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Phytochemistry ; 52(2): 291-6, 1999 Sep.
Article in English | MEDLINE | ID: mdl-10513402

ABSTRACT

Incubation of confertifolin and isodrimenin with Mucor plumbeus, Aspergillus niger or Rhizopus arrhizus gave in good yields the corresponding 3 beta-hydroxy derivatives. From isodrimenin, the known natural 7 alpha-hydroxy derivative (futronolide) was also obtained and its structure was definitely established by X-ray crystallographic study of its acetate derivative.


Subject(s)
Lactones/metabolism , Crystallography, X-Ray , Fungi/metabolism , Hydroxylation , Lactones/chemistry , Magnetic Resonance Spectroscopy , Mass Spectrometry , Molecular Structure
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