Plasmonic enhancement of photovoltaic characteristics of organic solar cells by employing parabola nanostructures at the back of the solar cell.

In this paper, we demonstrate the enhanced performance of organic solar cells (OSCs) comprising low band gap photoactive layers (PMDPP3T:PC70BM) and 2-dimensional (2D) arrays of either Ag nano-spheres, nano-hemispheres, or nano-parabolas embedded at the back of the OSCs. Finite-difference time-domain (FDTD) simulations were performed to compare the performance of the OSCs containing the different plasmonic nanostructures, in terms of optical absorption, short circuit current density (JSC) and power conversion efficiency (PCE). The results demonstrate that single junction OSCs consisting of this new active layer polymer (PMDPP3T), blended with PC70BM, and plasmonic nanostructures at the back of the OSC can enhance the optical absorption in the visible and the NIR region. We demonstrate that the aspect ratio of the nanoparticles embedded at the back of OSCs is a vital parameter for light absorption enhancement. It is observed that the performance in terms of JSC and PCE enhancement of OSC having 2D arrays of Ag nano-parabola at the back of the solar cell improved by 26.41% and 26.37%, respectively, compared to a planar OSC. The enhancement in photon absorption can be attributed due to the enhancement of light scattering from metallic nanostructures near their localized plasmon resonance.

Large-area and low-cost SERS substrates based on a gold-coated nanostructured surface fabricated on a wafer-scale.

This paper demonstrates a method to fabricate plasmonic nanostructures over a large area that can be implemented as SERS substrates. The proposed method comprises batch processes such as spin coating, reactive ion etching, and thin metal deposition. These processes can be performed on large wafers, resulting in large numbers of SERS substrates in a single run. The effects of different process parameters were studied to optimize the performance of the SERS substrates. The study of sensitivity on the optimized SERS substrates was conducted using the SERS-active molecule pMBA. The SERS substrates thus fabricated were able to detect molecule concentrations as low as 100 nM. The SERS substrates were also evaluated for uniformity across the sample and for sample-to-sample reproducibility. Finally, the SERS substrates were applied to demonstrate label-free detection of organophosphorous pesticides - paraoxon ethyl and paraoxon methyl.

Integrated non-volatile plasmonic switches based on phase-change-materials and their application to plasmonic logic circuits.

Integrated photonic devices or circuits that can execute both optical computation and optical data storage are considered as the building blocks for photonic computations beyond the von Neumann architecture. Here, we present non-volatile hybrid electro-optic plasmonic switches as well as novel architectures of non-volatile combinational and sequential logic circuits. The electro-optic switches consist of a plasmonic waveguide having a thin layer of a phase-change-material (PCM). The optical losses in the waveguide are controlled by changing the phase of the PCM from amorphous to crystalline and vice versa. The phase transition process in the PCM can be realized by electrical threshold switching or thermal conduction heating via external electrical heaters or the plasmonic waveguide metal itself as an integrated heater. We have demonstrated that all logic gates, a half adder circuit, as well as sequential circuits can be implemented using the plasmonic switches as the active elements. Moreover, the designs of the plasmonic switches and the logic operations show minimum extinction ratios greater than 20 dB, compact designs, low operating power, and high-speed operations. We combine photonics, plasmonics and electronics on the same platform to design an effective architecture for logic operations.

Periodic arrays of plasmonic crossed-bowtie nanostructures interspaced with plasmonic nanocrosses for highly sensitive LSPR based chemical and biological sensing.

In this paper, we present novel localized surface plasmon resonance (LSPR) sensors based on periodic arrays of gold crossed-bowtie nanostructures interspaced with gold nanocross pillars. Finite difference time domain (FDTD) numerical simulations were carried out to model bulk sensors as well as localized sensors based on the plasmonic nanostructures being proposed. The geometrical parameters of the plasmonic nanostructures are varied to obtain the best possible sensing performance in terms of sensitivity and figure of merit. A very high bulk sensitivity of 1753 nm per unit change in refractive index (nm RIU-1), with a figure of merit for bulk sensing (FOMbulk) of 3.65 RIU-1, is obtained for these plasmonic nanostructures. This value of bulk sensitivity is higher in comparison to previously proposed LSPR sensors based on plasmonic nanopillars and nanocrosses. Moreover, the optimized LSPR sensors being proposed in this paper provide maximum sensitivity of localized refractive index sensing of 70 nm/nm with a FOMlocalized of 0.33 nm-1. This sensitivity of localized refractive index sensing is the highest reported thus far in comparison with previously reported LSPR sensors. It is also demonstrated that the operating resonance wavelengths of these LSPR sensors can be controllably tuned for specific applications by changing the dimensions of the plasmonic nanostructures.

Nanostructured plasmonic chips employing nanopillar and nanoring hole arrays for enhanced sensitivity of SPR-based biosensing.

We present a theoretical analysis of the different nanostructured plasmonic sensor chips-consisting of plasmonic nanostructures present on the surface of plasmonic thin films-interrogated using the Kretschmann configuration for highly sensitive localized sensing, with high tunability from the visible to the infrared regions. Rigorous coupled-wave analysis is performed to analyze all the proposed nanostructured sensor chips and compare their sensing performance. The sensitivity parameters are defined to focus on the detection of a thin layer of biomolecules on the surface of nanostructures. The dimensions of the nanostructures and the incident angle shift the plasmon resonance wavelengths and can be used to tune the operating wavelength. The nanostructured films create local regions of high electric fields, which results in enhanced sensitivity of the proposed structures. The proposed sensors can be used in surface plasmon resonance imaging to detect multiple biomolecules in a single measurement. An extremely high surface sensitivity and figure of merit (FOMS) of 91 nm nm-1 and 0.59 nm-1 has been found, respectively, for one of the proposed nanostructured sensing platforms. Moreover, we demonstrate a very high differential reflectance of 55% per nm thickness of the biolayer.

Plasmonic nanoantennas on VO2 films for active switching of near-field intensity and radiation from nanoemitters.

In this paper, we propose novel plasmonic switches based on plasmonic nanoantennas lying on top of a thin film of a phase change material such as vanadium dioxide (VO2), such that the near-field properties of these nanoantennas can be actively switched by varying the phase of the VO2 film. We employ finite difference time domain (FDTD) simulations to first demonstrate that the near-field intensity in the vicinity of the plasmonic nanoantennas can be substantially switched by changing the phase of the vanadium dioxide film from the semiconductor state to the metallic state. We demonstrate that a ring-bowtie nanoantenna (RBN) switch can switch the near-field intensity by ∼ 59.5 times and ring-rhombus nanoantenna (RRN) switch can switch the near-field intensity by a factor of ∼ 80.8. These values of the maximum intensity switching ratios are substantially higher than those previously reported in the literature. In addition, we optimize the various geometrical parameters of the plasmonic switches to maximize the intensity switching ratio and to understand how the different parameters affect the performance of the plasmonic switches. In this paper, we also show that the intensity of emission from a nanoemitter placed in the gap between the two arms of a plasmonic nanoantenna can be significantly switched by changing the phase of the VO2 film between its semiconductor state and the metallic state. To quantify the switching of emission from the nanoemitters placed in the near-field of the nanoantennas, we define and calculate a parameter, called FESR, the ratio of fluorescent enhancement factors in the on-state and off-state of the plasmonic switch. The maximum fluorescence enhancement switching ratio (FESR) of ∼ 163 is obtained for the RBN switch and FESR of ∼ 200 is obtained for RRN switch. The plasmonic switches being proposed by us can be easily fabricated by employing the conventional nanofabrication and thin film deposition processes.

Plasmonic and photonic enhancement of photovoltaic characteristics of indium-rich InGaN p-n junction solar cells.

In this paper, we demonstrate via Finite-difference time-domain (FDTD) simulations that the performance of indium-rich InxGa1-xN (x = 0.6) p-n junction thin-film solar cells is improved by incorporating an integrated structure of a 2-dimensional (2D) array of ITO nanodiscs on the top surface and a 2D array of Ag nanodiscs in the active layer above the Ag back reflector of the solar cell. The bottom Ag nanodiscs primarily enhance the absorption of longer wavelengths by coupling incident light into surface plasmon resonance (SPR) and waveguide modes. The top ITO nanodiscs enhance the middle wavelengths (400 nm to 800 nm) by coupling the incident light to photonic modes in the active layer. Thus, the integrated structure of nanodisc arrays leads to a very high absorption in the active region in broad spectral range (> 0.85 for wavelengths lying between 350 nm and 800 nm), significantly increasing the short circuit current density (Jsc) and power conversion efficiency (PCE) of the solar cell. In the proposed solar cells, the geometries of the silver and ITO nanodiscs were optimized to obtain the maximum possible values of the Jsc. The highest enhancements in Jsc and PCE of ∼25% and ∼26%, respectively, were obtained in a solar cell containing the integrated structure of ITO and Ag nanodisc arrays. Moreover, the performance of these cells was examined under oblique light incidence and it was observed that the solar cells containing the integrated structure of nanodisc arrays have a significantly larger value of Jsc when compared to the cells having no nanostructures or having only the top ITO nanodisc array or only the bottom Ag nanodisc array.

Palladium-coated narrow groove plasmonic nanogratings for highly sensitive hydrogen sensing.

In this paper, we propose novel plasmonic hydrogen sensors based on palladium coated narrow-groove plasmonic nanogratings for sensing of hydrogen gas at visible and near-infrared wavelengths. These narrow-groove plasmonic nanogratings allow the incident light to be coupled directly into plasmonic waveguide modes thereby alleviating the need for bulky coupling methods to be employed. We carried out numerical simulations of the palladium coated narrow-groove plasmonic nanogratings using rigorous coupled wave analysis (RCWA). When palladium is exposed to varying concentrations of hydrogen gas, palladium undergoes phase transition to palladium hydride (PdH x ), such that there are different atomic ratios 'x' (H/Pd) of hydrogen present in the palladium hydride (PdH x ) depending on the concentration of the hydrogen gas. RCWA simulations were performed to obtain the reflectance spectral response of the Pd coated nanogratings in both the absence and presence of hydrogen, for various atomic ratios 'x' (x ∼ 0.125 to 0.65) in palladium hydride (PdH x ). The results of the RCWA simulations showed that as the dielectric permittivity of the palladium (Pd) thin film layers in between the adjacent walls of the plasmonic nanogratings changes upon exposure to hydrogen, significant shifts in the plasmon resonance wavelength (maximum Δλ being ∼80 nm for an increase in the value of the atomic ratio 'x' from 0 to 0.65) as well as changes in the differential reflection spectra are observed. The structural parameters of these Pd coated narrow groove nanogratings-such as the nanograting height, gap between the nanograting walls, thickness of the palladium layer, periodicity of the nanogratings-were varied to maximize the shift in the plasmon resonance wavelength as well as the differential reflectance when these nanostructures are exposed to different concentrations of hydrogen (i.e. for different atomic ratios 'x' in PdH x ).

Steerable plasmonic nanoantennas: active steering of radiation patterns using phase change materials.

In this article, we describe active steering of radiation patterns by complex nanoantenna structures - called steerable nanoantennas (SNs) - formed by combining multiple Yagi-Uda nanoantennas and thin films of a phase change material (VO2). The radiation patterns of these nanoantennas can be actively steered by tunably changing the phase of the VO2 thin films from the semiconductor phase to the metallic phase. Moreover, the nanoantennas enable steering of the radiation patterns 'in the plane' of the nanoantennas. We demonstrate that the radiation pattern's maximum achievable steering is 90° for a two-element steerable nanoantenna when the phase of the VO2 thin film is changed from the semiconductor phase to the metallic phase. Moreover, it was observed that the radiation pattern of the steerable nanoantennas being proposed in our paper can be designed to be much more directed than previously reported steerable nanoantennas. By employing a four element steerable nanoantenna, we also demonstrate a full 360° active steering of the radiation pattern. This steerable nanoantenna consists of four coplanar Yagi-Uda nanoantennas, with each Yagi-Uda nanoantenna being present inside a VO2 thin film but each individually addressable VO2 thin film being separated from the other VO2 films by an air gap. We demonstrate that the radiation pattern can be tunably steered in 12 different directions using this four element steerable nanoantenna depending on the states of the four VO2 thin films. The steerable nanoantennas can find applications in areas such as tunable on chip plasmonic interconnects, networks on chip, or for selective excitation of fluorophores on a sensor chip.

Tandem organic solar cells containing plasmonic nanospheres and nanostars for enhancement in short circuit current density.

In this paper, we propose double junction tandem organic solar cells with PTB7:PC70BM and PDPPSDTPS:PC60BM as the polymeric active materials to cover the wide solar spectrum from 300 nm to 1150 nm. We present novel designs and finite-difference time-domain (FDTD) simulation results of plasmonic double junction tandem OSCs in which Ag nanospheres are present over the top surface of the OSC and Ag nanostars are present in the bottom subcell which substantially enhance the absorption, short circuit current density, and efficiency of the OSC as compared to the reference tandem OSCs that do not contain any nanoparticles. Different geometries of the plasmonic nanoparticles such as nanospheres and nanostars were used in the top subcell and the bottom subcell, respectively, so that the absorption in the different spectral regimes - corresponding to the bandgaps of the active layers in the two subcells (PTB7:PC70BM in the top subcell and LBG:PC60BM in the bottom subcell) - could be enhanced. The thickness of the bottom subcell active layer as well as the geometries of the plasmonic nanoparticles were optimized such that the short circuit current densities in the two subcells could be matched in the tandem OSC. An overall enhancement of 26% in the short circuit current density was achieved in a tandem OSC containing the optimized Ag nanospheres over the top surface and Ag nanostars inside the bottom subcell active layer. The presence of plasmonic nanoparticles along with the wide spectrum absorption band of the active materials in the tandem OSC leads to a typical power conversion efficiency of ∼ 15.4%, which is higher than that of a reference tandem organic solar cell (12.25%) that does not contain any nanoparticles.

Bridged-bowtie and cross bridged-bowtie nanohole arrays as SERS substrates with hotspot tunability and multi-wavelength SERS response.

In this paper, we present bridged-bowtie nanohole arrays and cross bridged-bowtie nanohole arrays in a gold thin film as surface enhanced Raman scattering (SERS) substrates. These SERS substrates not only exhibit large electromagnetic enhancement of SERS but also have the SERS enhancement spread over a much larger area than what could be present in SERS substrates consisting of nanopillar arrays or nanopillar plasmonic nanoantennas. Numerical simulations based on the finite difference time domain (FDTD) method are employed to determine electric field enhancement factors (EFs) and therefore the electromagnetic SERS enhancement factor for these SERS substrates. It was observed that bridged-bowtie nanohole arrays and cross bridge-bowtie nanohole arrays exhibit a highest electromagnetic SERS enhancement factor (EF) of ~109, which is orders of magnitude higher than what has been previously reported for nanohole arrays as SERS substrates. This electromagnetic SERS EF (of ~109) is spread over a hotspot region of ~100 nm2 (in each periodic unit of the array), which is larger than the case of nanopillar arrays. In addition, it was observed that an electromagnetic SERS enhancement factor of at least 108 is spread over a large area (500 nm2 in each periodic unit of the array), thus increasing the average enhancement factor. It was observed that the bridged-bowtie nanohole arrays and the cross bridged-bowtie nanohole arrays can be employed as effective SERS substrates in both the transmission mode and the reflection mode. The resonance wavelength of these arrays of nanoholes can be tuned by altering the size of the nanoholes. The effects of varying the gold film thickness and the diameter of the bridged-bowtie nanoholes forming the arrays were also analyzed. The bridged-bowtie nanohole arrays and cross bridged-bowtie nanohole arrays exhibit very high electric field enhancement factors (EFs) at more than one wavelength, and can therefore be used to obtain a multi-wavelength SERS response. Moreover, the cross bridged-bowtie nanohole array allows the tunability of the position of the hotspot with the rotation of the direction of the polarization of incident field.

Tunable optical switching in the near-infrared spectral regime by employing plasmonic nanoantennas containing phase change materials.

We propose the design of switchable plasmonic nanoantennas (SPNs) that can be employed for optical switching in the near-infrared regime. The proposed SPNs consist of nanoantenna structures made up of a plasmonic metal (gold) such that these nanoantennas are filled with a switchable material (vanadium dioxide). We compare the results of these SPNs with inverted SPN structures that consist of gold nanoantenna structures surrounded by a layer of vanadium dioxide (VO2) on their outer surface. These nanoantennas demonstrate switching of electric-field intensity enhancement (EFIE) between two states (On and Off states), which can be induced thermally, optically or electrically. The On and Off states of the nanoantennas correspond to the metallic and semiconductor states, respectively of the VO2 film inside or around the nanoantennas, as the VO2 film exhibits phase transition from its semiconductor state to the metallic state upon application of thermal, optical, or electrical energy. We employ finite-difference time-domain (FDTD) simulations to demonstrate switching in the EFIE for four different SPN geometries - nanorod-dipole, bowtie, planar trapezoidal toothed log-periodic, and rod-disk - and compare their near-field distributions for the On and Off states of the SPNs. We also demonstrate that the resonance wavelength of the EFIE spectra gets substantially modified when these SPNs switch between the two states.

Tapered fiber nanoprobes: plasmonic nanopillars on tapered optical fiber tips for large EM enhancement.

Employing finite difference time domain simulations, we demonstrate that electromagnetic field enhancement is substantially greater for tapered optical fibers with plasmonic nanostructures present on their tips as compared with non-tapered optical fibers having those plasmonic nanostructures, or with tapered optical fibers without the plasmonic nanostructures. We also carried out fabrication of plasmonic nanostructures on optical fiber tips.

Plasmonic "nano-fingers on nanowires" as SERS substrates.

A surface-enhanced Raman scattering (SERS) substrate based on plasmonics-active metallic nano-finger arrays grown on arrays of triangular-shaped metal-coated silicon nanowire arrays is proposed. Finite-difference time-domain modeling is employed to numerically calculate the effect of the inter-finger gap and the growth angle of the nano-fingers on the magnitude of SERS enhancement and the plasmon resonance wavelength. Additionally, the polarization dependence of the SERS signals from these novel substrates has been studied. A protocol for the fabrication of the proposed SERS substrate is also discussed.

Plane wave scattering from a plasmonic nanowire-film system with the inclusion of non-local effects.

In this paper we present a theoretical analysis of the electromagnetic response of a plasmonic nanowire-film system. The analytical solution accounts for both the dispersive as well as non-local nature of the plasmonic media. The physical structure comprises of a plasmonic nanowire made of a plasmonic metal such as gold or silver placed over a plasmonic film of the same material. Such a nanostructure exhibits a spectrum that is extremely sensitive to various geometric parameters such as spacer thickness and nanowire radius, which makes it favorable for various sensing applications. The non-locality of the plasmonic medium, which can be captured using the hydrodynamic model, significantly affects the resonant wavelength of this system for structures of small dimensions (~ less than 5 nm gap between the nanowire and the film). We present an analytical method that can be used to predict the effect of non-locality on the resonances of the system. To validate the analytical method, we also report a comparison of our analytical solution with a numerical Finite Difference Time Domain analysis (FDTD) of the same structure with the plasmonic medium being treated as local in nature.

VO(2) based waveguide-mode plasmonic nano-gratings for optical switching.

In this paper, we present one dimensional plasmonic narrow groove nano-gratings, covered with a thin film of VO(2) (Vanadium Dioxide), as novel optical switches. These narrow groove gratings couple the incident optical radiation to plasmonic waveguide modes leading to high electromagnetic fields in the gaps between the nano-gratings. Since VO(2) changes from its semiconductor to its metallic phase on heating, on exposure to infra-red light, or on application of voltage, the optical properties of the underlying plasmonic grating also get altered during this phase transition, thereby resulting in significant switchability of the reflectance spectra. Moreover, as the phase transition in VO(2) can occur at femto-second time-scales, the VO(2)-coated plasmonic optical switch described in this paper can potentially be employed for ultrafast optical switching. We aim at maximizing this switchability, i.e., maximizing the differential reflectance (DR) between the two states (metallic and semiconductor) of this VO(2) coated nano-grating. Rigorous Coupled Wave Analysis (RCWA) reveals that the switching wavelengths - i.e., the wavelengths at which the values of the differential reflectance between VO(2) (S) and VO(2) (M) phases are maximum - can be tuned over a large spectral regime by varying the nano-grating parameters such as groove width, depth of the narrow groove, grating width, and thickness of the VO(2) layer. A comparison of the proposed ideal nano-gratings with various types of non-ideal nano-gratings - i.e., nano-gratings with non-parallel sidewalls - has also been carried out. It is found that significant switchability is also present for these non-ideal gratings that are easy to fabricate. Thus, we propose highly switchable and wide-spectra VO(2) based narrow groove nano-gratings that do not have a complex structure and can be easily fabricated.

Full-wave electromagentic analysis of a plasmonic nanoparticle separated from a plasmonic film by a thin spacer layer.

This paper presents a theoretical analysis of the electromagnetic response of a plasmonic nanoparticle-spacer-plasmonic film system. The physical system consists of a spherical nanoparticle of a plasmonic material such as gold or silver over a plasmonic metal film and separated from the same by a dielectric spacer material. This paper presents a complete analytical solution of the Maxwell's equations, to determine the optical fields near the gold nanoparticle. It was found that the electromagnetic fields in between the plasmonic nanoparticle and the plasmonic film are extremely sensitive to the spacing between the nanoparticle and the film. This could enable the use of such a system for various sensing applications. The non-local nature of the plasmonic medium was also included in our analysis and it's effect on the resonances of the system was studied. The analytical solution was compared with an independent numerical method, the Finite Difference Time Domain (FDTD) method, to demonstrate the accuracy of the solution.

Hybrid nanoparticle-nanoline plasmonic cavities as SERS substrates with gap-controlled enhancements and resonances.

We present hybrid nanoline-nanoparticle plasmonic substrates which allow easily achievable sub-5 nm gaps and a possibility of large-area fabrication. These substrates--based on plasmonic nanocavities formed by arrays of plasmonic nanoparticle (NP) dimers lying inside periodic metal nanolines (NLs)--can be used as tunable surface enhanced Raman scattering (SERS) substrates due to the tunability of cavity modes in the gap regions. Theoretical studies were conducted, using finite difference time domain (FDTD) modeling, to understand the plasmon resonance tunability as a function of gaps in these hybrid plasmonic substrates. The gaps forming the nanocavities include those between nanolines and nanoparticles (NL-NP) and between two nanoparticles (NP-NP). Our analysis reveals that these gaps play a combined role in tuning the resonance wavelength and the magnitude of electromagnetic field enhancement. Moreover, distinct structure-dependent plasmon resonance peaks are present in addition to material-dependent resonance peaks characteristic to the metal involved. Replacing the spherical particle arrays inside the nanolines with nanorod arrays revealed the possibility of tuning the plasmon resonance in the near-infrared regime. This indicates that there is a possibility of tuning the plasmon resonance wavelength to any region of the visible or near-infrared spectrum by changing the size or shape of the particles assembled inside these plasmonic nanolines.

Molecular sentinel-on-chip for SERS-based biosensing.

The development of DNA detection techniques on large-area plasmonics-active platforms is critical for many medical applications such as high-throughput screening, medical diagnosis and systems biology research. Here, we report for the first time a unique "molecular sentinel-on-chip" (MSC) technology for surface-enhanced Raman scattering (SERS)-based DNA detection. This unique approach allows label-free detection of DNA molecules on chips developed on a wafer scale using large area nanofabrication methodologies. To develop plasmonics-active biosensing platforms in a repeatable and reproducible manner, we employed a combination of deep UV lithography, atomic layer deposition, and metal deposition to fabricate triangular-shaped nanowire (TSNW) arrays having controlled sub-10 nm gap nanostructures over an entire 6 inch wafer. The detection of a DNA sequence of the Ki-67 gene, a critical breast cancer biomarker, on the TSNW substrate illustrates the usefulness and potential of the MSC technology as a novel SERS-based DNA detection method.

Bimodal behavior and isobestic transition pathway in surface plasmon resonance sensing.

In traditional interpretation of surface plasmon resonance (SPR) sensing and imaging data, total surface coverage of adsorbed or deposited chemical and biological molecules is generally assumed. This homogenous assumption leads to the modeling of monomodal propagation of plasmons on the surface of the metallic film corresponding to a certain relative permittivity and thickness of the medium-such as molecular thin film-next to the metal. In actual SPR Imaging (SPRI) and SPR sensing situations, the plasmonics-active platforms (e.g., biochips) employed may capture the biomolecular targets as aggregates of different domain sizes on the surface of the thin metallic films. Indeed, such binding of target material always has a finite thickness and is characterized by aggregate lateral sizes possibly varying from tens of nanometers to hundreds of micrometers. This paper studies the propagation of surface plasmons in metallic films, with dielectric domain sizes varying within such ranges. Through rigorous coupled wave analysis (RCWA) calculations, it is indicated that when the domain size is small, only a single mode of propagation-i.e. 'monomodal' propagation behavior-occurs as indicated by only one dip in the angular reflectance curves associated with metallic film having a periodically structured array of molecules on its surface. On the other hand, as the domain size is increased, there is a transition from the 'monomodal propagation behavior' to the existence of a 'mixture of monomodal and bimodal propagation behavior', which changes to a purely 'bimodal behavior' after the size of the domain periodicity is increased beyond about ten micron. Such a transition pathway clearly exhibits isobestic points. The calculations presented in this paper can enable correct interpretation of experimental angular or spectral reflectance data.