Atmospheric Thermodynamic Profiling through the Use of a Micro-Pulse Raman Lidar System: Introducing the Compact Raman Lidar MARCO.

It was for a long time believed that lidar systems based on the use of high-repetition micro-pulse lasers could be effectively used to only stimulate atmospheric elastic backscatter echoes, and thus were only exploited in elastic backscatter lidar systems. Their application to stimulate rotational and roto-vibrational Raman echoes, and consequently, their exploitation in atmospheric thermodynamic profiling, was considered not feasible based on the technical specifications possessed by these laser sources until a few years ago. However, recent technological advances in the design and development of micro-pulse lasers, presently achieving high UV average powers (1-5 W) and small divergences (0.3-0.5 mrad), in combination with the use of large aperture telescopes (0.3-0.4 m diameter primary mirrors), allow one to presently develop micro-pulse laser-based Raman lidars capable of measuring the vertical profiles of atmospheric thermodynamic parameters, namely water vapor and temperature, both in the daytime and night-time. This paper is aimed at demonstrating the feasibility of these measurements and at illustrating and discussing the high achievable performance level, with a specific focus on water vapor profile measurements. The technical solutions identified in the design of the lidar system and their technological implementation within the experimental setup of the lidar prototype are also carefully illustrated and discussed.

Shipborne oceanic high-spectral-resolution lidar for accurate estimation of seawater depth-resolved optical properties.

Lidar techniques present a distinctive ability to resolve vertical structure of optical properties within the upper water column at both day- and night-time. However, accuracy challenges remain for existing lidar instruments due to the ill-posed nature of elastic backscatter lidar retrievals and multiple scattering. Here we demonstrate the high performance of, to the best of our knowledge, the first shipborne oceanic high-spectral-resolution lidar (HSRL) and illustrate a multiple scattering correction algorithm to rigorously address the above challenges in estimating the depth-resolved diffuse attenuation coefficient Kd and the particulate backscattering coefficient bbp at 532 nm. HSRL data were collected during day- and night-time within the coastal areas of East China Sea and South China Sea, which are connected by the Taiwan Strait. Results include vertical profiles from open ocean waters to moderate turbid waters and first lidar continuous observation of diel vertical distribution of thin layers at a fixed station. The root-mean-square relative differences between the HSRL and coincident in situ measurements are 5.6% and 9.1% for Kd and bbp, respectively, corresponding to an improvement of 2.7-13.5 and 4.9-44.1 times, respectively, with respect to elastic backscatter lidar methods. Shipborne oceanic HSRLs with high performance are expected to be of paramount importance for the construction of 3D map of ocean ecosystem.

The effect of COVID-19 on the distribution of PM10 pollution classes of vehicles: Comparison between 2020 and 2018.

A recent study by Pini et al. (2021), focusing on year 2018, demonstrated that different strategies should be considered in different Italian cities to mitigate the effects of PM10 pollution produced by circulating cars and commercial vehicles. The current study focuses on year 2020, considering the same ten Italian cities. This new study relies on the estimation of specific indices used to assess the size of the different circulating vehicle fleets (vehicle yearly mileage, diesel-fuel car and LCV fleet dimension, etc.) and their impact on PM10 pollution (Strength of Pollution). Results for 2020, severely affected by vehicular restrictions associated with COVID-19, indicate the need to adopt PM10 pollution reduction strategies for the various cities partially different from those identified earlier. For example, Euro 4 cars is the fleet having the highest impact on PM10 pollution in Rome (emitting 3,3 times more than Euro 6 vehicles), while in Milan the most polluting vehicles are Euro 0 cars (emitting 2 times more than Euro 6 vehicles). In Naples, Euro 0 cars emit 12,5 times more than Euro 6 vehicles. A careful look into the results also reveals that, for all considered cities, the three top fleets in terms of PM10 pollution always include Euro 4 or a higher Euro category fleet and a lower Euro category fleet (Euro 0 or Euro 3). These values were validated based on the use of pollution data from ground monitoring stations, which also allowed estimating the atmospheric mixing layer height. Results from the paper suggest that different incentivization policies have to be considered for the different considered cities. For example, in Naples the allocation of incentives should be ~60% towards new vehicles and ~40% towards recent used (i.e. second-hand) non-diesel vehicles, while in Florence it should be ~90% towards ECVs and ~10% towards recent used non-diesel vehicles.

Impact of the different vehicle fleets on PM10 pollution: Comparison between the ten most populous Italian metropolitan cities for the year 2018.

The main aim of this research effort is to assess the impact of the different circulating vehicle fleets on PM10 pollution, comparing the results from the ten most populated metropolitan cities in Italy. Circulating diesel vehicles have been categorized in different groups depending on the vehicle type (car or Light Commercial Vehicle - LCV) and European emission standard. The annual mileage and the total PM10 emission for each category has been determined based on several data sources. Estimated overall annual emissions of PM10 particles have been compared with PM10 concentration measurements from distributed ground monitoring stations. A new index, named SoP (Strength of Pollution), has been defined in order to quantify the contribution of each fleet category to the overall PM10 pollution. The index has been computed for the ten most populated Italian metropolitan cities, i.e. all cities with more than 300.000 inhabits: Rome, Milan, Naples, Turin, Palermo, Genoa, Bologna, Florence, Bari and Catania. Results in terms of SoP estimates for year 2018 reveal the presence in these Italian cities of emission clusters with heterogeneous characteristics, which impose the adoption of different PM10 pollution mitigation approaches in the different cities. For example, in Naples, Catania and Palermo, Euro 0 car fleets emit a total PM10 mass which is respectively 19, 10 and 5 times the mass emitted by Euro 6 vehicles, and consequently a reduction of this fleet is desirable for pollution mitigation purposes. Conversely, in Rome, Genoa and Bari, Euro 3 and 4 car fleets emit a total PM10 mass which is 3-6 times the one emitted by Euro 6 vehicles, which calls for a reduction of these fleets. Thus, the extension to the entire national territory of the results obtained in a specific metropolitan city may be strongly misleading and produce limited effects in terms of pollution mitigation.

Evidence-Based Considerations Exploring Relations between SARS-CoV-2 Pandemic and Air Pollution: Involvement of PM2.5-Mediated Up-Regulation of the Viral Receptor ACE-2.

The COVID-19/SARS-CoV-2 pandemic struck health, social and economic systems worldwide, and represents an open challenge for scientists -coping with the high inter-individual variability of COVID-19, and for policy makers -coping with the responsibility to understand environmental factors affecting its severity across different geographical areas. Air pollution has been warned of as a modifiable factor contributing to differential SARS-CoV-2 spread but the biological mechanisms underlying the phenomenon are still unknown. Air quality and COVID-19 epidemiological data from 110 Italian provinces were studied by correlation analysis, to evaluate the association between particulate matter (PM)2.5 concentrations and incidence, mortality rate and case fatality risk of COVID-19 in the period 20 February-31 March 2020. Bioinformatic analysis of the DNA sequence encoding the SARS-CoV-2 cell receptor angiotensin-converting enzyme 2 (ACE-2) was performed to identify consensus motifs for transcription factors mediating cellular response to pollutant insult. Positive correlations between PM2.5 levels and the incidence (r = 0.67, p < 0.0001), the mortality rate (r = 0.65, p < 0.0001) and the case fatality rate (r = 0.7, p < 0.0001) of COVID-19 were found. The bioinformatic analysis of the ACE-2 gene identified nine putative consensus motifs for the aryl hydrocarbon receptor (AHR). Our results confirm the supposed link between air pollution and the rate and outcome of SARS-CoV-2 infection and support the hypothesis that pollution-induced over-expression of ACE-2 on human airways may favor SARS-CoV-2 infectivity.

Assessment of the potential role of atmospheric particulate pollution and airborne transmission in intensifying the first wave pandemic impact of SARS-CoV-2/COVID-19 in Northern Italy.

The severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), which exploded in Wuhan (Hebei Region, China) in late 2019, has later spread around the world, causing pandemic effects on humans. During the first wave of the pandemic, Italy, and especially its Northern regions around the Po Valley, faced severe consequences in terms of infected individuals and casualties (more than 31,000 deaths and 255,000 infected people by mid-May 2020). While the spread and effective impact of the virus is primarily related to the lifestyles and social habits of the different human communities, environmental and meteorological factors also play a role. Among these, particulate pollution may directly impact the human respiratory system or act as virus carrier, thus behaving as potential amplifying factor in the pandemic spread of SARS-CoV-2. Enhanced levels of PM2.5 and PM10 particles in Northern Italy were observed over the 2-month period preceding the virus pandemic spread. Threshold levels for PM10 (< 50 µg/m3) were exceeded on 20-35 days over the period January-February 2020 in many areas in the Po Valley, where major effects in terms of infections and casualties occurred, with levels in excess of 80 µg/m3 occasionally observed in the 1-3 weeks preceding the contagious activation around February 25, 2020. Threshold values for PM2.5 indicated in WHO air quality guidelines (< 25 µg/m3) were exceeded on more than 40 days over the period January-February 2020 in large portions of the Po Valley, with levels up to 70 µg/m3 observed in the weeks preceding the contagious activation. In this paper, PM10 particle measurements are compared with epidemiologic parameters' data. Specifically, a statistical analysis is carried out to correlate the infection rate, or incidence of the pathology, the mortality rate, and the case fatality rate with PM concentrations. The study considers epidemiologic data for all 110 Italian provinces, as reported by the Italian Statistics Institute, over the period 20 February-31 March 2020. Corresponding PM10 concentrations covering the period 15-26 February 2020 were collected from the network of air quality monitoring stations run by different regional and provincial environment agencies. The case fatality rate is found to be highly correlated to the average PM10 concentration, with a correlation coefficient of 0.89 and a slope of the regression line of (6.7 ± 0.3) × 10-3 m3/µg, which implies a doubling (from 3 to 6%) of the mortality rate of infected patients for an average PM10 concentration increase from 22 to 27 µg/m3. Infection and mortality rates are also found to be correlated with PM10 concentrations, with correlation coefficients being 0.82 and 0.80, respectively, and the slopes of the regression lines indicating a doubling (from 1 to 2‰) of the infection rate and a tripling (from 0.1 to 0.3‰) of the mortality rate for an average PM10 concentration increase from 25 to 29 µg/m3. Considerations on the exhaled particles' sizes, their concentrations and residence times, the transported viral dose and the minimum infective dose, in combination with PM2.5 and PM10 pollution measurements and an analytical microphysical model, allowed assessing the potential role of airborne transmission through virus-laden PM particles, in addition to droplet and the traditional airborne transmission, in conveying SARS-CoV-2 in the human respiratory system. In specific circumstances which can be found in indoor environments, the number of small potentially infectious particles coalescing on PM2.5 and PM10 particles is estimated to exceed the number of infectious particles needed to activate COVID-19 infection in humans.

Space-borne profiling of atmospheric thermodynamic variables with Raman lidar: performance simulations.

The performance of a space-borne water vapour and temperature lidar exploiting the vibrational and pure rotational Raman techniques in the ultraviolet is simulated. This paper discusses simulations under a variety of environmental and climate scenarios. Simulations demonstrate the capability of Raman lidars deployed on-board low-Earth-orbit satellites to provide global-scale water vapour mixing ratio and temperature measurements in the lower to middle troposphere, with accuracies exceeding most observational requirements for numerical weather prediction (NWP) and climate research applications. These performances are especially attractive for measurements in the low troposphere in order to close the most critical gaps in the current earth observation system. In all climate zones, considering vertical and horizontal resolutions of 200 m and 50 km, respectively, mean water vapour mixing ratio profiling precision from the surface up to an altitude of 4 km is simulated to be 10%, while temperature profiling precision is simulated to be 0.40-0.75 K in the altitude interval up to 15 km. Performances in the presence of clouds are also simulated. Measurements are found to be possible above and below cirrus clouds with an optical thickness of 0.3. This combination of accuracy and vertical resolution cannot be achieved with any other space borne remote sensing technique and will provide a breakthrough in our knowledge of global and regional water and energy cycles, as well as in the quality of short- to medium-range weather forecasts. Besides providing a comprehensive set of simulations, this paper also provides an insight into specific possible technological solutions that are proposed for the implementation of a space-borne Raman lidar system. These solutions refer to technological breakthroughs gained during the last decade in the design and development of specific lidar devices and sub-systems, primarily in high-power, high-efficiency solid-state laser sources, low-weight large aperture telescopes, and high-gain, high-quantum efficiency detectors.

Retrieval of foreign-broadened water vapor continuum coefficients from emitted spectral radiance in the H2O rotational band from 240 to 590 cm(-1).

The paper presents a novel methodology to retrieve the foreign-broadened water vapor continuum absorption coefficients in the spectral range 240 to 590 cm(-1) and is the first estimation of the continuum coefficient at wave numbers smaller than 400 cm(-1) under atmospheric conditions. The derivation has been accomplished by processing a suitable set of atmospheric emitted spectral radiance observations obtained during the March 2007 Alps campaign of the ECOWAR project (Earth Cooling by WAter vapor Radiation). It is shown that, in the range 450 to 600 cm(-1), our findings are in good agreement with the widely used Mlawer, Tobin-Clough, Kneizys-Davies (MT CKD) continuum. Below 450 cm(-1) however the MT CKD model overestimates the magnitude of the continuum coefficient.

Spatial distribution of doubly scattered polarized laser radiation in the focal plane of a lidar receiver.

Depolarization lidars are widely used to study clouds and aerosols because of their ability to discriminate between spherical particles and particles of irregular shape. Depolarization of cloud backscattered radiation can be caused also by multiple scattering events. One of the ways to gain information about particle parameters in the presence of strong multiple scattering is the measurement of radial and azimuthal dependence of the polarization patterns in the focal plane of receiver. We present an algorithm for the calculation of corresponding polarized patterns in the frame of double scattering approximation. Computations are performed for various receiver field of views, for different parameters of the scattering geometry, e.g., cloud base and sounding depth, as well as for different values of cloud particle size and refractive index. As the spatial distribution of cross-polarized radiation is of cross shape and rotated at 45 degrees with respect to laser polarization, the use of a properly oriented cross-shaped mask in the receiver focal plane allows the removal of a significant portion of the depolarized component of the backscattered radiation produced by double scattering. This has been verified experimentally based on cloud depolarization measurements performed at different orientations of the cross-shaped mask. Results obtained from measurements are in agreement with model predictions.

Spaceborne profiling of atmospheric temperature and particle extinction with pure rotational Raman lidar and of relative humidity in combination with differential absorption lidar: performance simulations.

The performance of a spaceborne temperature lidar based on the pure rotational Raman (RR) technique in the UV has been simulated. Results show that such a system deployed onboard a low-Earth-orbit satellite would provide global-scale clear-sky temperature measurements in the troposphere and lower stratosphere with precisions that satisfy World Meteorological Organization (WMO) threshold observational requirements for numerical weather prediction and climate research applications. Furthermore, nighttime temperature measurements would still be within the WMO threshold observational requirements in the presence of several cloud structures. The performance of aerosol extinction measurements from space, which can be carried out simultaneously with temperature measurements by RR lidar, is also assessed. Furthermore, we discuss simulations of relative humidity measurements from space obtained from RR temperature measurements and water-vapor data measured with the differential absorption lidar (DIAL) technique.

Numerical simulation of light backscattering by spheres with off-center inclusion. Application to the lidar case.

A Mie backscattering model for spherical particles with off-center inclusion has been developed and tested. The program is capable of dealing with size parameter values up to approximately 1000, thus allowing one to simulate the optical behavior of a large variety of atmospheric aerosols, as well as cloud and precipitation particles. On the basis of this model, we simulated the optical properties of polydisperse composite atmospheric particles as observed by ground-based and airborne lidar systems. We have characterized optical properties in terms of host and inclusion radii, considering water particles with different composition inclusions. The performed modeling provides some insight into the so-called lidar bright- and dark-band phenomenon.