Testing and application of simple semi-analytical models for soil temperature estimation and prediction in environmental assessments.

The ability of various semi-analytical models to predict soil temperature profiles in an experimental plot during a 16-year monitoring study for soil depths up to 120 cm is evaluated. The models are developed from an analytical model by replacing the steady-state soil temperature with easily obtained hourly and daily average temperature values. Such values include the hourly air temperature, the daily average air temperature, the hourly soil temperature of selected soil depths from three daily observations, the daily average of the soil temperature profile and the hourly soil temperature for the bottom depth. The performance evaluation results show that, in principle, all models exhibit high correlation (R2 values in the range 0.85-0.97), indicating a very good agreement between measured and predicted values. In addition, error statistics reveal that the best performance in terms of Mean Absolute Error (MAE) and Root Mean Square Error (RMSE) is the model based on the daily average of the soil temperature profile with MAE values in the range of 0-0.4°C and RMSE values in the range of 0.1-1.5°C.

Sorption of 3,4-dichloroaniline on four contrasting Greek agricultural soils and the effect of liming.

Sorption of 3,4-dichloroaniline (3,4-DCA) on four typical Greek agricultural soils, with distinct texture, organic matter content and cation exchange capacities, was compared by using sorption isotherms and the parameters calculated from the fitted Freundlich equations. The sorption process of 3,4-DCA to the soil was completed within 48-72 h. The 3,4-DCA sorption on all soils was well described by the Freundlich equation and all sorption isotherms were of the L-type. The sandy clay loam soil with the highest organic matter content and a slightly acidic pH was the most sorptive, whereas the two other soil types, a high organic matter and neutral pH clay and a low organic matter and acidic loam, had an intermediate sorption capacity. A typical calcareous soil with low organic matter had the lowest sorption capacity which was only slightly higher than that of river sand. The 3,4-DCA sorption correlated best to soil organic matter content and not to clay content or cation exchange capacity, indicating the primary role of organic matter. The distribution coefficient (K(d)) decreased with increasing initial 3,4-DCA concentration and the reduction was most pronounced with the highly sorptive sandy clay loam soil, suggesting that the available sorption sites of the soils are not unlimited. Liming of the two acidic soils (the sandy clay loam and the loam) raised their pH (from 6.2 and 5.3, respectively) to 7.8 and reduced their sorption capacity by about 50 %, indicating that soil pH may be the second in importance factor (after organic matter) determining 3,4-DCA sorption.