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A novel iodine-mediated tandem cyclization-cycloaddition reaction leading to polyoxacyclic ring systems.
Xie, Yong-Xin; Yan, Ze-Yi; Qian, Bo; Deng, Wen-Ye; Wang, Dan-Zhu; Wu, Lu-Yong; Liu, Xue-Yuan; Liang, Yong-Min.
Chem Commun (Camb) ; (36): 5451-3, 2009 Sep 28.
Article in English | MEDLINE | ID: mdl-19724815

ABSTRACT

A novel iodine-catalyzed tandem cyclization-cycloaddition reaction of ortho-alkynyl-substituted benzaldehydes leading to polyoxacyclic ring systems has been developed, which represents a useful approach towards the synthesis of the oxabicyclo-[3.2.1]octane ring skeleton found in a variety of natural products.


Subject(s)
Heterocyclic Oxides/chemical synthesis , Iodine/chemistry , Polycyclic Compounds/chemical synthesis , Alkynes/chemistry , Benzaldehydes/chemistry , Catalysis , Crystallography, X-Ray , Cyclization , Heterocyclic Oxides/chemistry , Models, Chemical , Molecular Conformation , Polycyclic Compounds/chemistry
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