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Cp*(iPr3P)Ru(Cl)(eta2-HSiClMe2): the first complex with simultaneous Si-H and RuCl...SiCl inter-ligand interactions.
Osipov, Alexander L; Vyboishchikov, Sergei F; Dorogov, Konstantin Y; Kuzmina, Lyudmila G; Howard, Judith A K; Lemenovskii, Dmitrii A; Nikonov, Georgii I.
Chem Commun (Camb) ; (26): 3349-51, 2005 Jul 14.
Article in English | MEDLINE | ID: mdl-15983670

ABSTRACT

The addition of HSiMe2Cl to the unsaturated compound Cp*(iPr3P)RuCl gives an unstable adduct which, according to NMR (J(H-Si)= 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane sigma-complex Cp*(iPr3P)Ru(Cl)(eta2-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand RuCl...SiCl hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group.


Subject(s)
Organometallic Compounds/chemical synthesis , Organosilicon Compounds/chemistry , Ruthenium/chemistry , Crystallography, X-Ray , Ligands , Models, Chemical , Models, Molecular , Molecular Conformation , Organometallic Compounds/chemistry , Stereoisomerism
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