Competitive adsorption of acetaminophen and caffeine onto activated Tingui biochar: characterization, modeling, and mechanisms.

Tingui biochar (TB) activated with potassium hydroxide (TB-KOH) was synthesized in the present study. The adsorption capacity of TB-KOH was evaluated for the removal of acetaminophen and caffeine in monocomponent and bicomponent solutions. As a result, the study of the TB-KOH characterization as well as the adsorption kinetics, isotherm, thermodynamics, and a suggestion of the global adsorption mechanism are presented. TB-KOH was characterized through physical-chemical analysis to understand its surface morphology and how it contributes to the adsorption of these drugs. Furthermore, modelling using advanced statistical physical models was performed to describe how acetaminophen and caffeine molecules are adsorbed in the active sites of TB-KOH. Through the characterizations, it was observed that the activation with KOH contributed to the development of porosity and functional groups (-OH, C-O, and C = O) on the surface of TB. The monocomponent adsorption equilibrium was reached in 90 min with a maximum adsorption capacity of 424.7 and 350.8 mg g-1 for acetaminophen and caffeine, respectively. For the bicomponent solution adsorption, the maximum adsorption capacity was 199.4 and 297.5 mg g-1 for acetaminophen and caffeine, respectively. The isotherm data was best fitted to the Sips model, and the thermodynamic study indicated that acetaminophen removal was endothermic, while caffeine removal was exothermic. The mechanism of adsorption of acetaminophen and caffeine by TB-KOH was described by the involvement of hydrogen bonds and π-π interactions between the surface of TB-KOH and the molecules of the contaminants.

Nanogreen is the new future: the conversion of lignin and lignocellulosic wastes into nanomaterials.

The lignocellulose biorefinery industry has assumed an important role within the current scenario. Lignin is an abundant and available biopolymer and one of the compounds present in the lignocellulosic waste. Therefore, processing lignin into new materials and nanomaterials, such as nanolignin, has attracted the attention of the scientific community. Lignin nanoparticles are materials that have excellent properties, such as biodegradability and non-toxicity, and have great potential as chelating agents, antimicrobials agents, UV protectors, nanofillers, adsorbents, catalysts, supercapacitors, emulsion stabilizers, delivered systems, drugs, and gene carriers. This review article covers the emergent scenario of nanolignin and the main aspects of scientific interest, such as the conversion and functionalization of lignin, the valorization of lignocellulose waste, and nanoparticle synthesis. A techno-economic evaluation of the biorefinery model of the nanolignin synthesis is presented based on the simulation of the process on the experimental and commercial databases available and reported by some authors. Finally, the techno-economic assessment is complemented by the life cycle assessment of various nanolignin synthesis pathways reported to evaluate the environmental implications and support this emergent technology development.

Acetaminophen removal by calcium alginate/activated hydrochar composite beads: Batch and fixed-bed studies.

The occurrence of acetaminophen in surface water has been reported worldwide, indicating the need of alternative wastewater treatments. Activated hydrochar (AHC) is efficient for pharmaceuticals removal. Powdered AHC presents challenges that hamper its expansion. However, these issues can be overcome by adding polymers, such as alginate, in composite beads. Therefore, the present study aimed to develop and characterize alginate/brewer's spent grain AHC beads, applying them to acetaminophen adsorption in batch and fixed-bed experiments. The adsorbent presented a high surface area (533.42 m2 g-1) and Fourier-transform infrared spectroscopy (FTIR) showed that alginate assigned new functional groups to the composite. Batch studies revealed an endothermic behavior and maximum adsorption capacity of 165.94 mg g-1, with an equilibrium time of 240 min. The fixed-bed maximum adsorption capacity was 127.01 mg g-1, with a mass transfer zone of 5.89 cm. The importance of alginate for the adsorbent development has been successfully proven.