Precise Photoexcitation Measurement of Tan's Contact in the Entire BCS-BEC Crossover.

We study two-body correlations in a spin-balanced ultracold harmonically trapped Fermi gas of ^{6}Li atoms in the crossover from the Bardeen-Cooper-Schrieffer (BCS) to the Bose-Einstein-Condensate (BEC) regime. For this, we precisely measure Tan's contact using a novel method based on photoexcitation of atomic pairs, which was recently proposed by Wang et al. [Photoexcitation measurement of Tan's contact for a strongly interacting Fermi gas, Phys. Rev. A 104, 063309 (2021).PLRAAN2469-992610.1103/PhysRevA.104.063309]. We map out the contact in the entire phase diagram of the BCS-BEC crossover for various temperatures and interaction strengths, probing regions in phase space that have not been investigated yet. Our measurements reach an uncertainty of ≈2% at the lowest temperatures and thus represent a precise quantitative benchmark. By comparison to our data, we localize the regions in phase space where theoretical predictions and interpolations give valid results. In regions where the contact is already well known we find excellent agreement with our measurements. Thus, our results demonstrate that photoinduced loss is a precise probe to measure quantum correlations in a strongly interacting Fermi gas.

Spin-Conservation Propensity Rule for Three-Body Recombination of Ultracold Rb Atoms.

We explore the physical origin and the general validity of a propensity rule for the conservation of the hyperfine spin state in three-body recombination. This rule was recently discovered for the special case of ^{87}Rb with its nearly equal singlet and triplet scattering lengths. Here, we test the propensity rule for ^{85}Rb for which the scattering properties are very different from ^{87}Rb. The Rb_{2} molecular product distribution is mapped out in a state-to-state fashion using resonance-enhanced multiphoton ionization detection schemes which fully cover all possible molecular spin states. Interestingly, for the experimentally investigated range of binding energies from zero to ∼13 GHz×h we observe that the spin-conservation propensity rule also holds for ^{85}Rb. From these observations and a theoretical analysis we derive an understanding for the conservation of the hyperfine spin state. We identify several criteria to judge whether the propensity rule will also hold for other elements and collision channels.

Reaction kinetics of ultracold molecule-molecule collisions.

Studying chemical reactions on a state-to-state level tests and improves our fundamental understanding of chemical processes. For such investigations it is convenient to make use of ultracold atomic and molecular reactants as they can be prepared in well defined internal and external quantum states. Here, we investigate a single-channel reaction of two Li2-Feshbach molecules where one of the molecules dissociates into two atoms 2AB ⇒ AB + A + B. The process is a prototype for a class of four-body collisions where two reactants produce three product particles. We measure the collisional dissociation rate constant of this process as a function of collision energy/temperature and scattering length. We confirm an Arrhenius-law dependence on the collision energy, an a4 power-law dependence on the scattering length a and determine a universal four body reaction constant.

State-to-state chemistry for three-body recombination in an ultracold rubidium gas.

Experimental investigation of chemical reactions with full quantum state resolution for all reactants and products has been a long-term challenge. Here we prepare an ultracold few-body quantum state of reactants and demonstrate state-to-state chemistry for the recombination of three spin-polarized ultracold rubidium (Rb) atoms to form a weakly bound Rb2 molecule. The measured product distribution covers about 90% of the final products, and we are able to discriminate between product states with a level splitting as small as 20 megahertz multiplied by Planck's constant. Furthermore, we formulate propensity rules for the distribution of products, and we develop a theoretical model that predicts many of our experimental observations. The scheme can readily be adapted to other species and opens a door to detailed investigations of inelastic or reactive processes.

Energy Scaling of Cold Atom-Atom-Ion Three-Body Recombination.

We study three-body recombination of Ba^{+}+Rb+Rb in the mK regime where a single ^{138}Ba^{+} ion in a Paul trap is immersed into a cloud of ultracold ^{87}Rb atoms. We measure the energy dependence of the three-body rate coefficient k_{3} and compare the results to the theoretical prediction, k_{3}∝E_{col}^{-3/4}, where E_{col} is the collision energy. We find agreement if we assume that the nonthermal ion energy distribution is determined by at least two different micromotion induced energy scales. Furthermore, using classical trajectory calculations we predict how the median binding energy of the formed molecules scales with the collision energy. Our studies give new insights into the kinetics of an ion immersed in an ultracold atom cloud and yield important prospects for atom-ion experiments targeting the s-wave regime.

Single ion as a three-body reaction center in an ultracold atomic gas.

We report on three-body recombination of a single trapped Rb(+) ion and two neutral Rb atoms in an ultracold atom cloud. We observe that the corresponding rate coefficient K(3) depends on collision energy and is about a factor of 1000 larger than for three colliding neutral Rb atoms. In the three-body recombination process large energies up to several 0.1 eV are released leading to an ejection of the ion from the atom cloud. It is sympathetically recooled back into the cloud via elastic binary collisions with cold atoms. Further, we find that the final ionic product of the three-body processes is again an atomic Rb(+) ion suggesting that the ion merely acts as a catalyzer, possibly in the formation of deeply bound Rb(2) molecules.

An apparatus for immersing trapped ions into an ultracold gas of neutral atoms.

We describe a hybrid vacuum system in which a single ion or a well-defined small number of trapped ions (in our case Ba(+) or Rb(+)) can be immersed into a cloud of ultracold neutral atoms (in our case Rb). This apparatus allows for the study of collisions and interactions between atoms and ions in the ultracold regime. Our setup is a combination of a Bose-Einstein condensation apparatus and a linear Paul trap. The main design feature of the apparatus is to first separate the production locations for the ion and the ultracold atoms and then to bring the two species together. This scheme has advantages in terms of stability and available access to the region where the atom-ion collision experiments are carried out. The ion and the atoms are brought together using a moving one-dimensional optical lattice transport which vertically lifts the atomic sample over a distance of 30 cm from its production chamber into the center of the Paul trap in another chamber. We present techniques to detect and control the relative position between the ion and the atom cloud.

Dynamics of a cold trapped ion in a Bose-Einstein condensate.

We investigate the interaction of a laser-cooled trapped ion (Ba+ or Rb+) with an optically confined 87Rb Bose-Einstein condensate. The system features interesting dynamics of the ion and the atom cloud as determined by their collisions and their motion in their respective traps. Elastic as well as inelastic processes are observed and their respective cross sections are determined. We demonstrate that a single ion can be used to probe the density profile of an ultracold atom cloud.

Dark state experiments with ultracold, deeply-bound triplet molecules.

We examine dark quantum superposition states of weakly bound Rb2 Feshbach molecules and tightly bound triplet Rb2 molecules in the rovibrational ground state, created by subjecting a pure sample of Feshbach molecules in an optical lattice to a bichromatic Raman laser field. We analyze, both experimentally and theoretically, the creation and dynamics of these dark states. Coherent wavepacket oscillations of deeply bound molecules in lattice sites, as previously observed by Lang et al. (Phys. Rev. Lett., 2008, 101, 133005), are suppressed due to laser-induced phase locking of molecular levels. This can be understood as the appearance of a novel multilevel dark state. In addition, the experimental methods developed help to determine important properties of our coupled atom/ laser system.