Magnesium-Vacancy Optical Centers in Diamond.

We provide the first systematic characterization of the structural and photoluminescence properties of optically active centers fabricated upon implantation of 30-100 keV Mg+ ions in synthetic diamond. The structural configurations of Mg-related defects were studied by the electron emission channeling technique for short-lived, radioactive 27Mg implantations at the CERN-ISOLDE facility, performed both at room temperature and 800 °C, which allowed the identification of a major fraction of Mg atoms (∼30 to 42%) in sites which are compatible with the split-vacancy structure of the MgV complex. A smaller fraction of Mg atoms (∼13 to 17%) was found on substitutional sites. The photoluminescence emission was investigated both at the ensemble and individual defect level in the 5-300 K temperature range, offering a detailed picture of the MgV-related emission properties and revealing the occurrence of previously unreported spectral features. The optical excitability of the MgV center was also studied as a function of the optical excitation wavelength to identify the optimal conditions for photostable and intense emission. The results are discussed in the context of the preliminary experimental data and the theoretical models available in the literature, with appealing perspectives for the utilization of the tunable properties of the MgV center for quantum information processing applications.

Limitations of Bulk Diamond Sensors for Single-Cell Thermometry.

The present paper reports on a Finite Element Method (FEM) analysis of the experimental situation corresponding to the measurement of the temperature variation in a single cell plated on bulk diamond by means of optical techniques. Starting from previous experimental results, we have determined-in a uniform power density approximation and under steady-state conditions-the total heat power that has to be dissipated by a single cell plated on a glassy substrate in order to induce the typical maximum temperature increase ΔTglass=1 K. While keeping all of the other parameters constant, the glassy substrate has been replaced by a diamond plate. The FEM analysis shows that, in this case, the maximum temperature increase is expected at the diamond/cell interface and is as small as ΔTdiam=4.6×10-4 K. We have also calculated the typical decay time in the transient scenario, which resulted in τ≈ 250 µs. By comparing these results with the state-of-the-art sensitivity values, we prove that the potential advantages of a longer coherence time, better spectral properties, and the use of special field alignments do not justify the use of diamond substrates in their bulk form.

Nanodiamond-Quantum Sensors Reveal Temperature Variation Associated to Hippocampal Neurons Firing.

Temperature is one of the most relevant parameters for the regulation of intracellular processes. Measuring localized subcellular temperature gradients is fundamental for a deeper understanding of cell function, such as the genesis of action potentials, and cell metabolism. Notwithstanding several proposed techniques, at the moment detection of temperature fluctuations at the subcellular level still represents an ongoing challenge. Here, for the first time, temperature variations (1 °C) associated with potentiation and inhibition of neuronal firing is detected, by exploiting a nanoscale thermometer based on optically detected magnetic resonance in nanodiamonds. The results demonstrate that nitrogen-vacancy centers in nanodiamonds provide a tool for assessing various levels of neuronal spiking activity, since they are suitable for monitoring different temperature variations, respectively, associated with the spontaneous firing of hippocampal neurons, the disinhibition of GABAergic transmission and the silencing of the network. Conjugated with the high sensitivity of this technique (in perspective sensitive to < 0.1 °C variations), nanodiamonds pave the way to a systematic study of the generation of localized temperature gradients under physiological and pathological conditions. Furthermore, they prompt further studies explaining in detail the physiological mechanism originating this effect.

Quantum Zeno and Anti-Zeno Probes of Noise Correlations in Photon Polarization.

We experimentally demonstrate, for the first time, noise diagnostics by repeated quantum measurements, establishing the ability of a single photon subjected to random polarization noise to diagnose non-Markovian temporal correlations of such a noise process. Both the noise spectrum and temporal correlations are diagnosed by probing the photon with frequent (partially) selective polarization measurements. We show that noise with positive temporal correlations corresponds to our single photon undergoing a dynamical regime enabled by the quantum Zeno effect (QZE), whereas noise characterized by negative (anti) correlations corresponds to regimes associated with the anti-Zeno effect (AZE). This is the first step toward a novel noise spectroscopy based on QZE and AZE in single-photon state probing able to extract information on the noise while protecting the probe state, a conceptual paradigm shift with respect to traditional interferometric measurements.

Emergence of Constructor-Based Irreversibility in Quantum Systems: Theory and Experiment.

How irreversibility arises in a universe with time-reversal symmetric laws is a central problem in physics. In this Letter, we discuss a radically different take on the emergence of irreversibility, adopting the recently proposed constructor theory framework. Irreversibility is expressed as the requirement that a task is possible, while its inverse is not. We prove the compatibility of such irreversibility with quantum theory's time-reversal symmetric laws, using a dynamical model based on the universal quantum homogenizer. We also test the physical realizability of this model by means of an experimental demonstration with high-quality single-photon qubits.

Coherent phase transfer for real-world twin-field quantum key distribution.

Quantum mechanics allows distribution of intrinsically secure encryption keys by optical means. Twin-field quantum key distribution is one of the most promising techniques for its implementation on long-distance fiber networks, but requires stabilizing the optical length of the communication channels between parties. In proof-of-principle experiments based on spooled fibers, this was achieved by interleaving the quantum communication with periodical stabilization frames. In this approach, longer duty cycles for the key streaming come at the cost of a looser control of channel length, and a successful key-transfer using this technique in real world remains a significant challenge. Using interferometry techniques derived from frequency metrology, we develop a solution for the simultaneous key streaming and channel length control, and demonstrate it on a 206 km field-deployed fiber with 65 dB loss. Our technique reduces the quantum-bit-error-rate contributed by channel length variations to <1%, representing an effective solution for real-world quantum communications.

Quantum conformance test.

We introduce a protocol addressing the conformance test problem, which consists in determining whether a process under test conforms to a reference one. We consider a process to be characterized by the set of end products it produces, which is generated according to a given probability distribution. We formulate the problem in the context of hypothesis testing and consider the specific case in which the objects can be modeled as pure loss channels. We demonstrate theoretically that a simple quantum strategy, using readily available resources and measurement schemes in the form of two-mode squeezed vacuum and photon counting, can outperform any classical strategy. We experimentally implement this protocol, exploiting optical twin beams, validating our theoretical results, and demonstrating that, in this task, there is a quantum advantage in a realistic setting.

Temporal teleportation with pseudo-density operators: How dynamics emerges from temporal entanglement.

We show that, by using temporal quantum correlations as expressed by pseudo-density operators (PDOs), it is possible to recover formally the standard quantum dynamical evolution as a sequence of teleportations in time. We demonstrate that any completely positive evolution can be formally reconstructed by teleportation with different temporally correlated states. This provides a different interpretation of maximally correlated PDOs, as resources to induce quantum time evolution. Furthermore, we note that the possibility of this protocol stems from the strict formal correspondence between spatial and temporal entanglement in quantum theory. We proceed to demonstrate experimentally this correspondence, by showing a multipartite violation of generalized temporal and spatial Bell inequalities and verifying agreement with theoretical predictions to a high degree of accuracy, in high-quality photon qubits.

Anomalous weak values via a single photon detection.

Is it possible that a measurement of a spin component of a spin-1/2 particle yields the value 100? In 1988 Aharonov, Albert and Vaidman argued that upon pre- and postselection of particular spin states, weakening the coupling of a standard measurement procedure ensures this paradoxical result1. This theoretical prediction, called weak value, was realised in numerous experiments2-9, but its meaning remains very controversial10-19, since its "anomalous" nature, i.e., the possibility to exceed the eigenvalue spectrum, as well as its "quantumness" are debated20-22. We address these questions by presenting the first experiment measuring anomalous weak values with just a single click, without the need for statistical averaging. The measurement uncertainty is significantly smaller than the gap between the measured weak value and the nearest eigenvalue. Beyond clarifying the meaning of weak values, demonstrating their non-statistical, single-particle nature, this result represents a breakthrough in understanding the foundations of quantum measurement, showing unprecedented measurement capability for further applications of weak values to quantum photonics.

Non-Monogamy of Spatio-Temporal Correlations and the Black Hole Information Loss Paradox.

Pseudo-density matrices are a generalisation of quantum states and do not obey monogamy of quantum correlations. Could this be the solution to the paradox of information loss during the evaporation of a black hole? In this paper we discuss this possibility, providing a theoretical proposal to extend quantum theory with these pseudo-states to describe the statistics arising in black-hole evaporation. We also provide an experimental demonstration of this theoretical proposal, using a simulation in optical regime, that tomographically reproduces the correlations of the pseudo-density matrix describing this physical phenomenon.

Optimal estimation of entanglement and discord in two-qubit states.

Recently, the fast development of quantum technologies led to the need for tools allowing the characterization of quantum resources. In particular, the ability to estimate non-classical aspects, e.g. entanglement and quantum discord, in two-qubit systems, is relevant to optimise the performance of quantum information processes. Here we present an experiment in which the amount of entanglement and discord are measured exploiting different estimators. Among them, some will prove to be optimal, i.e., able to reach the ultimate precision bound allowed by quantum mechanics. These estimation techniques have been tested with a specific family of states ranging from nearly pure Bell states to completely mixed states. This work represents a significant step towards the development of reliable metrological tools for quantum technologies.

Theoretical description and experimental simulation of quantum entanglement near open time-like curves via pseudo-density operators.

Closed timelike curves are striking predictions of general relativity allowing for time-travel. They are afflicted by notorious causality issues (e.g. grandfather's paradox). Quantum models where a qubit travels back in time solve these problems, at the cost of violating quantum theory's linearity-leading e.g. to universal quantum cloning. Interestingly, linearity is violated even by open timelike curves (OTCs), where the qubit does not interact with its past copy, but is initially entangled with another qubit. Non-linear dynamics is needed to avoid violating entanglement monogamy. Here we propose an alternative approach to OTCs, allowing for monogamy violations. Specifically, we describe the qubit in the OTC via a pseudo-density operator-a unified descriptor of both temporal and spatial correlations. We also simulate the monogamy violation with polarization-entangled photons, providing a pseudo-density operator quantum tomography. Remarkably, our proposal applies to any space-time correlations violating entanglement monogamy, such as those arising in black holes.

Investigating the Effects of the Interaction Intensity in a Weak Measurement.

Measurements are crucial in quantum mechanics, for fundamental research as well as for applicative fields like quantum metrology, quantum-enhanced measurements and other quantum technologies. In the recent years, weak-interaction-based protocols like Weak Measurements and Protective Measurements have been experimentally realized, showing peculiar features leading to surprising advantages in several different applications. In this work we analyze the validity range for such measurement protocols, that is, how the interaction strength affects the weak value extraction, by measuring different polarization weak values on heralded single photons. We show that, even in the weak interaction regime, the coupling intensity limits the range of weak values achievable, setting a threshold on the signal amplification effect exploited in many weak measurement based experiments.

Quantifying backflash radiation to prevent zero-error attacks in quantum key distribution.

Single-photon avalanche diodes (SPADs) are the most widespread commercial solution for single-photon counting in quantum key distribution applications. However, the secondary photon emission that arises from the avalanche of charge carriers that occurs during the detection of a photon may be exploited by an eavesdropper to gain information without inducing errors in the transmission key. In this paper, we characterize such backflash light in gated InGaAs/InP SPADs and discuss its spectral and temporal characterization for different detector models and different operating parameters. We qualitatively bound the maximum information leakage due to backflash light and propose solutions for preventing such leakage.

Detection of multimode spatial correlation in PDC and application to the absolute calibration of a CCD camera.

We propose and demonstrate experimentally a new method based on the spatial entanglement for the absolute calibration of analog detectors. The idea consists on measuring the sub-shot-noise intensity correlation between two branches of parametric down conversion, containing many pairwise correlated spatial modes. We calibrate a scientific CCD camera and a preliminary evaluation of the uncertainty indicates the metrological interest of the method.

Experimental estimation of entanglement at the quantum limit.

Entanglement is the central resource of quantum information processing and the precise characterization of entangled states is a crucial issue for the development of quantum technologies. This leads to the necessity of a precise, experimental feasible measure of entanglement. Nevertheless, such measurements are limited both from experimental uncertainties and intrinsic quantum bounds. Here we present an experiment where the amount of entanglement of a family of two-qubit mixed photon states is estimated with the ultimate precision allowed by quantum mechanics.

Experimental test of nonclassicality for a single particle.

In a recent paper [R. Alicki and N. Van Ryn, J. Phys. A: Math. Theor., 41, 062001 (2008)] a test of nonclassicality for a single qubit was proposed. Here, we discuss the class of hidden variables theories to which this test applies and present an experimental realization.

Ghost imaging with intense fields from chaotically seeded parametric downconversion.

We present the first experimental demonstration, to the best of our knowledge, of ghost imaging realized with intense beams generated by a parametric downconversion interaction seeded with pseudothermal light. As expected, the real image of the object is reconstructed satisfying the thin-lens equation. We show that the experimental visibility of the reconstructed image is in accordance with the theoretically expected one.

Intercomparison of a correlated-photon-based method to measure detector quantum efficiency.

We report on the absolute calibration of photodetector quantum efficiency by using correlated photon sources, performed independently at two laboratories, the National Institute of Standards and Technology and the Istituto Elettrotecnico Nazionale (IEN). The goal is to use an interlaboratory comparison to demonstrate the inherent absoluteness of the photon correlation technique by showing its independence from the particular experimental setup. We find that detector nonuniformity limited this comparison rather than uncertainty inherent in the method itself. The ultimate goal of these investigations is development of a robust measurement protocol that allows the uncertainties of individual measurements to be determined experimentally and verified operationally. Furthermore, to demonstrate the generality of the procedure, the IEN measurement setup was also used to calibrate a fiber-coupled avalanche photodiode module. Uncertainties are evaluated for the detector both with and without fiber coupling and differences are discussed. The current IEN setup using a thinner and higher transmittance nonlinear crystal for the generation of correlated photons shows a significant improvement in overall accuracy with respect to previously reported results from IEN [Metrologia 32, 501-503 (1996)].