ABSTRACT
The inherent weak bonding nature of hydrogen-bonded organic frameworks (HOFs) performs like a double-edged sword in that it endows HOFs with superiority in processability and dynamicity but deactivates its on-demand controllability in the crystalline phase. Herein, based on the synergy of dynamic H-bonding interactions and the tailored low solubility in common organic solvents, reversible and fast topological transitions between cage- and channel-type HOFs were achieved upon immersing in the solution state. The aggregation-induced-emission character of the tecton facilitates the visualization of the elusive initial transition process with high sensitivity. In addition, the visible transition from cage- and channel-type HOFs to thermally stable crystalline phases is also achieved under thermal induction.
ABSTRACT
The development of new strategies to construct on-demand porous lattice frameworks from simple motifs is desirable. However, mitigating complexity while combing multiplicity and reversibility in the porous architectures is a challenging task. Herein, based on the synergy of dynamic intermolecular interactions and flexible molecular conformation of a simple cyano-modified tetraphenylethylene tecton, eleven kinetic-stable hydrogen-bonded organic frameworks (HOFs) with various shapes and two thermo-stable non-porous structures with rare perpendicular conformation are obtained. Multimode reversible structural transformations along with visible fluorescence output between porous and non-porous or between different porous forms is realized under different external stimuli. Furthermore, the collaborative of flexible framework and soft long-chain guests facilitate the relaxation from intrinsic blue emission to yellow emission in the excited state, which represents a strategy for generating white-light emission. The dynamic intermolecular interactions, facilitated by flexible molecular conformation and soft guests, diversifies the strategies of construction of versatile smart molecular frameworks.
