Elevating Thermoelectric Performance by Compositing Dibromo-Substituted Thienoacene with SWCNTs.

Composites of organic small molecules (OSMs) and single-walled carbon nanotubes (SWCNTs) have drawn great attention as flexible thermoelectric (TE) materials in recent years. Here, we synthesized thieno[2',3':4,5]thieno[3,2-b]thieno[2,3-d]thiophene (TTA) and 2,6-dibromothieno[2',3':4,5]thieno[3,2-b]thieno[2,3-d]thiophene (TTA-2Br) and compounded them with SWCNTs, obtaining thermoelectric TTA/SWCNT and TTA-2Br/SWCNT composites. The introduction of the electron-withdrawing Br group was found to decrease the highest molecular orbital energy level and bandgap (Eg) of TTA-2Br. As a result, the Seebeck coefficient (S) and power factor (PF) of the OSM/SWCNT composite films were significantly improved. Moreover, suitable energy barrier between TTA-2Br and SWCNTs facilitates the energy filtering effect, which further enhances thermoelectric properties of the 40 wt % TTA-2Br/SWCNT composite film with optimum thermoelectric properties (PF = 242.59 ± 9.42 µW m-1 K-2 at room temperature), good thermal stability, and mechanical flexibility. In addition, the thermoelectric generator (TEG) prepared using 40 wt % TTA-2Br/SWCNT composite films and n-type SWCNT films can generate an output power of 102.8 ± 7.4 nW at a temperature difference of 20 °C. This work provides new insights into the preparation of OSM/SWCNT composites with significantly enhanced thermoelectric properties.

A Domino Protocol toward High-performance Unsymmetrical Dibenzo[d,d']thieno[2,3-b;4,5-b']dithiophenes Semiconductors.

Unsymmetric organic semiconductors have many advantages such as good solubility, rich intermolecular interactions for potential various optoelectronic applications. However, their synthesis is more challenging due to intricate structures thus normally suffering tedious synthesis. Herein, we report a trisulfur radical anion (S3⋅-) triggered domino thienannulation strategy for the synthesis of dibenzo[d,d']thieno[2,3-b;4,5-b']dithiophenes (DBTDTs) using readily available 1-halo-2-ethynylbenzenes as starting materials. This domino protocol features no metal catalyst and the formation of six C-S and one C-C bonds in a one-pot reaction. Mechanistic study revealed a unique domino radical anion pathway. Single crystal structure analysis of unsymmetric DBTDT shows that its unique unsymmetric structure endows rich and multiple weak S⋅⋅⋅S interactions between molecules, which enables the large intermolecular transfer integrals of 86 meV and efficient charge transport performance with a carrier mobility of 1.52 cm2 V-1 s-1. This study provides a facile and highly efficient synthetic strategy for more high-performance unsymmetric organic semiconductors.

Neuromorphic Vision-Based Fall Localization in Event Streams With Temporal-Spatial Attention Weighted Network.

Falling down is a serious problem for health and has become one of the major etiologies of accidental death for the elderly living alone. In recent years, many efforts have been paid to fall recognition based on wearable sensors or standard vision sensors. However, the prior methods have the risk of privacy leaks, and almost all these methods are based on video clips, which cannot localize where the falls occurred in long videos. For these reasons, in this article, the bioinspired vision sensor-based falls temporal localization framework is proposed. The bioinspired vision sensors, such as dynamic and active-pixel vision sensor (DAVIS) camera applied in this work responds to pixels' brightness change, and each pixel works independently and asynchronously compared to the standard vision sensors. This property makes it have a very high dynamic range and privacy preserving. First, to better represent event data, compared with the typical constant temporal window mechanism, an adaptive temporal window conversion mechanism is developed. The temporal localization framework follows a proven proposal and classification paradigm. Second, for the high-efficient and recall proposal generation, different from the traditional sliding window scheme, the event temporal density as the actionness score is set and the 1D-watershed algorithm to generate proposals is applied. In addition, we combine the temporal and spatial attention mechanism with our feature extraction network to temporally model the falls. Finally, to evaluate the performance of our framework, 30 volunteers are recruited to join the simulated fall experiments. According to the results of experiments, our framework can realize precise falls temporal localization and achieve the state-of-the-art performance.

A recyclable fluorescent probe for picric acid detection in water samples based on inner filter effect.

1-Aminopyrene@ZIF-8 composite was synthesized as the fluorescent probe for picric acid (PA) based on inner filter effect. The probe displayed selective response toward PA within 10s, and a linear range was obtained from 1 to 150µM with detection limit of 0.3µM, which is much lower than the permissible level of PA in drinking water reservoir (0.5mgL-1/2.2µM) set by China's State Environmental Protection Administration (GB3838-2002). Most importantly, the probe possessed excellent recyclability and could be recycled for at least six times. It was further applied to the detection of PA in water samples, and satisfactory recoveries were obtained in the range of 96.0-104.0%.