Legacy and emerging flame retardants in indoor and outdoor dust from Indo-Gangetic Region (Patna) of India: implication for source apportionment and health risk exposure.

The fate of legacy and emerging flame retardants are poorly reported in developing countries, including India. Also, the positive matrix factorization (PMF) application-based source apportionment of these pollutants is less comprehensive. This study analyzed the contamination level and sources of 25 flame retardants in dust from India's central Indo-Gangetic Plain (Patna city) using the PCA and PMF model. Dust samples were collected from various functional areas of indoor (n = 22) and outdoor (n = 16) environments. The sum of four groups of FRs in indoor dust (median 8080 ng/g) was 3-4 times greater than the outdoor dust (median 2410 ng/g). The novel-brominated flame retardants (NBFRs) and organophosphate esters (OPFRs) were more dominant than polybrominated diphenyl ethers (PBDEs), indicating the influence of worldwide elimination of PBDEs. The median concentration of ∑NBFRs in indoor and outdoor dust was 1210 ng/g and 6820 ng/g, while the median concentration of ∑OPFRs was measured to be 383 ng/g and 1210 ng/g, respectively. Likewise, ∑9PBDEs in indoor and outdoor dust ranged from 2-1040 ng/g (median 38.8 ng/g) to 0.62-249 ng/g (median 10.7 ng/g), respectively. Decabromodiphenylethane (DBDPE) was identified as the most abundant NBFR in dust, comprising 99.9% of ∑6NBFR, while tri-cresyl phosphates (TMPPs) showed the highest concentration among OPFR and accounted for 75% ∑8OPFRs. The PMF analysis indicated that a significant fraction of FRs in the dust (80%) could derive from plastics, textiles, polyurethane foam, anti-foam agents, PVC, paint, and coatings. In comparison, debromination of higher PBDE congeners contributed 20% in the dust environment. FR's estimated daily exposure risk in dust showed dermal absorption as the main route of FR's intake to adult and children populations. Children were more vulnerable to the risk of FRs than the adult population. The estimated daily exposure risk for selected FRs in this study was 4-6 orders of magnitude lesser than the respective reference dose (RfD), proposing negligible health risk.

Nitrated- and oxygenated-polycyclic aromatic hydrocarbon in urban soil from Nepal: Source assessment, air-soil exchange, and soil-air partitioning.

In contrast to more frequently investigated priority pollutants, such as polycyclic aromatic hydrocarbons (PAHs), only little is known about the fate and distribution of nitrated- and oxygenated-PAHs (NPAHs and OPAHs) in urban soils, particularly in Indian sub-continent. Moreover, experimental data on air-soil exchange and soil-air partitioning are also lacking, which is critical in assessing the partitioning, fugacity coefficient, and secondary emission of PAH-derivatives. Hence, this article provides an insight into the fate, sources, air-soil exchange, and soil-air partitioning of PAH-derivatives on a molecular basis. Prospective health risk due to their exposure has also been discussed. The result showed that PAH-derivatives had significantly polluted all four Nepalese cities. Æ©15NPAHs and Æ©2OPAHs in soil were 4 and 20 times lower than their parent-PAHs, and ranged 396-2530 ng/g (median 458 ng/g) and 91.9-199 ng/g (median 94.9 ng/g), respectively. Æ©15NPAHs was higher than a few global studies, while Æ©2OPAHs was lower than some of the less urbanized/remote areas worldwide. The 6-Nitobenzo[a]pyrene (6-NBaP) was most abundant in soil, and accounted for 10-12% of Æ©15NPAHs, while Benzanthrone (BZONE) exceeded among OPAHs, and represented 71-76% of Æ©2OPAHs, respectively. Source identification study indicated that direct emissions from domestic/residential cooking and heating and secondary formations are the essential sources of derivative chemicals in soil. Fugacity fraction ratio (fratio) indicated volatilization from the soil. The soil-air partitioning study showed sorption by soil organic matter/black carbon has little role in soil-air partitioning of PAH-derivatives in Nepal's urban soil. The toxicity equivalency quotients (TEQs) of NPAHs (314 ± 102 ng/g) was estimated slightly higher than their parent-PAHs (294 ± 121 ng/g) suggesting a relatively higher risk of soil toxicity in Nepal.

Polychlorinated biphenyls and organochlorines pesticides in indoor dust: An exploration of sources and health exposure risk in a rural area (Kopawa) of Nepal.

While contamination of indoor environment with organochlorine compounds (OCs) is well documented worldwide, only a few studies highlighted the problem of indoor pollution in Indian sub-continent, including Nepal. This study insight the contamination level, distribution pattern, and sources of OCs in indoor dust from a rural area of Nepal. Additionally, daily exposure risk through different intake pathways was estimated in order to mark the potential risk of OCs to local residents. Results indicated the predominance of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in dust. Æ©26OCPs (median 87 ng/g) in dust was about 7-8 times greater than Æ©30PCBs (median 10.5 ng/g). DDT was the most abundant chemical among Æ©26OCPs, followed by HCHs and endosulfan, and accounted for 73%, 7%, and 4% of Æ©26OCPs, respectively. A relatively high level of Æ©DDT than other OCPs suggests the existence of DDT source in the Nepalese environment. Among PCB, tetra-CBs were most prevalent, trailed by penta-CBs, hexa-CBs, and hepta-CBs, and comprised 28%, 21%, 17% and 17% of Æ©30PCBs, respectively. Dioxin like-PCBs (median 3.48 ng/g) was about two times higher than the total indicator-PCB (median 1.63 ng/g). High p,p-DDT/p,p-DDE ratio (median 2.89) suggested fresh application and minimal degradation of DDT in the local environment of Kopawa. While lower α-/γ-HCH ratio (median 0.75) indicated lindane contamination as the primary sources of HCH. Moreover, the low α-/ß-endosulfan ratio (median 0.86) specified the fresh use of commercial endosulfan. Among OCPs, only DDT positively related to total organic carbon (TOC) (Rho = 0.55, p < 0.05) but not black carbon (BC), proposing minimal or zero impact of TOC and BC. For PCBs, PCB-126 was moderately and negatively correlated with TOC (Rho = -0.49, p < 0.05), but not BC. The daily risk exposure (DRE) assessment showed that children are more vulnerable to OCs than the adult. The DRE of OCs in this study were 2-4 order of magnitude lower than their corresponding reference dose (RfD), proposing insignificant risk.

Airborne brominated, chlorinated and organophosphate ester flame retardants inside the buildings of the Indian state of Bihar: Exploration of source and human exposure.

Since many household products used by individuals contain flame retardants (FRs), there is more chance that these chemicals may be present in the various exhibit of the indoor environment. Despite being one of the fastest-growing economies worldwide, the contamination level, sources, products, and pathways of FRs in India, is either not known or limited. This inspired us to investigate the level, profile, spatial distribution, and sources of different classes of FRs in the indoor air. For this purpose, 15 brominated, 2 chlorinated, and 8 organophosphate FRs (OPFRs) were investigated in indoor air samples from urban and suburban sites of an Indian state of Bihar. Additionally, inhalation health risk exposure to children and the adult was estimated to predict the risk of these chemicals. Overall, ∑8OPFRs (median 351 pg/m3) was the most prominent in air, followed by novel brominated FR (∑6NBFRs) (median 278 pg/m3), polybrominated diphenyl ether (∑9PBDE) (median 5.05 pg/m3), and dechlorane plus (∑2DPs) (median 2.52 pg/m3), and accounted for 55%, 44%, 0.8% and 0.4% of ∑FRs, respectively. Generally, ∑9PBDEs (median 6.29 pg/m3) and ∑8OPFRs (median 355 pg/m3) were measured high at sub-urban sites, while urban sites had the highest level of ∑2DPs (median 2.81 pg/m3) and ∑6NBFRs (median 740 pg/m3). BDE-209 was most abundant among ∑9PBDEs, while syn-DP dominated in ∑2DPs. Likewise, DBDPE was most prevalent in ∑6NBFRs, while TMPP topped among ∑8OPFRs. The principal component analysis revealed contribution from household items, food packaging and paints, hydraulic fluid, a gasoline additive, and de-bromination of BDE-209 as the primary sources of FRs. The estimated daily inhalation exposure (DIE) indicated a relatively high risk to children than the adult. The DIE of individual FR was several folds lower than their corresponding oral reference dose (RfDs), suggesting minimal risk. However, exposure risk, especially to children, may still need attention because other routes of intake may always be significant in the case of Bihar.

Data on fate and distribution of organophosphate esters in the soil - sediments from Kathmandu Valley, Nepal.

Globally, soil and sediments are known as the likely sinks of various organic pollutants, such as organophosphate esters (OPEs). However, the fate of OPEs in soil/sediment matrices is limited in the whole of South Asia, especially if there should be an occurrence of Nepal. This data article elucidates the fate and distribution of OPEs in soil and sediment samples from the capital city of Nepal (Kathmandu). A total of eight different compounds of OPE was measured in soil (N = 19) and sediment (N = 20) samples collected during October 2014. The median concentration and composition of the individual OPE have been discussed. Additionally, health risk exposure due to ingestion and dermal contact of OPE was assessed to mark the endanger of OPE. Moreover, risk quotient (RQ) for fish, Daphnia, and algae was calculated to forecast the risk of OPEs on aquatic organisms.

Data relating to fate and transport of organophosphate ester flame retardants in indoor air and dust from Nepal.

The ubiquitous occurrence of organophosphate ester flame retardants (OPFRs) may pose a threat to human health. Most of the OPFRs are suspected to be carcinogenic, neurotoxic and can cause fertility and reproductive effects (World Health Organization, 2000) and (Van der Veen and De Boer, 2012). Although a number of researches have detailed high level of organophosphate ester flame retardant worldwide, unfortunately Nepal has never been part of any global/regional monitoring campaign. This data article presents the concentration of eight different compounds of organophosphate ester flame retardants (OPFRs) measured in indoor air and house dust. Thirty four indoor air and 28 house dust samples were collected from four major cities (Kathmandu, Pokhara, Birgunj, and Biratnagar) of Nepal to investigate the contamination level and distribution pattern of OPFR. The median concentration and relative contribution of individual OPFR has been also discussed (Yadav et al., 2017).

Dataset on assessment of heavy metals contamination in multi-environmental samples from Patna, India.

Accumulation of heavy metals in vegetables adversely affects the well-being of human health. In this study, we investigated the heavy metals (Hg, Zn, Cu, Pb and Mn) contamination in different environmental samples collected from five major sites (Gaighat, Paijawa, Danapur, Ranipur and Marchi) of Patna. In all the samples concentration of manganese (Mn) was found to be higher in soil samples. The concentration of heavy metals in soil samples were in the order Mn > Zn > Cu > Pb > Hg in water sample; Mn > Zn > Pb > Cu > Hg, and in vegetables Mn > Zn > Cu > Pb > Hg. In all sites, majority of heavy metal were within the permissible limits except the Zn and Pb. The Zn and Pb contents in vegetables and soil were measured above the permissible limit recommended by WHO/FAO (2007) and Indian standard. The bioconcentration factors (BCFs) for the heavy metal transfer from soils to vegetables are analysed and were ranked in the order of Hg > Pb > Zn > Cu > Mn. The estimated daily intake of metals suggested low health risk despite higher metal content in soil/vegetables. The metal pollution index (MPI) analysis showed high MPI for spinach (15.6) followed by red spinach (14.0) whereas beans (8.6) showed lower metal pollution index.

Examining the role of total organic carbon and black carbon in the fate of legacy persistent organic pollutants (POPs) in indoor dust from Nepal: Implication on human health.

Despite the fact that the consumption and import of legacy persistent organic pollutants (POPs) have been stopped in Nepal since 2001, they are still of worry for human prosperity and the environment because of their persistence behavior and constant release from sources that are presently being used. The essential objective of this study was to assess the concentration and spatial distribution of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in residential dust from Nepal keeping in mind the end goal to evaluate the importance of total organic carbon (TOC) and black carbon (BC) in the fate of legacy POPs. Additionally, health risk exposure via dust ingestion and dermal absorption was estimated to evaluate the significance of dust media for human exposure. Results demonstrated that ∑OCPs in dust was 37 times greater than ∑PCBs. DDT was mostly dominated in the dust, and contributed 90% of the ∑OCPs, while hexa-CBs predominated among PCBs and represented 34% of ∑PCBs. Birgunj and Biratnagar had a relatively higher level of ∑OCPs and ∑PCBs than those of Kathmandu and Pokhara. TOC and BC showed a poor connection with OCPs, recommending little or no role. However, PCB in the dust, especially low congeners was strongly linked with TOC but not BC indicating the significant role of TOC. The daily risk exposure estimation indicated dermal absorption through dust as the principal means of OCPs/PCBs intake to both adult and children population. These estimated exposures were 2-4 orders of magnitude inferior to their corresponding reference dose showing insignificant risk.

Spatial distribution, source analysis, and health risk assessment of heavy metals contamination in house dust and surface soil from four major cities of Nepal.

Raising population, deteriorating environmental conditions and limiting natural resources to handle the key environmental health problems have critically affected human health and the environment. Policy makers and planners in Nepal are more concerned today than at any other time in the past about the deterioration of the environmental condition. Therefore, understanding the connection between pollution and human wellbeing is fundamental endeavors to control pollution exposures and secure human wellbeing. This ability is especially critical for countries like Nepal where the issues of environmental pollution have customarily taken a second place to request for economic development. In this study, spatial distribution and sources of 12 heavy metals (HMs) were investigated in surface soils (n = 24) and house dust (n = 24) from four major urban areas of Nepal in order to mark the pollution level. Additionally, a health risk was estimated to establish the link between HMs pollution and human health. Results showed that the median concentration of Ag, Cd, Co, Cr, Cu, Ni, Pb, Sb, Mn and Zn in soil and dust were 2-13 times greater than the background value. The As, Zn, Cu, Cd, and Pb showed a relatively higher spatial variability in soil and dust. Zn was the most abundant metal measured in dust and soil and accounted for 59% and 55% of ∑7HMs, respectively. The HMs in soil and dust were poorly correlated with total organic carbon (TOC) and black carbon (BC), suggesting little or no influence on HMs contamination. Source analysis study indicated the distribution of Cr, Ni, Sb, Ag, Pb, Cu, and Zn in soil and dust are mainly affected by anthropogenic sources, particularly traffic emissions, industrial source, and domestic households materials, while Co, Fe, As, Mn and Cd were from natural sources. The estimated carcinogenic risk (CR) of HMs in soil and dust exceeded the acceptable level of human exposure, recommending significant CR to the local population.

Measurement of legacy and emerging flame retardants in indoor dust from a rural village (Kopawa) in Nepal: Implication for source apportionment and health risk assessment.

Under the Stockholm Convention, signatory countries are obliged to direct source inventories, find current sources, and provide ecological monitoring evidence to guarantee that the encompassing levels of persistent organic pollutants (POPs) are declining. However, such monitoring of different types of POPs are to a great degree constrained in most developing countries including Nepal and are primarily confined to suspected source area/ densely populated regions. In this study, 9 polybrominated diphenyl ethers (PBDEs), 2 dechlorane plus (DPs), 6 novel brominated flame retardants (NBFRs) and 8 organophosphate ester flame retardants (OPFRs) were investigated in indoor dust from a rural area (Kopawa) in Nepal in order to evaluate their occurrence/level, profile, spatial distribution and their sources. Additionally, health risk exposure was estimated to anticipate the possible health risk to the local population. The results showed that OPFRs was the most abundant FR measured in the dust. The concentration of ∑8OPFRs was about 2, 3 and 4 orders of magnitude higher than the ∑6NBFRs, ∑9PBDEs, and ∑2DPs, respectively. Tris (methylphenyl) phosphate (TMPP) and Tris (2-ethylhexyl) phosphate (TEHP) were the most abundant OPFRs analyzed in the dust; while decabromodiphenyl ethane (DBDPE) exceeded among NBFRs. Likewise, 2,2',3,3',4,4',5,5',6,6'-decabromodiphenylether (BDE-209) was the most identified chemical among PBDEs. The total organic carbon (TOC) content in dust was significantly and positively connected with octa-BDEs (Rho = 0.615, p < 0.01), BTBPE (Rho = 0.733, p < 0.01), TPHP (Rho = 0.621, p < 0.01), TEHP (Rho = 0.560, p < 0.01) and TMPPs (Rho = 0.550, p < 0.01), while black carbon (BC) was either weakly related or not related, suggesting little or no impact of BC in the distribution of FRs. Principal component analysis indicated the contribution from commercial penta-, octa- and deca-BDEs formulation, the adhesive substance, food packaging and paints, and degradation of BDE-209 as the essential sources of FRs. Health risk exposure estimates showed that dermal absorption via dust as the primary route of FRs intake. The estimated daily exposure of PBDEs, NBFRs and OPFRs were 2-10 orders of magnitude lower than their corresponding reference dose (RfD), suggesting insignificant risk. However, other routes such as inhalation and dietary intake might still be significant in the case of Kopawa which should be tested in future.

Concentrations, sources and health risk of nitrated- and oxygenated-polycyclic aromatic hydrocarbon in urban indoor air and dust from four cities of Nepal.

Although the fate and behavior of parent polycyclic aromatic hydrocarbon (PAHs) have been documented worldwide, the information about PAH-derivatives (NPAHs and OPAHs) is limited, especially in developing countries, including Nepal. Moreover, the greater parts of the investigations concentrating on NPAHs/OPAHs are on the air (borne) particulate phase only; and are primarily based on a limited number of compounds analyzed. Little is known about the environmental concentration, fate, and behavior of NPAHs and OPAHs in air gas phase and dust. In this study, the concentration, fate, spatial distributions of 26 NPAHs and 3 OPAHs in the air (n = 34) and dust (n = 24) were investigated in suspected source area/more densely populated areas of Nepal. Four critical source areas in Nepal were considered as it was conjectured that the urban areas are more prone to NPAH/OPAH contamination due to the high density of automobiles and industrial activities. Overall, the measured ∑19NPAHs in air and dust were 5 and 2 times lower than their parent-PAHs, respectively. Highest levels of NPAHs/OPAHs were measured in Birgunj, followed by Kathmandu, Biratnagar, and Pokhara, respectively, while Biratnagar showed the highest level of ∑OPAHs. 3-Nitrodibenzofuran (3-NDBF) was the most abundant NPAHs measured both in air and dust, whereas 9-Fluorenone (9-FLUONE) prevailing OPAHs. The molecular diagnostic ratio (MDR) of 2-Nitrofluoranthene/1-Nitropyrene indicated the contribution from secondary emission via photochemical reaction as the primary source of NPAHs, while solid fuel combustion and crop residue burning were identified as the essential sources of OPAHs. The human exposure to NPAH/OPAH through the different route of intake suggested dermal contact via dust as the primary pathway of NPAH/OPAH exposure for both adult and children. However, other routes of exposure, for instance, dietary intake or dermal absorption via soil may still be prominent in case of Nepal.

Polychlorinated Biphenyls in Surface Soil from North-East India: Implication for Sources Apportionment and Health-Risk Assessment.

Although India never manufactured polychlorinated biphenyls (PCBs), evidence suggests the prevalence of PCBs in multi-environmental matrices. Despite the high level of PCBs that has been detailed in the major urban areas of India, little is known about the fate and sources of PCBs in Northeast India (NEI). This motivated us to investigate the contamination level and sources of PCBs in the surface soil. In this study, the environmental concentration and sources of 25 PCBs were investigated in surface soil (n = 60) from three states of NEI (lower Assam, Manipur, and Tripura). Additionally, the relationship between soil organic carbon (SOC) and PCBs was studied to investigate the role of SOC in the distribution of PCBs. Overall, the concentration of ∑25PCBs ranged from 2950 to 16,700 pg/g dw (median 7080 pg/g dw), 3580-21,100 pg/g dw (median 11,500 pg/g dw), and 2040-11,000 pg/g dw (median 4270 pg/g dw) in Assam, Manipur, and Tripura, respectively. Low-chlorinated PCBs were more prevalent than highly chlorinated PCBs. PCB-49 was identified as the most abundant in soil, followed by PCB-52, and accounted for 13% and 12.9% of ∑25PCBs, respectively. With respect to land use categories, high ∑25PCBs were related to grassland areas and proximity to the roadside soil. The principal component analysis indicated emissions from technical PCB mixtures, combustion of municipal wastes/residential wood, incineration of hospital wastes, and e-waste recycling/disposal sites are the real sources of PCBs. Marginally, a moderate-to-weak correlation of SOC with ∑25PCBs (R2 = 0.144, p < 0.05) and their homologs (R2 = 0.280-0.365, p < 0.05) indicated the little role of SOC in the dispersion of PCBs. The estimated toxic equivalency of dioxin-like PCBs suggested that PCB-126 is the most toxic contaminant to endanger the human population.

Chemometric evaluation of heavy metal pollutions in Patna region of the Ganges alluvial plain, India: implication for source apportionment and health risk assessment.

While metal pollution and distribution in soil are well documented for many countries, the situation is more serious in developing countries because of the rapid increase in industrialization and urbanization during last decades. Although it is well documented in developed countries, data about substantial metal pollution in Indian soil, especially in eastern Ganges alluvial plain (GAP), are limited. In this study, eight different blocks of Patna district located in eastern GAP were selected to investigate the contamination, accumulation, and sources of metals in surface soil considering different land use types. Additionally, human health risk assessment was estimated to mark the potential carcinogenic and non-carcinogenic effect of metals in soil. The concentration of all metals (except Pb) in soil was below the Indian standard limit of the potential toxic element for agricultural soil. Pb was the most abundant in soil, followed by Zn and Cu, and accounted for 52, 33 and 8% of the total metal. In terms of land use types, roadside soil detected higher concentrations of all metals, followed by park/grassland soil. Principal component analysis results indicated traffic pollution and industrial emissions are the major sources of heavy metals in soil. This was further confirmed by strong inter-correlation of heavy metals (Cd, Cr, Ni, Cu and Pb). Human health risk assessment results indicated ingestion via soil as the primary pathway of heavy metal exposure to both adults and children population. The estimated hazard index was highest for Pb, suggesting significant non-carcinogenic effect to both adults and children population. The children were more prone to the non-carcinogenic effect of Pb than adults. However, relatively low cancer risk value estimated for all metals suggested non-significant carcinogenic risk in the soil.

Altitudinal and spatial variations of polycyclic aromatic hydrocarbons in Nepal: Implications on source apportionment and risk assessment.

Although several global/regional studies have detailed the high level of polycyclic aromatic hydrocarbons in urban areas worldwide, unfortunately, Nepal has never been part of any global/regional regular monitoring plan. Despite few sporadic studies exist, the systematic monitoring and integrated concentration of PAHs in urban region of Nepal are lacking. In this study, the concentrations, sources, and health risk assessment of 16 PAHs in air (n = 34) were investigated in suspected source areas/more densely populated regions of Nepal. Four potential source areas in Nepal were focused as it was conjectured that urban centers in plain areas (Birgunj and Biratnagar) would possibly be more influenced by PAHs as a result of intense biomass/crop residue burning than those in hilly areas (Kathmandu and Pokhara). The overall concentrations of ∑16PAHs ranged from 4.3 to 131 ng/m3 (median 33.3 ng/m3). ∑16PAH concentrations in plain areas were two folds higher than those in hilly areas. PHE was the most abundant followed by FLUA, PYR, and NAP, which accounted for 36%, 15%, 12%, and 9% of ∑16PAHs, respectively. Principal component analysis confirmed that PAHs in highly urbanized areas (Kathmandu and Pokhara) were related to diesel exhausts and coal combustion, while PAHs in less urbanized regions (Birgunj and Biratnagar) originated from biomass and domestic wood combustions. Furthermore, in the urban areas of Nepal, vehicular emission could also influence atmospheric PAHs. The lifetime cancer risk per million populations due to PAH exposures was estimated to be higher for plain areas than that for hilly areas, suggesting a relatively greater risk of cancer in people living in plain areas.

Concentration and spatial distribution of organophosphate esters in the soil-sediment profile of Kathmandu Valley, Nepal: Implication for risk assessment.

Despite the fact that soil and sediments, which act as a sink or potential source of organic pollutants, have been polluted with organophosphate esters (OPEs) around the globe, extremely constrained data is accessible on environmental concentration and fate of OPEs in solid matrices in whole of the South Asia particularly if there should be an occurrence in Nepal. In this study, surface soil (N=19) and sediments samples (N=20) were analyzed for eight different OPE in Kathmandu Valley during October 2014. The concentration of ∑8OPE measured in sediments samples was 12 times higher than soil and ranged 983-7460ng/g dw (median 2210ng/g dw) and 65-27,500ng/g dw (186ng/g dw), respectively. TMPP was most abundant in soil followed by TCIPP, TEHP and EHDPHP and ranged 17-25,300ng/g dw (41.3ng/g dw), 11.2-911ng/g dw (31.7ng/g dw), 8.52-858ng/g dw (26.1ng/g dw) and 10.2-114ng/g dw (25.6ng/g dw), respectively. TEHP was most prevalent in sediments followed by TMPP and EHDPHP and were in the range of 657-3020ng/g dw (median 1140ng/g dw), 267-2630ng/g dw (median 815g/g dw), 34-418ng/g (median 131ng/g dw), respectively. The sources of the high level of OPEs in soil was related to the end point use of consumer materials, traffic emission, and close proximity to commercial and industrial areas; while domestic sewage discharges and effluents from carpet industry were identified as the possible entry of OPE in sediments. Total organic carbon (TOC) and black carbon (BC) content in soil were moderately and positively correlated with ∑8OPE indicating more or less influence of soil organic carbon. The health risk assessment suggested dermal absorption of OPEs via soil is the primary pathway of human exposure to the general population. The significantly high-risk quotient (RQ) estimated for ∑8OPEs especially TMPP and TPHP suggested significant potential adverse risk for aquatic organisms.

Polycyclic aromatic hydrocarbons in house dust and surface soil in major urban regions of Nepal: Implication on source apportionment and toxicological effect.

Urban centers have turned to be the provincial store for resource consumptions and source releases of different types of semi-volatile organic compounds (SVOCs) including polycyclic aromatic hydrocarbons (PAHs), bringing about boundless environmental pollutions, among different issues. Human prosperity inside urban communities is unambiguously dependent on the status of urban soils and house dusts. However, environmental occurrence and sources of release of these SVOCs are challenging in Nepalese cities, as exceptionally very limited data are accessible. This motivated us to explore the environmental fate, their source/sink susceptibilities and health risk associated with PAHs. In this study, we investigated the contamination level, environmental fate and sources/sink of 16 EPA's priority pollutants in surface soil and house dusts from four major cities of Nepal. Additionally, the toxicological effect of individual PAH was studied to assess the health risk of PAHs. Generally, the concentrations of ∑16PAHs in surface soil were 1.5 times higher than house dust, and ranged 767-6770ng/g dry weight (dw) (median 1810ng/g dw), and 747-4910 dw (median 1320ng/g dw), respectively. High molecular weight-PAHs both in soil and dust were more abundant than low molecular weight-PAHs, suggesting the dominance of pyrogenic source. Moderate to weak correlation of TOC and BC with PAHs in soil and dust suggested little or no role of soil organic carbon in sorption of PAHs. Source diagnostic ratio and principal component analysis indicated fossil fuel combustion, traffic/vehicular emissions and combustion of biomass are the principal sources of PAHs contamination in Nepalese urban environment. The high average TEQ value of PAHs in soil than dust suggested high risk of soil carcinogenicity compared to dust.

Organophosphate ester flame retardants in Nepalese soil: Spatial distribution, source apportionment and air-soil exchange assessment.

Despite soil being the major terrestrial environmental reservoir and one of the significant sinks for many hydrophobic organic compounds including organophosphate ester flame retardants (OPFRs), limited information is available about concentration and fate of OPFRs contamination in urban soil in general and especially in case of Nepal. This study investigates the environmental concentration, spatial distribution and source apportionment of eight OPFRs in surface soil (n = 28) from four major cities of Nepal with special interest on air-soil exchange. Overall, significantly high concentrations of ∑8OPFR were measured in soil ranging from 25-27,900 ng/g dw (median 248 ng/g dw). In terms of compositional pattern, tris(methyl phenyl) phosphate (TMPP) was the most abundant phosphorus chemical in soil, followed by tris(2-chloroisopropyl) phosphate (TCIPP), and accounted for 35-49% and 8-25% of ∑8OPFRs, respectively. The high level of these OPFRs was attributed to local sources as opposed to transboundary influence from remote areas. A Spearman's rank correlation analysis exhibited weak correlation of ∑8OPFRs with TOC (Rho = 0.117, p < 0.05) and BC (Rho = 0.007, p < 0.05), suggesting little or no influence of TOC and BC on the concentration of ∑8OPFRs. The fugacity fraction (ff) results indicated a strong influence of soil contamination on atmospheric level of OPFRs via volatilization.

Environmental concentration and atmospheric deposition of halogenated flame retardants in soil from Nepal: Source apportionment and soil-air partitioning.

While various investigations have been driven on polybrominated diphenyl ethers (PBDEs) and other flame retardants (FRs) in different framework around the world, information about contamination and fate of PBDEs and other FRs in developing countries especially in the Indian subcontinent is uncommon. Nepal being located in the Indian subcontinent, very little is known about contamination level of semi-volatile organic pollutants discharged into the environment. This motivated us to investigate the environmental fate of halogenated flame retardant (HFRs) in Nepalese condition. In this study, we investigated the concentration, fate, and sources of 9 PBDEs, 2 dechlorane plus isomers (DPs), and 6 novel brominated flame retardants (NBFRs). Moreover, air-soil exchange and soil-air partitioning were also evaluated to characterize the pattern of air-soil exchange and environmental fate. In general, the concentrations of NBFRs in soil were more prevalent than PBDEs and DPs, and accounted 95% of ∑HFRs. By and large, the concentrations of NBFRs and DPs were measured high in Kathmandu, while PBDEs level exceeded in Pokhara. Principal component analysis (PCA) study suggested contributions from commercial penta-, octa-, and deca-BDEs products and de-bromination of highly brominated PBDEs as the significant source of PBDEs. Likewise, low fanti ratio suggested DPs in soil might have originated from long-range atmospheric transport from remote areas, while high levels of decabromodiphenyl ethane (DBDPE) in soil were linked with the use of wide varieties of consumer products. The estimated fugacity fraction (ff) for individual HFR was quite lower (<0.05) than equilibrium value, suggesting that deposition and net transport from air to the soil is overwhelming. Soil-air partitioning study revealed neither octanol-air partition coefficient (KOA) nor black carbon partition coefficient (KBC-A) is an appropriate surrogate for soil organic matter (SOM), subsequently, absorption by SOM has no or little role in the partitioning of HFRs.

Occurrence and fate of organophosphate ester flame retardants and plasticizers in indoor air and dust of Nepal: Implication for human exposure.

The present study was carried out in Nepal, a landlocked country located between world's two most populous countries i.e. India and China. In this study, the occurrence, profiles, spatial distributions and fate of eight organophosphate ester flame retardants (OPFRs) were investigated in indoor air and house dust. Overall, the concentrations of ∑OPFR were in the range of 153-12100 ng/g (median732 ng/g) and 0.32-64 ng/m3 (median 5.2 ng/m3) in house dust and indoor air, respectively. The sources of high OPFR in the indoor environment could be from locally used wide variety of consumer products and building materials in Nepalese houses. Significantly, high concentration of tri-cresyl phosphate (TMPP) was found both in air and dust, while tri (2-ethylhexyl) phosphate (TEHP) had the highest concentration in air samples. It might be due to fact that the high concentrations of TMPP are related to intense traffic and/or nearby airports. On the other hand, significantly high concentration of TEHP could be due to anthropogenic activities. Only TEHP showed positive correlation between indoor air and house dust (Rho = 0.517, p < 0.01), while rest of compounds were either less correlated or not correlated at all. The estimated human exposure to ∑OPFR via different pathway of intake suggested dermal absorption via indoor dust as major pathway of human exposure to both children and adult population. However, other pathways of OPFR intake such as dietary or dermal absorption via soil may still be significant in case of Nepal.

Polychlorinated biphenyls in Nepalese surface soils: Spatial distribution, air-soil exchange, and soil-air partitioning.

Regardless of the ban on the polychlorinated biphenyls (PCBs) decade ago, significant measures of PCBs are still transmitted from essential sources in cities and are all inclusive ecological contaminants around the world. In this study, the concentrations of PCBs in soil, the air-soil exchange of PCBs, and the soil-air partitioning coefficient (KSA) of PCBs were investigated in four noteworthy urban areas in Nepal. Overall, the concentrations of ∑30PCBs ranged from 10 to 59.4ng/g dry weight; dw (mean 12.2ng/g ±11.2ng/g dw). The hexa-CBs (22-31%) was most dominant among several PCB-homologues, followed by tetra-CBs (20-29%), hepta-CBs (12-21%), penta-CBs (15-17%) and tri-CBs (9-19%). The sources of elevated level of PCBs discharge in Nepalese soil was identified as emission from transformer oil, lubricants, breaker oil, cutting oil and paints, and cable insulation. Slightly strong correlation of PCBs with TOC than BC demonstrated that amorphous organic matter (AOM) assumes a more critical part in holding of PCBs than BC in Nepalese soil. The fugacity fraction (ff) results indicated the soil being the source of PCB in air through volatilization and net transport from soil to air. The soil-air partitioning coefficient study suggests the absorption by soil organic matter control soil-air partitioning of PCBs. Slightly weak but positive correlation of measured Log KSA with Log KOA (R2 = 0.483) and Log KBC-A (R2 = 0.438) suggests that both Log KOA and Log KBC-A can predict soil-air partitioning to lesser extent for PCBs.