On the analyses of carbon atom diffused into grey cast iron during carburisation process.

The study employed Fick's second law of diffusion to discover some unknown aspect of carbon diffusion in grey cast iron during carburisation process. Emphasis on the experiments and theoretical modelling were established for better accomplishments. Pulverised palm kernel and eggshell additives of 70 (wt.%) and 30 (wt.%) according to the Voige law of mixture was considered as a continuous medium without considering the atomic nature of the mixture. Furthermore, a kinetic approach was described where a physical model of the substrate immersed in the carbon mixture was established while diffusion equations were modelled to establish the mechanism of carbon diffusion during carburisation. Initial composition and concentration of diffused atom remained constant which are 2.68 and 6.67% carbon. While the carburizing time used varied from 60 min, 90 min, 120 min, 150 min, 180 min and 210 min respectively at constant carburising temperature of 900° The results revealed varying composition gradient of carbon atom ranging from 5.4%, 5.42%, 5.44%, 5.46%, 5.51%, and 5.65 compared to the initial carbon content of 2.68%. The concentration of carbon atom on the substrate surface at varying time implies that the process was non-steady state diffusion which verified Fick's second law of diffusion. Hence, the composition achieved is a function of boundary conditions such as time position and temperature. This novel study will enhance the understanding of heat treat treatment of metals such that their applications in the industry will be numerous.

Corrosion resistance of galvanized roofing sheets in acidic and rainwater environments.

The galvanization of steel sheets for building roofs and construction of additional structures has been a valued solution to the challenges faced by the deterioration of roofing steel sheets in an unfavourable surroundings. This research was conducted on galvanized roofing sheets obtained from the open market in Nigeria. The samples were cut to a small size (5 cm by 4 cm) and immersed in sulfuric acid (H2SO4) and hydrochloric acid (HCl). As the control medium for the experiment, rainwater was used. The experiment was performed over 1200 hours; each sample was removed every 240 hours, thoroughly washed, dried, and weighed again. Based on the reacting media, variations in the weights of the samples were obtained. According to ASTM G1-03 standard practice, Corrosion rates were calculated for preparing, cleaning, and evaluating corrosion test specimens. Scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) was also carried out. Although some samples resisted corrosion, other samples corroded. It is predicted that the green-coated samples are more resistant to corrosion in rainwater and H2SO4 and thus more stable.