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J Am Chem Soc ; 133(24): 9282-5, 2011 Jun 22.
Article in English | MEDLINE | ID: mdl-21612204

ABSTRACT

The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee).


Subject(s)
Palladium/chemistry , Phenols/chemistry , Catalysis , Spiro Compounds/chemistry , Substrate Specificity
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