Thermal Regeneration of Spent Sand with Furfuryl Binder from an Ecological and Economic Point of View.

The recovery of the grain matrix from spent moulding sand is a constant challenge in making the best possible use of the deposits of quartz sand material, as well as in protecting them. In the case of spent sand with organic binders, the best method to recover the grain matrix is thermal regeneration. However, this method is expensive and requires adequate attention to the emission of harmful compounds into the atmosphere. This paper presents a new concept for implementing the thermal regeneration process. A suitable regeneration temperature was adopted for the furfuryl binder moulding sand, and a change in the design of the device was introduced in the area of the utilisation of gases generated during the combustion of the spent binder. To confirm the assumptions made, and to assess the appropriate suitability of the material recovered, the technological parameters of the material obtained were verified, namely, ignition losses, sieve analysis, bending strength, and pH value. The consumption of media for the process was also analysed from an economic point of view, as well as the emission of BTEX (a mixture of volatile aromatic hydrocarbons-benzene, toluene and three isomers of xylene) gases under different conditions of the process. On the basis of the research conducted, it was concluded that lowering the regeneration temperature of regeneration does not adversely affect the technological parameters of the moulding sand on the regenerate matrix. Changing the design of the regenerator does not result in increased emissions of harmful substances to the environment. Studies indicate that the appropriate setting of thermal regeneration parameters and the optimal design of the employed equipment are favourable factors in reducing the cost of the process while not compromising the quality of the moulding sand and the environmental impact.

The Influence of 3D Printing Core Construction (Binder Jetting) on the Amount of Generated Gases in the Environmental and Technological Aspect.

This article presents the findings of a study focusing on the gas generation of 3D-printed cores fabricated using binder-jetting technology with furfuryl resin. The research aimed to compare gas emission levels, where the volume generated during the thermal degradation of the binder significantly impacts the propensity for gaseous defects in foundries. The study also investigated the influence of the binder type (conventional vs. 3D-printed dedicated binder) and core construction (shell core) on the quantity of gaseous products from the BTEX group formed during the pouring of liquid foundry metal into the cores. The results revealed that the emitted gas volume during the thermal decomposition of the organic binder depended on the core sand components and binder type. Cores produced using conventional methods emitted the least gases due to lower binder content. Increasing Kaltharz U404 resin to 1.5 parts by weight resulted in a 37% rise in gas volume and 27% higher benzene emission. Adopting shell cores reduced gas volume by over 20% (retaining sand with hardener) and 30% (removing sand with hardener), presenting an eco-friendly solution with reduced benzene emissions and core production costs. Shell cores facilitated the quicker removal of gaseous binder decomposition products, reducing the likelihood of casting defects. The disparity in benzene emissions between 3D-printed and vibratory-mixed solid cores is attributed to the sample preparation process, wherein 3D printing ensured greater uniformity.

3D Printed (Binder Jetting) Furan Molding and Core Sands-Thermal Deformation, Mechanical and Technological Properties.

Casting cores produced in additive manufacturing are more often used in industrial practice, in particular in the case of the production of unit castings and castings with very complex geometry. The growing interest in the technology of 3D printing of cores and molds also brings emerging doubts related to their mechanical and technological properties. This article presents a comparison of the properties of cores made of sand with acid-curing furfuryl resin, made with 3D printing technology; the cores were prepared in a conventional way (mixing and compaction). The main purpose of this research was to determine the possibility of using shell cores as a substitute for solid cores, aimed at reducing the amount of binder in the core. The influence of the type of the binder and the size of the grain matrix fraction on the obtained mechanical and technological properties of the cores, with particular emphasis on abrasion and thermal deformation, as well as on the kinetics of their hardening, was demonstrated.