Comparative study of different ultrasound based hybrid oxidation approaches for treatment of real effluent from coke oven plant.

The present study investigates the treatment of real coke plant effluent utilising several ultrasound-based hybrid oxidation approaches including Ultrasound (US) alone, US + catalyst, US + H2O2, US + Fenton, US + Ozone, and US + Peroxone, with main objective as maximizing the reduction of chemical oxygen demand (COD). Ultrasonic horn at power of 130 W, frequency as 20 kHz and duty cycle as 70% was applied. Study with varying catalyst (TiO2) dose from 0.5 g/L - 2 g/L revealed 1 g/L as the optimum dose resulting in 65.15% reduction in COD. A 40 ml/L dose of H2O2 was shown to be optimal, giving an 81.96% reduction in COD, based on the study of varied doses of H2O2 from 20 ml/L to 60 ml/L. US + Fenton reagent combination at optimum Fe2+/H2O2 (w/v) ratio of 1:1 resulted in a COD reduction of 85.29% whereas reduction of COD as 81.75% was obtained at the optimum flow rate of ozone as 1 LPM for US + Ozone approach. US + Peroxone demonstrated the best efficiency (90.48%) for COD reduction. To find the toxicity effects, the treated (US + peroxone) and non-treated samples were tested for the growth of bacterial cultures. It was observed that the toxicity of the treated sample increased only marginally after treatment. High-resolution liquid chromatography mass spectrometry (HR-LCMS) analysis was also performed to establish intermediate compounds. Overall, the coupling of ultrasound with oxidation processes produced better results with US + Peroxone established as best treatment approach for coke plant effluent.

Sonochemical synthesis of Ce-TiO2 nanocatalyst and subsequent application for treatment of real textile industry effluent.

Treatment of real textile industry effluent using photocatalysis, sonocatalysis, sonophotocatalysis and H2O2 assisted sonophotocatalysis have been studied based on the use of Ce-TiO2 nanocatalyst synthesized using sonochemical co-precipitation method. Characterization studies of the obtained catalyst revealed crystallite size as 1.44 nm with particles having spherical morphology. A shift of the absorption edge to the visible light range was also observed in UV-Vis diffuse reflectance spectra (UV-DRS) analysis. The effects of different operational parameters viz catalyst dose (0.5 g/L-2 g/L), temperature (30 °C-55 °C) and pH (3-12) on the COD reduction were studied. The reduction in the COD was higher at lower pH and the optimum temperature established was 45 °C. It was also elucidated that the required catalyst dose was lesser in combined sonophotocatalysis when compared with individual photocatalysis and sonocatalysis. Combination of processes and addition of oxidants increased the COD reduction with the sonophotocatalytic oxidation combined with H2O2 treatment showing the best results for COD reduction (84.75%). The highest reduction in COD for photocatalysis was only 45.09% and for sonocatalysis, it was marginally higher at 58.62%. The highest reduction in COD achieved by sonophotocatalysis was 64.41%. Toxicity tests coupled with Liquid Chromatography Mass Spectrometry (LC-MS) analysis revealed that there were no additional toxic intermediates added to the system during the treatment. Kinetic study allowed establishing that generalized kinetic model fits the experimental results well. Overall, the combined advanced oxidation processes showed better results than the individual processes with higher COD reduction and lower requirement of the catalyst.

Imbibitional redox and hormonal priming revealed regulation of oxidative window as a key factor for progression of germination of indica rice cultivars.

In the present investigation we have manipulated seeds of two indica rice cultivars, differing in sensitivity towards salinity stress (Oryza sativa L. cv. IR29 and Pokkali), with different combination of germination influencing hormones and redox modulating agents [500 µM Gibberellic acid (GA) + 20 mM H2O2, 500 µM GA + 100 µM Diphenyleneiodonium chloride (DPI), 500 µM GA + 500 µM N,N-dimethylthiourea (DMTU), 30 µM Triadimefon (TDM) + 100 µM DPI, 30 µM TDM + 500 µM DMTU] during early imbibition for exploring significance of regulation of oxidative window during germination. Reactive oxygen species (ROS)-antioxidant (AOX) interaction dynamics, assessed through redox metabolic fingerprints revealed significant changes in oxidative window of germinating tissue under redox and hormonal priming. GA (500 µM) + H2O2 (20 mM) priming formed favorable redox cue and opened the oxidative window for germination, whereas GA (500 µM) + DPI (100 µM), GA (500 µM) + DMTU (500 µM) and TDM (30 µM) + DPI (100 µM) combination failed to generate redox cue for opening the oxidative window at metabolic interface. Assessment of transcript abundance of genes of enzymes of central redox hub (RBOH-SOD-ASC-GSH/CAT pathway) further confirmed the transcriptional reprogramming of genes (Osrboh, OsSodCc2, OsCatA, OsAPx2, OsGRase) necessary for antioxidant-coupled origin of redox cue for germination. Assessment of pool of gibberellic acid, abscisic acid and jasmonic acid revealed a close connection between the hormonal homeostasis and internal redox cue. Role of oxidative window generated during metabolic reactivation phase for successful progression of germination is suggested. Supplementary Information: The online version contains supplementary material available at 10.1007/s12298-023-01303-x.