ABSTRACT
Hydrophobic surfaces are of high interest to industry. While surface functionalization has attracted significant interest, from both industry and research, the durability of engineered surfaces remains a challenge, as wear and scratches deteriorate their functional response. In this work, a cost-effective combination of surface engineering processes on stainless steel was investigated. Low-temperature plasma surface alloying was applied to increase surface hardness from 172 to 305 HV. Then, near-infrared nanosecond laser patterning was deployed to fabricate channel-like patterns that enabled superhydrophobicity. Abrasion tests were carried out to examine the durability of such engineered surfaces during daily use. In particular, the evolution of surface topographies, chemical composition, and water contact angle with increasing abrasion cycles were studied. Hydrophobicity deteriorated progressively on both hardened and raw stainless steel samples, suggesting that the major contributing factor to hydrophobicity was the surface chemical composition. At the same time, samples with increased surface hardness exhibited a slower deterioration of their topographies when compared with nontreated surfaces. A conclusion is made about the durability of laser-textured hardened stainless steel surfaces produced by applying the proposed combined surface engineering approach.
ABSTRACT
An experimental arrangement is described where a Babinet-Soleil compensator is inserted into the path of one of the three beams used for noncoplanar beam interference lithography. This birefringent element can change the phase of the beam so that either a positive two-dimensional pattern or an inverselike structure is generated in a photoresist without disturbing the mechanical geometry of the setup. Simulations are presented that confirm the validity of this approach. Large defect-free sample areas (>1 cm(2)) with submicrometer periodic patterns were obtained by expanding the laser beams used in the lithography experiment.
ABSTRACT
Results are presented for the trace analysis of Pd and Rh by time-of-flight-resonance ionization mass spectrometry (TOF-RIMS). The spectrometer, developed at the Advanced Mineral Technology Laboratory (Ontario, Canada), is based on a commercial laser-induced mass analyzer with upgrades that include independent laser ablation and ionization sources and pulsed ion optics to minimize noise caused by primary ion formation. The schemes presented for Rh and particularly for Pd detection are simpler than others reported in the literature. The experimental laser fluences were found to be in reasonable agreement with theoretical estimates. The TOF-RIMS measurements were quantified on the basis of calibration curves derived using reference samples covering 3 orders of magnitude in concentration. Minimum detection limits of ~15 parts per billion were found for both metals, with a precision of ~ +/-15%. Samples from sulfide, iron oxide, and silicate minerals were also examined. The results are in excellent agreement with those obtained using dynamics secondary ion mass spectrometry.
ABSTRACT
A series of liquid O,S-dialkyl dithiocarbonates (xanthate esters) have been synthesized, and time-of-flight (TOF) mass spectra were recorded for their vapors using both ultraviolet (UV) and vacuum ultraviolet (VUV) laser excitation. These compounds are chemical derivatives of low vapor pressure xanthate salts which have found important commercial application as collectors in mineral sulfide flotation circuits. Our experiments demonstrate that esters ionized by short-wavelength VUV light can be detected by parent mass with high efficiency and minimal fragmentation. In contrast, the mass spectra of the same compounds obtained by UV light excitation exhibit a large number of low molecular mass peaks. A preliminary quantitative analysis of the composition of a gas-phase mixture of xanthate esters has also been achieved, which indicates possible subfemtomole detection limits.
ABSTRACT
In this paper we report on the results of comparative investigations of different pump cavities. Numerical estimations of the geometrical transfer efficiency of various cavities are presented. An experimental study of the pumping efficiency and pumping uniformity of the laser heads with respect to the cavity geometry, types of flashlamp, and reflecting coatings have been carried out. The influence of the discharge circuit on the pumping efficiency is also discussed.
