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Chem Commun (Camb) ; 50(23): 3007-9, 2014 Mar 21.
Article in English | MEDLINE | ID: mdl-24513788

ABSTRACT

The reaction of As(NMe2)3 with Mes*PHLi provides a direct source of the 1,3-diphosphaarsa-2-allyl anion, [(Mes*P)2As](-) (isoelectronic with the allyl anion). The equilibrium between the E,E and E,Z isomers of this anion depends on the extent of Li(+) ion-pairing.

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