ABSTRACT
The identification of fluoride (F-) sources and enrichment mechanisms is imperative to understand the multiple fluorine (F) pathways, and further, to control regional diffuse F- contamination in groundwater. However, the factors that control high-F- groundwater are not fully understood in desert climate regions. Hence, a sampling campaign was conducted from 71 desert groundwater sites and six river water sites in the Cherchen River Basin (CRB), northwestern China. This study combined hydrochemical compositions with an optimized forward model, with the aim of determining the potential sources and enrichment mechanisms in F--contaminated desert groundwater. Approximately 58.46% of the samples had F- concentrations over the national standard of 1.0 mg/L. More severe F- contamination was found in the multi-layered structured confined aquifer (MCA) of the alluvial plain (1.42 ± 1.11 mg/L). The primary contributors of desert groundwater F- were the dissolution of F-bearing minerals containing evaporite (â¼58.80%), silicate (â¼15.89%), and carbonate (â¼12.94%), followed by the river water input (â¼12.08%). In contrast, anthropogenic activities (â¼0.16%) and precipitation contributed less to desert groundwater F-. The dissolution equilibrium of CaF2 was important for F- enrichment in desert groundwater. Compared with the piedmont plain, intensive evaporation and salinization were more conducive to F- enrichment in the alluvial plain. Under alkaline condition, the dissolutions of evaporite and fluorite allowed extra F- to release into desert groundwater when Ca2+ and Mg2+ were up to oversaturation. Moreover, the desorption of F- was promoted by competitive adsorption of OH- and HCO3-, and the adsorption capacity of F- was weakened by cation exchange of K++Na+ with Ca2++Mg2+. As a result, desert groundwater had a higher concentration of F- in the alluvial plain. Our study provided a comprehensive understanding of multiple F pathways in desert groundwater. This study also highlights the effect of hydrogeochemical background on high-F- desert groundwater.
Subject(s)
Groundwater , Water Pollutants, Chemical , Fluorides/analysis , Rivers , Water Pollutants, Chemical/analysis , Environmental Monitoring , Groundwater/chemistry , China , WaterABSTRACT
To analyze spatial-temporal variation in groundwater quality and contamination sources in the Shihezi-Changji area in Xinjiang, a Bayesian water quality evaluation model based on Shannon entropy, Spearman rank correlation coefficient, principal component analysis, and an absolute principal component scores-multiple linear regression receptor model (APCS-MLR) were comprehensively used in this study. Groundwater samples in 23 in-situ wells were collected from 2016 to 2021 for quality analysis. The results showed that â groundwater quality was generally good, with most samples having a phreatic water quality of Class â and Class â ¡ and most confined groundwater quality being of Class â . â¡ Temporally, 2016 and 2017 were the key time nodes of water quality variation in phreatic water and confined groundwater, respectively. Class â £ and Class â ¤ groundwater was observed only before the key time nodes, whereas after those time nodes the groundwater quality fluctuated within Class â to Class â ¢. ⢠Spatially, the order of phreatic water quality in descending order was Shihezi City, Hutubi county, Manas county, and Changji City, whereas that of confined groundwater quality was:Shihezi City and Changji City, Hutubi county, and Manas county. ⣠The spatial-temporal variations in groundwater quality and that in major related indices were basically similar and highly heterogeneous. ⤠Phreatic water quality was mainly affected by leaching (67.30%), leaching-migration (10.89%), and agricultural-domestic pollution (9.44%); by contrast, unconfined groundwater quality was mainly affected by leaching-enrichment (52.08%), agricultural-domestic pollution (16.06%), and ion exchange under an alkaline environment (12.64%). Although groundwater quality was improved over the years, more attention should be paid to groundwater salinization in the 149 Regiment in northern Manas County.
