ABSTRACT
The fundamentals, performance, and applications of piezoresistive strain sensors based on polymer nanocomposites are summarized herein. The addition of conductive nanoparticles to a flexible polymer matrix has emerged as a possible alternative to conventional strain gauges, which have limitations in detecting small strain levels and adapting to different surfaces. The evaluation of the properties or performance parameters of strain sensors such as the elongation at break, sensitivity, linearity, hysteresis, transient response, stability, and durability are explained in this review. Moreover, these nanocomposites can be exposed to different environmental conditions throughout their lifetime, including different temperature, humidity or acidity/alkalinity levels, that can affect performance parameters. The development of flexible piezoresistive sensors based on nanocomposites has emerged in recent years for applications related to the biomedical field, smart robotics, and structural health monitoring. However, there are still challenges to overcome in designing high-performance flexible sensors for practical implementation. Overall, this paper provides a comprehensive overview of the current state of research on flexible piezoresistive strain sensors based on polymer nanocomposites, which can be a viable option to address some of the major technological challenges that the future holds.
ABSTRACT
An adhesive based on a Fe3O4-nanoparticle (MNP)-doped epoxy resin was proposed for the development of detachable adhesive joints with GFRP substrates. The analysis of cryofractures showed that the increasing MNP content promotes a higher presence of larger aggregates and a lower sedimentation of nanoparticles due to the higher viscosity of the mixture. In this regard, the inclusion of expandable microspheres (MS) induces a more uniform dispersion of MNPs, reducing their sedimentation. The capability of the proposed adhesives for electromagnetic (EM) heating was also evaluated, with increases in temperature of around 100 °C at 750 A, enough to reach the Tg of the polymer required to facilitate the adhesive detachment, which is around 80 °C. Finally, the lap shear strength (LSS) of 14 and 20 wt.% MNP samples was evaluated in a single-lap shear joint with simultaneous EM heating. The LSS values were reduced by 60-80% at 750 A, thus promoting successful adhesive joint detachment under EM heating.
ABSTRACT
Multifunctional nanocomposites based on carbon nanotubes (CNT)-reinforced Surlyn, which is a commercial ionomeric polymer, are manufactured by micro-compounding and hot-press processes. Multifunctionality is studied in terms of electromechanical response and self-healing abilities. The strain sensing analysis under tensile conditions shows ultra-high gauge factor (GF) values from 10 to 20 at low strain levels up to 106 at high strain levels, and a decreasing sensitivity as CNT content increases because of the reduction in the tunneling distance between neighboring nanoparticles. The electromechanical response under consecutive tensile cycles demonstrated the robustness of the proposed materials due to the repeatability of both responses. With regard to mechanical properties, the addition of CNT induces a clear increase in Young's modulus because the nanoparticles enable uniform load distributions. Moreover, self-healing capabilities are improved when 4 and 5 wt.% CNT are introduced because of the synergistic effect of the high thermal conductivity of CNT and their homogeneous distribution, promoting an increase in the thermal conductivity of bulk nanocomposites. Thus, by comparing the measured functionalities, 4 and 5 wt.% CNT-reinforced Surlyn nanocomposites showed a high potential for various applications due to their high degree of multifunctionality.
ABSTRACT
Carbon nanotube (CNT) reinforced polydimethylsiloxane (PDMS) easy-scalable sensors for human motion monitoring are proposed. First, the analysis of the dispersion procedure of nanoparticles into the polymer matrix shows that the ultrasonication (US) technique provides a higher electrical sensitivity in comparison to three-roll milling (3RM) due to the higher homogeneity of the CNT distribution induced by the cavitation forces. Furthermore, the gauge factor (GF) calculated from tensile tests decreases with increasing the CNT content, as the interparticle distance between CNTs is reduced and, thus, the contribution of the tunnelling mechanisms diminishes. Therefore, the optimum conditions were set at 0.4 CNT wt.% dispersed by US procedure, providing a GF of approximately 37 for large strains. The electrical response under cycling load was tested at 2%, 5%, and 10% strain level, indicating a high robustness of the developed sensors. Thus, this strain sensor is in a privileged position with respect to the state-of-the-art, considering all the characteristics that this type of sensor must accomplish: high GF, high flexibility, high reproducibility, easy manufacturing, and friendly operation. Finally, a proof-of-concept of human motion monitoring by placing a sensor for elbow and finger movements is carried out. The electrical resistance was found to increase, as expected, with the bending angle and it is totally recovered after stretching, indicating that there is no prevalent damage and highlighting the huge robustness and applicability of the proposed materials as wearable sensors.
