Presence of fluoride in water diminishes fast the SPR peak of silver nanocrystals showing large red shift with quick sedimentation - A fast sensing and fast removal case.

The medicinal use of fluoride is beneficial up to a low ppm level but regular ingestion at high doses show many adverse effects in human. Fluoride may get ingested through drinking water specially through ground water near the hilly regions, where fluoride content is huge. Hence, fluoride sensing and removal of it from water is very important as fluoride contaminated water is transparent and not easily detectable. Here, we have studied colorimetric and spectrophotometric techniques for sensing of fluoride along with its fast removal from water by using prepared saponin capped silver nanoparticles (AgNPs). Colorimetric study has confirmed the presence of fluoride ions in water samples above the colorimetric detection limit of 10 ppm. But spectroscopic sensing further provides more lower limit of sensing with the total removal of fluoride ions up to 1.2 ppm level. On repeating this this study 15 times, sensing and removal of fluoride is found to be well reproducible. The interaction of fluoride ions with silver nanoparticles has resulted in sedimentation of fluoride ions in the form of fluoride-nanoparticles complex and that interaction has been confirmed by FTIR spectral study of the sedimented part. EDX analysis has also provided the information of easy removal of the fluoride ions from water as presence of fluoride peak has been found in EDX spectra.

Effects of saponin capped triangular silver nanocrystals on the germination of Pisum sativum, Cicer arietinum, Vigna radiata seeds & their subsequent growth study.

In this study, saponin capped triangular silver nanocrystals have been synthesised using fenugreek seed extract, where the extract acts both as a reducing and capping agent. X-ray diffraction study confirms the purity and crystalline nature of the prepared nanocrystals and transmission electron microscopic study shows the triangular morphology with the average edge length of 72 nm, along with the atomic force microscopy study for the height or the width of the triangular nanocrystals. These nanocrystals have been investigated against a few pulses (seeds) such as Pisum sativum, Cicer arietinum and Vigna radiata for their effect on the germination as well as growth of root and shoot. Considering different concentration of silver nanocrystals solution, it has been found that 25 × 10-4 and 80 × 10-4 µg/ml are the minimum and maximum concentrations of silver nanocrystals, within this range, germination and subsequent growth of root and shoot are effective. The result shows significant positive influence on the growth of root and shoot of all seeds in comparison to those of unexposed control germination. Therefore, the result of this experiment has confirmed that the use of saponin capped silver nanocrystals enhances the germination and growth of plants.