1.
J Am Chem Soc
; 130(24): 7566-7, 2008 Jun 18.
Article
in English
| MEDLINE
| ID: mdl-18505255
ABSTRACT
The synthesis of corilagin was achieved by the integration of the development of the oxidative coupling of the symmetrically protected gallates and the temporarily ring-opened synthetic route for the 3,6-hexahydroxydiphenoyl (HHDP) bridge. This is the first total synthesis of the 1C4/B-ellagitannins, which contain ring-flipped glucose.