring discharge and various meteorological and topographic parameters in the studied mountain area and provide a preliminary framework of the impacts of climatic variability on the availability and temperature of the exploited water resources.

Incorporating oral bioaccessibility into human health risk assessment due to potentially toxic elements in extractive waste and contaminated soils from an abandoned mine site.

The waste rock, tailings and soil around an abandoned mine site in Gorno (northwest Italy) contain elevated concentrations of potentially toxic elements (PTE) exceeding the permissible limits for residential uses. Specifically, the maximum concentrations of As, Cd, Pb, and Zn were 107 mg/kg, 340 mg/kg, 1064 mg/kg, and 148 433 mg/kg, respectively. A site-specific human health risk assessment (HHRA) was conducted for residential and recreational exposure scenarios, using an approach based on Risk Based Corrective Action (RBCA) method, refined by incorporating oral bioaccessibility data. Oral bioaccessibility analyses were performed by simulating the human digestion process in vitro (Unified BARGE Method). Detailed analysis of oral bioaccessible fraction (BAF i.e. ratio of bioaccessible concentrations to total concentrations on <250 µm fraction) indicated BAF of As (5-33%), Cd (72-98%), Co (24-42%), Cr (3-11%), Cu (25-90%), Ni (17-60%), Pb (16-88%) and Zn (73-94%). The solid phase distribution and mineralogical analyses showed that the variation of BAF is attributed to presence of alkaline calcareous rocks and association of PTE with a variety of minerals. The HHRA for ingestion pathway, suggested that bioaccessibility-corrected cancer risk reached up to 2.7 × 10-5 and 0.55 × 10-5 for residential and recreational senarios respectively (acceptable level is 1 × 10-5). The hazard index (HI) recalculated after incorporation of oral bioaccessible concentrations for a residential scenario ranged from 0.02 to 17.9. This was above the acceptable level (>1) for 50% of the samples, indicating potential human health risks. This study provides information for site-specific risk assessments and planning future research.

Groundwater hydrodynamic behaviours based on water table levels to identify natural and anthropic controlling factors in the Piedmont Plain (Italy).

Water table level monitoring and analysis are among the tools available to identify variations in the quantitative state of groundwater. Moreover, these levels highlight the response of groundwater to climate change and other global change drivers, including land use changes. In this study, water table level (37 monitoring wells) and rainfall (30 rain gauges) data analyses were performed in an alluvial unconfined aquifer in the Piedmont Plain (NW Italy) for the 2002-2017 period. The aim of this study was to identify possible trends in the time series and classify the groundwater hydrodynamic behaviours, as well as their spatial distributions and the main drivers of change in the plain. Moreover, two different sub-periods (2002-2008 and 2009-2017), which were identified with a change point analysis, were analysed to highlight possible variations in the groundwater hydrodynamic behaviours. The results of this study highlighted the lack of a trend in the rainfall time series, while a trend was detected for the water table. To explain this inconsistency, water table behaviours were analysed during the year, highlighting different groundwater hydrodynamic behaviours. Over time, the groundwater hydrodynamic behaviour generally showed the dependence of the water table level on rainfall occurrence. This correlation was also underscored by analysing the standardised anomalies of rainfall and groundwater levels. A different behaviour was observed in the paddy field areas, where the main driver of water level modification is the agricultural technique of rice cultivation. Furthermore, a reduction in the maximum water table level period was observed in 2009-2017 in this area. More specifically, the high water table period passes from 4 to 3 months, which could be the result of changes in irrigation methods. In this study, by analysing the present resource status, a first step is made to obtain future insights into flow dynamics and trends in storage.

Evaluation of sources and fate of nitrates in the western Po plain groundwater (Italy) using nitrogen and boron isotopes.

Diffuse nitrate pollution in groundwater is currently considered one of the major causes of water quality degradation. Determining the sources of nitrate contamination is an important first step for a better management of water quality. Thus, the isotopic composition of nitrate (δ15NNO3 and δ18ONO3) and boron (δ11B) were used to evaluate nitrate contamination sources and to identify geochemical processes occurring in the shallow and deep aquifers of the Turin-Cuneo plain (NW Italy). The study area is essentially an agricultural zone, where use of synthetic nitrogenous fertilizers and organic manure is a common practice and the connection to sewer services is locally lacking. Also livestock farming are highly developed. A groundwater sampling campaign was performed on 34 wells in the shallow aquifer and 8 wells in the deep aquifers, to analyze nitrate, chloride, boron, δ15NNO3, δ18ONO3 and δ11B. Isotope data of nitrate indicate that nitrate contamination in the Turin-Cuneo plain originates from mixtures of synthetic and organic sources, slightly affected by denitrification, and manure or septic tank effluents. Moreover, boron isotopes were used to discriminate further among the main anthropogenic sources of pollution. The analyses results confirm that both animal manure and domestic sewage, especially under the city of Turin, can contribute to the nitrate contamination. The isotope analysis was also used for the evaluation of denitrification and nitrification processes: contrary to expectations, a significant denitrification phenomenon was assessed only in the shallow unconfined aquifer, especially in the Poirino Plateau, the most contaminated sector of the study area.

Linking oral bioaccessibility and solid phase distribution of potentially toxic elements in extractive waste and soil from an abandoned mine site: Case study in Campello Monti, NW Italy.

Oral bioaccessibility and solid phase distribution of potentially toxic elements (PTE) from extractive waste streams were investigated to assess the potential human health risk posed by abandoned mines. The solid phase distribution along with micro-X-ray fluorescence (micro-XRF) and scanning electron microscopy (SEM) analysis were also performed. The results showed that the total concentrations of PTE were higher in <250 µm size fractions of waste rock and soil samples in comparison to the <2 mm size fractions. Mean value of total concentrations of chromium(Cr), copper (Cu), and nickel (Ni) in waste rocks (size fractions <250 µm) were found to be 1299, 1570, and 4010 mg/kg respectively due to the parent material. However, only 11% of Ni in this sample was orally bioaccessible. Detailed analysis of the oral bioaccessible fraction (BAF, reported as the ratio of highest bioaccessible concentration compared with the total concentration from the 250 µm fraction) across all samples showed that Cr, Cu, and Ni varied from 1 to 6%, 14 to 47%, and 5 to 21%, respectively. The variation can be attributed to the difference in pH, organic matter content and mineralogical composition of the samples. Non-specific sequential extraction showed that the non-mobile forms of PTE were associated with the clay and Fe oxide components of the environmental matrices. The present study demonstrates how oral bioaccessibility, solid phase distribution and mineralogical analysis can provide insights into the distribution, fate and behaviour of PTE in waste streams from abandoned mine sites and inform human health risk posed by such sites .

Extractive waste management: A risk analysis approach.

Abandoned mine sites continue to present serious environmental hazards because the heavy metals associated with extractive waste are continuously released into the environment, where they threaten human life and the environment. Remediating and securing extractive waste are complex, lengthy and costly processes. Thus, in most European countries, a site is considered for intervention when it poses a risk to human health and the surrounding environment. As a consequence, risk analysis presents a viable decisional approach towards the management of extractive waste. To evaluate the effects posed by extractive waste to human health and groundwater, a risk analysis approach was used for an abandoned nickel extraction site in Campello Monti in North Italy. This site is located in the Southern Italian Alps. The area consists of large and voluminous mafic rocks intruded by mantle peridotite. The mining activities in this area have generated extractive waste. A risk analysis of the site was performed using Risk Based Corrective Action (RBCA) guidelines, considering the properties of extractive waste and water for the properties of environmental matrices. The results showed the presence of carcinogenic risk due to arsenic and risks to groundwater due to nickel. The results of the risk analysis form a basic understanding of the current situation at the site, which is affected by extractive waste.

The use of multilevel sampling techniques for determining shallow aquifer nitrate profiles.

Nitrate is a worldwide pollutant in aquifers. Shallow aquifer nitrate concentrations generally display vertical stratification, with a maximum concentration immediately below the water level. The concentration then gradually decreases with depth. Different techniques can be used to highlight this stratification. The paper aims at comparing the advantages and limitations of three open hole multilevel sampling techniques (packer system, dialysis membrane samplers and bailer), chosen on the base of a literary review, to highlight a nitrate vertical stratification under the assumption of (sub)horizontal flow in the aquifer. The sampling systems were employed at three different times of the year in a shallow aquifer piezometer in northern Italy. The optimal purge time, equilibration time and water volume losses during the time in the piezometer were evaluated. Multilevel techniques highlighted a similar vertical nitrate stratification, present throughout the year. Indeed, nitrate concentrations generally decreased with depth downwards, but with significantly different levels in the sampling campaigns. Moreover, the sampling techniques produced different degrees of accuracy. More specifically, the dialysis membrane samplers provided the most accurate hydrochemical profile of the shallow aquifer and they appear to be necessary when the objective is to detect the discontinuities in the nitrate profile. Bailer and packer system showed the same nitrate profile with little differences of concentration. However, the bailer resulted much more easier to use.