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1.
ACS Appl Mater Interfaces ; 15(32): 38769-38780, 2023 Aug 16.
Article in English | MEDLINE | ID: mdl-37535833

ABSTRACT

As a kind of typical green material, natural materials tend to exhibit excellent performance in the engineering field because of their structure and special functions. The homogeneous vessels of red willow (RW) are potentially unique structures to store lubricants or reinforcing agents to present special functions for engineering applications. A series of novel red willow wood-based composites, which were infused with nano-MoS2 and then reinforced by the epoxy, were developed. Their self-lubricating, mechanical vibration and noise reduction performances were investigated, and the friction, vibration, and noise reduction mechanisms were disclosed. The infusion MoS2 treatment was very beneficial for improving the tribological properties of MoS2-curing epoxy/red willow (MCW), and the coefficient of friction (COF) was reduced by 65.8% under water-lubricated friction after infusing 24 times. Meanwhile, the mechanical performances of MCW were obviously enhanced through the curing treatment of the epoxy. The synergistic effects of the infusion and curing treatments significantly decreased the wear phenomena on the friction surfaces of MCW and weakened the COF and its fluctuation amplitudes, which resulted in the presented excellent vibration and noise reduction performance. The knowledge gained herein could not only develop a novel wood-based composite with low COF and good vibration reduction properties in the engineering field but also provide a new methodology for the design of artificial porous materials with stable and smooth friction processes.

2.
Polymers (Basel) ; 14(3)2022 Jan 21.
Article in English | MEDLINE | ID: mdl-35160423

ABSTRACT

Reducing the deformation of polymer matrix materials can decrease the fluctuation of coefficient of friction (COF), and friction-induced vibration and its amplitudes. HDPE composites with T-ZnOw as a fixed strengthening filler were modified with the addition of Si3N4 particles at different concentrations. The COFs, wear rates, micro-morphologies, and friction-induced vibrations were obtained by conducting sliding tests against carbon steel balls in an aqueous environment at a low velocity and high load. The mechanism of the reduction in frictional fluctuation due to the addition of Si3N4 particles was revealed through the frictional responses. The results demonstrated that 4 wt% addition of Si3N4 in HDPE can enhance the strain-stress property and improve the lubrication by forming a lubricating film. Therefore, the surface deformation and the fluctuations of COFs and its vibrations were reduced. The aggregation phenomenon and reduced strain-stress response at a high concentration of Si3N4 disrupted the positive fluctuating reduction, and resulted in a rough surface with severe tearing and cracking deformations. Additionally, it led to fluctuating wear behaviors with high COF and vibrations. The results obtained in this study can elucidate the effects of adding Si3N4 particles to enhance lubrication in polymer composites. Additionally, the results provide a new research method for designing and manufacturing polymer-based composites with low friction-induced fluctuations.

3.
Materials (Basel) ; 15(4)2022 Feb 12.
Article in English | MEDLINE | ID: mdl-35207903

ABSTRACT

The insufficient lubrication of the contact interface between moving parts can easily induce severe friction vibration and noise under extreme working conditions, which will threaten the service life and reliability of polymer moving components, including water-lubricated stern tube polymer bearings. Thermoplastic polyurethane (TPU) modified by polytetrafluoroethylene (PTFE) particles was developed. The effects of PTFE on the wear and vibration behaviors of modified TPU sliding against the ZCuSn10Zn2 ring-plates were investigated. The coefficients of friction (COFs), wear mass losses, wear morphologies, frictional vibration, and noise were analyzed synthetically. The results showed that a suitable mass content of PTFE reduced the COFs and wear mass losses of the TPU composites by more than 50% and 40%, respectively, while presenting an excellent friction reduction. The lower COFs of modified TPU showed a small fluctuation amplitude and eliminated vibration waveforms at high vibrational frequencies, which was useful for reducing frictional vibration and noise. The knowledge gained in this study is useful for a better understanding of the wear behaviors of polymer composites, as well as for the design a new polymer material with good self-lubricating and frictional vibration and noise reduction properties.

4.
Carbohydr Polym ; 220: 228-235, 2019 Sep 15.
Article in English | MEDLINE | ID: mdl-31196545

ABSTRACT

With the increasing requirement of environmental protection, the development of lubricating materials with non-toxicity and good biodegradability becomes more and more significant. As the novel green nanomaterial derived from natural cellulose, cellulose nanocrystals (CNCs) in the present work were prepared from native cotton and added into polyalphaolefin (PAO) base oil as the lubricant additive. To improve the compatibility of CNCs with PAO, the surface of CNCs were grafted by stearoyl chains, which entangled with polyolefin chains and led to a good dispersibility and stability of the colloidal solution. This hybrid oil with the elevated viscosity improved the formation of lubricant film in the boundary lubrication regime. Combining with the mending effect of CNC particles on the surface roughness and scars, both the friction and the wear were dramatically reduced. Specifically, the introduction of 2 wt% modified nanocrystals (mCNC) in PAO base oil reduced the coefficient of friction (COF) by 30%. The results of this study suggest that cellulose nanocrystal is a promising ecofriendly and effective lubricant additive.


Subject(s)
Alkenes/chemistry , Cellulose/chemistry , Gossypium/metabolism , Lubricants/chemistry , Nanoparticles/chemistry , Friction , Lubrication , Surface Properties , Viscosity
5.
Langmuir ; 35(7): 2878-2884, 2019 Feb 19.
Article in English | MEDLINE | ID: mdl-30688467

ABSTRACT

Textured surfaces with varied functionalities are generally fabricated by etching, cutting, or printing. In this study, different from the usual generation of grooves along the sliding direction in friction, regular parallel ripples that are perpendicular to the sliding direction were generated on a polymer surface by the stick-slip friction of polymer/metal friction pairs lubricated with water. Ripple height was proportional to the peak friction force in the sticking process. Ripple wavelength decreased as the sliding velocity increased. The generation of ripples was ascribed to the adhesion and plastic deformation during stick-slip motion. The achieved rippled surface effectively improved the lubrication property of the two surfaces. These findings demonstrate a new method of in situ manufacturing ripples on a soft material surface through a controlled traditional sliding friction and also provide a new insight into the stick-slip friction behavior of materials.

6.
Sci Rep ; 7(1): 13041, 2017 10 12.
Article in English | MEDLINE | ID: mdl-29026197

ABSTRACT

The coefficient of friction (COF) between two materials is usually believed to be an intrinsic property of the materials themselves. In this study, metals of stainless steel (304) and brass (H62), and polymers of polypropylene (PP) and polytetrafluoroethylene (PTFE) were tested on a standard ball-on-three-plates test machine. Significantly different tribological behaviors were observed when fixed and moving materials of tribo-pairs (metal/polymer) were switched. As an example, under the same applied load and rotating speed, the COF (0.49) between a rotating PP ball and three fixed H62 plates was approximately 2.3 times higher than that between switched materials of tribo-pairs. Meanwhile, the COF between H62 and PTFE was relatively stable. The unexpected tribological behaviors were ascribed to the thermal and mechanical properties of tribo-pairs. Theoretical analysis revealed that the differences in the maximum local temperature between switching the fixed and moving materials of tribo-pairs were consistent with the differences in the tested COF. This result indicated the precise prediction of the COF of two materials is complexcity, and that thermal and mechanical properties should be properly considered in designing tribo-pairs, because these properties may significantly affect tribological performance.

7.
Sci Rep ; 7(1): 2327, 2017 05 24.
Article in English | MEDLINE | ID: mdl-28539605

ABSTRACT

Stainless steel is widely used in strongly oxidizing hydrogen peroxide (H2O2) environments. It is crucial to study its wear behaviour and failure mode. The tribological properties and oxidation of 304 stainless steel were investigated using a MMW-1 tribo-tester with a three-electrode setup in H2O2 solutions with different concentrations. Corrosion current densities (CCDs), coefficients of frictions (COFs), wear mass losses, wear surface topographies, and metal oxide films were analysed and compared. The results show that the wear process and oxidation process interacted significantly with each other. Increasing the concentration of H2O2 or the oxidation time was useful to form a layer of integrated, homogeneous, compact and thick metal oxide film. The dense metal oxide films with higher mechanical strengths improved the wear process and also reduced the oxidation reaction. The wear process removed the metal oxide films to increase the oxidation reaction. Theoretical data is provided for the rational design and application of friction pairs in oxidation corrosion conditions.

8.
Sci Rep ; 6: 35023, 2016 10 07.
Article in English | MEDLINE | ID: mdl-27713573

ABSTRACT

Frictional vibration and noise caused by water-lubricated rubber stern tube bearings, which are generated under extreme conditions, severely threaten underwater vehicles' survivability and concealment performance. This study investigates the effect of flaky and spherical MoS2 nanoparticles on tribological properties and damping capacity of water-lubricated rubber materials, with the aim of decreasing frictional noise. A CBZ-1 tribo-tester was used to conduct the sliding tests between rubber ring-discs and ZCuSn10Zn2 ring-discs with water lubrication. These materials' typical mechanical properties were analysed and compared. Coefficients of friction (COFs), wear rates, and surface morphologies were evaluated. Frictional noise and critical velocities of generating friction vibration were examined to corroborate above analysis. Results showed that spherical MoS2 nanoparticles enhanced rubber material's mechanical and tribological properties and, in turn, reduced the friction noise and critical velocity. Flaky MoS2 nanoparticles reduced COF but did not enhance their mechanical properties, i.e., the damping capacity, wear resistance property; thus, these nanoparticles did not reduce the critical velocity obviously, even though increased the frictional noise at high load. The knowledge gained in the present work will be useful for optimizing friction pairs under extreme conditions to decrease frictional noise of water-lubricated rubber stern tube bearings.

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