Influence of curing protocol on selected properties of light-curing polymers: degree of conversion, volume contraction, elastic modulus, and glass transition temperature.

OBJECTIVES: The purpose of this study was to investigate the effect of light-curing protocol on degree of conversion (DC), volume contraction (C), elastic modulus (E), and glass transition temperature (T(g)) as measured on a model polymer. It was a further aim to correlate the measured values with each other. METHODS: Different light-curing protocols were used in order to investigate the influence of energy density (ED), power density (PD), and mode of cure on the properties. The modes of cure were continuous, pulse-delay, and stepped irradiation. DC was measured by Raman micro-spectroscopy. C was determined by pycnometry and a density column. E was measured by a dynamic mechanical analyzer (DMA), and T(g) was measured by differential scanning calorimetry (DSC). Data were submitted to two- and three-way ANOVA, and linear regression analyses. RESULTS: ED, PD, and mode of cure influenced DC, C, E, and T(g) of the polymer. A significant positive correlation was found between ED and DC (r=0.58), ED and E (r=0.51), and ED and T(g) (r=0.44). Taken together, ED and PD were significantly related to DC and E. The regression coefficient was positive for ED and negative for PD. Significant positive correlations were detected between DC and C (r=0.54), DC and E (r=0.61), and DC and T(g) (r=0.53). Comparisons between continuous and pulse-delay modes of cure showed significant influence of mode of cure: pulse-delay curing resulted in decreased DC, decreased C, and decreased T(g). Influence of mode of cure, when comparing continuous and step modes of cure, was more ambiguous. SIGNIFICANCE: A complex relationship exists between curing protocol, microstructure of the resin and the investigated properties. The overall performance of a composite is thus indirectly affected by the curing protocol adopted, and the desired reduction of C may be in fact a consequence of the decrease in DC.

Softening and elution of monomers in ethanol.

OBJECTIVES: The purpose of this study was to investigate the effect of light-curing protocol on softening and elution of monomers in ethanol as measured on a model polymer. It was a further aim to correlate the measured values with previously reported data on degree of conversion and glass transition temperature for the same polymer and curing protocols. METHODS: Different light-curing protocols were used in order to investigate the influence of energy density, power density, and mode of cure on the properties of a model polymer. The modes of cure were continuous, pulse-delay, and stepped irradiation of the specimens. Wallace hardness was used to determine the softening of the polymer after storage in ethanol for 24h. Elution of monomers from the polymer was assessed after 7 days in ethanol by means of high-pressure liquid chromatography (HPLC). Data were submitted to two- and three-way analysis of variance (ANOVA), Newman-Keuls' multiple comparison test, and linear regression analysis. RESULTS: Energy density, power density, and mode of cure of the polymer influenced the softening and elution of monomers in ethanol. As energy density increased, softening and elution in ethanol decreased. At same energy density, the influence of power density varied with the mode of cure. When compared to the continuous mode of cure, and at same energy density, pulse-delay irradiation resulted in polymers that in general were more susceptible to softening, but eluted monomers to a lower extent. Less elution was also found with step-cured polymers. Significant, negative correlations were detected between softening and elution in ethanol, respectively, and degree of conversion and between softening and elution in ethanol, respectively, and glass transition temperature. SIGNIFICANCE: A complex relationship exists between curing protocol and the properties selected for investigation. The effect of different combinations of exposure periods and power densities are important to understanding how the curing protocol affects the properties of polymer-based materials.

Class II restorations: influence of a liner with rubbery qualities on the occurrence and size of cervical gaps.

The aim of this study was to evaluate the ability of new rubbery liners, used as a cervical increment, to relieve contraction stress and thereby reduce the formation of cervical gaps in class II composite restorations. The investigated liners were made of polyester-acrylate (PE(1), PE(2) or PE(3)) or silicone-acrylate (S), mixed with UDMA, without (A, B, C, D) or with HEMA (AH, BH, CH, DH). A silanized filler was added to the mixture, DH, to give composites with 20, 40, 60, and 70% (w/w) of filler (DHF20, DHF40, DHF60, DHF70, respectively). The presence and width of cervical gaps were determined using a light microscope. Statistical analysis showed that six of the 12 rubbery liners (AH-DH, DHF20-DHF40) significantly decreased gap formation in comparison with the control group. In addition, the polymerization shrinkage, flow, and strain capacity of these liners were measured and the influence of these factors on gap formation was examined. Two- and three-dimensional regression analyses showed significantly negative linear correlations between gap formation and strain capacity, and between gap formation and flow, and a significantly positive linear correlation between gap formation and shrinkage.

Volume contraction in photocured dental resins: the shrinkage-conversion relationship revisited.

UNLABELLED: Polymerization shrinkage and degree of conversion (DC) of resin composites are closely related manifestations of the same process. Ideal dental composite would show an optimal degree of conversion and minimal polymerization shrinkage. These seem to be antagonistic goals, as increased monomer conversion invariably leads to high polymerization shrinkage values. OBJECTIVES: This paper aims at accurately determining the polymerization volume contraction of experimental neat resins and to link it to the number of actual vinyl double bonds converted in single ones instead of, as generally done, to the degree of conversion. METHODS: Different mixtures of Bis-GMA/TEGDMA (traditionally used monomers) were analyzed. Contraction of the polymers was determined by pycnometry and the use of a density column. DC was determined by the use of Raman spectrometry. RESULTS: An univocal relationship has been found between the volume contraction and the actual number of vinyl double bonds converted into single ones. A contraction value of 20.39 cm3/mole (of converted C=C) was deduced from 27 measurements. SIGNIFICANCE: This relationship helps in finding solutions to the polymerization shrinkage problem. A reduction of the polymerization shrinkage due to the chemical reaction may obviously be expected from the addition of molecules allowing a decrease in the number of double bonds converted per unit volume of resin matrix, while maintaining the degree of conversion (of Bis-GMA and TEGDMA) and thus the mechanical properties. Further research will be directed at this objective.