Environmental, bystander and resident exposure from orchard applications using an agricultural unmanned aerial spraying system.

Unmanned aerial spraying systems (UASS), i.e., unmanned aerial vehicles designed for pesticide applications, are widely used in East Asia and increasingly prevalent in other regions of the world, including North America and Europe. However, according to a recent report of the Organization for Economic Co-operation and Development, spray drift and exposure caused by these systems are not yet fully understood. In particular, there are at present no peer-reviewed reports on direct exposure of residents and bystanders to spray drift following UASS applications. This lack of data results in regulatory concerns with respect to the environment and human safety. The objective of this study was to quantify environmental, resident and bystander exposure following the application of a plant protection product to an orchard using a commercial UASS under field conditions. Using a fluorescent tracer, horizontal and vertical downwind drift data were collected and direct exposure of residents and bystanders located downwind the sprayed area to spray drift was quantified using display mannequins equipped with personal air sampling pumps. Spray drift and exposure inversely correlated with sampling height and downwind distance. Furthermore, drift and exposure were strongly influenced by wind speed and direction, albeit hardly affected by the growth stage of the trees. In addition, substantially less tracer was extracted from the filters of the air sampling pumps than from the coveralls worn by mannequins, suggesting that direct resident/bystander exposure to spray drift may predominantly occur via the dermal route. This report provides essential data on UASS spray drift potential that are relevant for environmental and health risk assessments related to these systems. The results are compared to predicted values of current regulatory models and previously reported field data on drift and exposure caused by different spraying equipment.

Hydrothermal degradation of a 3Y-TZP translucent dental ceramic: A comparison of numerical predictions with experimental data after 2 years of aging.

OBJECTIVES: The purpose of the study was to assess the hydrothermal resistance of a translucent zirconia with two clinical relevant surface textures by means of accelerated tests (LTD) and to compare predicted monoclinic fractions with experimental values measured after two years aging at 37°C. METHODS: Polished (P) and ground (G) specimens were subjected to hydrothermal degradation by exposure to water steam at different temperatures and pressures. The t-m phase transformation was quantified by grazing incidence X-ray diffraction (GIXDR). The elastic modulus and hardness before- and after LTD were determined by nanoindentation. RESULTS: G specimens presented a better resistance to hydrothermal degradation than P samples. Activation energies of 89 and 98kJ/mol and b coefficients of 2.0×10(-5) and 1.8×10(-6) were calculated for P and G samples respectively. The coefficients were subsequently used to predict transformed monoclinic fractions at 37°C. A good correlation was found between the predicted values and the experimental data obtained after aging at 37°C during 2 years. Hydrothermal degradation led to a significant decrease of the elastic moduli and hardness in both groups. SIGNIFICANCE: The dependency of the t-m phase transformation rate on temperature must be determined to accurately predict the hydrothermal behavior of the zirconia ceramics at oral temperatures. The current prevailing assumption, that 5h aging at 134°C corresponds to 15-20 years at 37°C, will underestimate the transformed fraction of the translucent ceramic at 37°C. In this case, the mechanical surface treatment influences the ceramic's transformability. While mild grinding could potentially retard the hydrothermal transformation, polishing after occlusal adjustment is recommended to prevent wear of the antagonist teeth and maintain structural strength.

Model of annual plants dynamics with facilitation and competition.

An individual-based model describing the dynamics of one type of annual plants is presented. We use Monte Carlo simulations where each plant has its own history and the interactions among plants are between nearest neighbours. The character of the interaction (positive or negative) depends on local conditions. The plants compete for two external resources-water and light. The amount of water and/or light a plant receives depends on the external factor but also on local arrangement. Survival, growth and seed production of plants are determined by how well their demands for the resources are met. The survival and seeds production tests have a probabilistic character, which makes the dynamics more realistic than by using a deterministic approach. There is a non-linear coupling between the external supplies. Water evaporates from the soil at a rate depending on constant evaporation rate, local conditions and the amount of light. We examine the dynamics of the plant population along two environmental gradients, allowing also for surplus of water and/or light. We show that the largest number of plants is when the demands for both resources are equal to the supplies. We estimate also the role of evaporation and we find that it depends on the situation. It could be negative, but sometimes it has a positive character. We show that the link between the type of interaction (positive or negative) and external conditions has a complex character. In general in favourable environment plants have a stronger tendency for competitive interactions, leading to mostly isolated plants. When the conditions are getting more difficult, cooperation becomes the dominant type of interactions and the plants grow in clusters. The type of plants-sun-loving or shade tolerating, plays also an important role.

Surface roughness and EDS characterization of a Y-TZP dental ceramic treated with the CoJet™ Sand.

OBJECTIVES: (1) To determine the surface roughness and material loss of a Y-TZP ceramic before and after tribochemical grit blasting and (2) to characterize the changes in elemental surface composition and the phase transformations after tribochemical treatment. METHODS: Machined bar shaped specimens (Zeno, Wieland) were subdivided into three groups. After grit blasting for 10, 20 and 30s respectively, half of the specimens of each group were ultrasonically cleaned in ethanol for 10min. The other half was rinsed with a water spray. Surface roughness was measured using an electro-mechanical profilometer. The elemental composition of the samples was obtained by energy dispersive X-ray spectroscopy (EDS). X-ray diffraction (XRD) was used for phase transformations determination. RESULTS: The median Ra increased significantly from 0.24 to 0.32-0.38µm after grit blasting. Augmentations were also noted for R(max), R(v) and R(p). The highest roughness parameters were, obtained for water sprayed specimens and samples abraded for 30s. Loss of material ranged between 1 and 3µm for 30s grit blasting. Tetragonal and cubic phases were identified in 'as machined' specimens. Grit blasting resulted in domain switching and lattice deformations. The elemental composition comprised Si and Al. The duration of grit blasting did not significantly, influence the atomic percentages of Si or Al. Significantly lower values for both Si and Al were noted, after ultrasonic cleaning. SIGNIFICANCE: Grit blasting with CoJet™ Sand resulted in an increase of surface roughness, a removal of maximum 3µm of material and coated the surface with submicron silica and alumina particles.

Entropy-based characterizations of the observable dependence of the fluctuation-dissipation temperature.

The definition of a nonequilibrium temperature through generalized fluctuation-dissipation relations relies on the independence of the fluctuation-dissipation temperature from the observable considered. We argue that this observable independence is deeply related to the uniformity of the phase-space probability distribution on the hypersurfaces of constant energy. This property is shown explicitly on three different stochastic models, where observable dependence of the fluctuation-dissipation temperature arises only when the uniformity of the phase-space distribution is broken. The first model is an energy transport model on a ring, with biased local transfer rules. In the second model, defined on a fully connected geometry, energy is exchanged with two heat baths at different temperatures, breaking the uniformity of the phase-space distribution. Finally, in the last model, the system is connected to a zero temperature reservoir, and preserves the uniformity of the phase-space distribution in the relaxation regime, leading to an observable-independent temperature.

Dependence of the fluctuation-dissipation temperature on the choice of observable.

On general grounds, a nonequilibrium temperature can be consistently defined from generalized fluctuation-dissipation relations only if it is independent of the observable considered. We argue that the dependence on the choice of observable generically occurs when the phase-space probability distribution is nonuniform on constant energy shells. We relate quantitatively this observable dependence to a fundamental characteristics of nonequilibrium systems, namely, the Shannon entropy difference with respect to the equilibrium state with the same energy. This relation is illustrated on a mean-field model in contact with two heat baths at different temperatures.

Extinction risk and structure of a food web model.

We investigate in detail the model of a trophic web proposed by Amaral and Meyer [Phys. Rev. Lett. 82, 652 (1999)]. We focus on small-size systems that are relevant for real biological food webs and for which the fluctuations play an important role. We show, using Monte Carlo simulations, that such webs can be nonviable, leading to extinction of all species in small and/or weakly coupled systems. Estimations of the extinction times and survival chances are also given. We show that before the extinction the fraction of highly connected species ("omnivores") is increasing. Viable food webs exhibit a pyramidal structure, where the density of occupied niches is higher at lower trophic levels, and moreover the occupations of adjacent levels are closely correlated. We also demonstrate that the distribution of the lengths of food chains has an exponential character and changes weakly with the parameters of the model. On the contrary, the distribution of avalanche sizes of the extinct species depends strongly on the connectedness of the web. For rather loosely connected systems, we recover the power-law type of behavior with the same exponent as found in earlier studies, while for densely connected webs the distribution is not of a power-law type.

Complex population dynamics as a competition between multiple-time-scale phenomena.

The role of the selection pressure and mutation amplitude on the behavior of a single-species population evolving on a two-dimensional lattice, in a periodically changing environment, is studied both analytically and numerically. The mean-field level of description allows one to highlight the delicate interplay between the different time-scale processes in the resulting complex dynamics of the system. We clarify the influence of the amplitude and period of the environmental changes on the critical value of the selection pressure corresponding to a phase-transition "extinct-alive" of the population. However, the intrinsic stochasticity and the dynamically-built in correlations among the individuals, as well as the role of the mutation-induced variety in population's evolution are not appropriately accounted for. A more refined level of description, which is an individual-based one, has to be considered. The inherent fluctuations do not destroy the phase transition "extinct-alive," and the mutation amplitude is strongly influencing the value of the critical selection pressure. The phase diagram in the plane of the population's parameters-selection and mutation are discussed as a function of the environmental variation characteristics. The differences between a smooth variation of the environment and an abrupt, catastrophic change are also addressed.

Intensive thermodynamic parameters in nonequilibrium systems.

Considering a broad class of steady-state nonequilibrium systems for which some additive quantities are conserved by the dynamics, we introduce from a statistical approach intensive thermodynamic parameters (ITPs) conjugated to the conserved quantities. This definition does not require any detailed balance relation to be fulfilled. Rather, the system must satisfy a general additivity property, which holds in most of the models usually considered in the literature, including those described by a matrix product ansatz with finite matrices. The main property of these ITPs is to take equal values in two subsystems, making them a powerful tool to describe nonequilibrium phase coexistence, as illustrated on different models. We finally discuss the issue of the equalization of ITPs when two different systems are put into contact. This issue is closely related to the possibility of measuring the ITPs using a small auxiliary system, in the same way as temperature is measured with a thermometer, and points at one of the major difficulties of nonequilibrium statistical mechanics. In addition, an efficient alternative determination, based on the measure of fluctuations, is also proposed and illustrated.

Boltzmann and hydrodynamic description for self-propelled particles.

We study analytically the emergence of spontaneous collective motion within large bidimensional groups of self-propelled particles with noisy local interactions, a schematic model for assemblies of biological organisms. As a central result, we derive from the individual dynamics the hydrodynamic equations for the density and velocity fields, thus giving a microscopic foundation to the phenomenological equations used in previous approaches. A homogeneous spontaneous motion emerges below a transition line in the noise-density plane. Yet, this state is shown to be unstable against spatial perturbations, suggesting that more complicated structures should eventually appear.

Self-organized packs selection in predator-prey ecosystems.

We present a lattice model of a system of predators of five kinds, competing for prey. The predators are grouped in packs and characterized by two parameters-the energy spent on hunting and energy gained by the kill. The success of hunting depends on the actual competition among predators found near a prey. We determine via Monte Carlo simulations the numbers of predators of each kind as a function of time and the distribution of the size of their packs. We show that the ratio of the energy spent by the competing predators determines their fate. The energy gain plays only a secondary role. We show also that the system self-organizes itself into groups of predators living in well defined packs, which size depends on the energy spent. The most preferred size dependence on the energy spent follows a very simple power law. We present also a mean-field-type approach to the problem and we discuss the differences in the results obtained by the two methods, showing in particular, that the simulation approach produces more reliable results.

Definition and relevance of nonequilibrium intensive thermodynamic parameters.

We show that intensive thermodynamic parameters associated to additive conserved quantities can be naturally defined from a statistical approach in far-from-equilibrium steady-state systems, under few assumptions, and without any detailed balance requirement. It may apply, e.g., to dissipative systems such as granular gases where volume or mass is still conserved or to systems with periodic boundary conditions where fluxes of conserved quantities are present. We emphasize the usefulness of this concept to characterize the coexistence of different nonequilibrium phases and discuss the influence of the contact between two different systems, in relation with measurement issues.

Maxwell and very-hard-particle models for probabilistic ballistic annihilation: hydrodynamic description.

The hydrodynamic description of probabilistic ballistic annihilation, for which no conservation laws hold, is an intricate problem with hard spherelike dynamics for which no exact solution exists. We consequently focus on simplified approaches, the Maxwell and very-hard-particle (VHP) models, which allows us to compute analytically upper and lower bounds for several quantities. The purpose is to test the possibility of describing such a far from equilibrium dynamics with simplified kinetic models. The motivation is also in turn to assess the relevance of some singular features appearing within the original model and the approximations invoked to study it. The scaling exponents are first obtained from the (simplified) Boltzmann equation, and are confronted against direct Monte Carlo simulations. Then, the Chapman-Enskog method is used to obtain constitutive relations and transport coefficients. The corresponding Navier-Stokes equations for the hydrodynamic fields are derived for both Maxwell and VHP models. We finally perform a linear stability analysis around the homogeneous solution, which illustrates the importance of dissipation in the possible development of spatial inhomogeneities.

Nonequilibrium temperatures in steady-state systems with conserved energy.

We study a class of nonequilibrium lattice models describing local redistributions of a globally conserved quantity, which is interpreted as an energy. A particular subclass can be solved exactly, allowing us to define a statistical temperature T(th) along the same lines as in the equilibrium micro-canonical ensemble. We compute the response function and find that when the fluctuation-dissipation relation is linear, the slope T(FD)(-1) of this relation differs from the inverse temperature T(th)(-1). We argue that T(th) is physically more relevant than T(FD), since in the steady-state regime, it takes equal values in two subsystems of a large isolated system. Finally, a numerical renormalization group procedure suggests that all models within the class behave similarly at a coarse-grained level, leading to a parameter that describes the deviation from equilibrium. Quantitative predictions concerning this parameter are obtained within a mean-field framework.

Gold coating of non-conductive membranes before matrix-assisted laser desorption/ionization tandem mass spectrometric analysis prevents charging effect.

Acquisition of tandem mass spectra from peptides or other analytes deposited on non-conductive membranes is inhibited on instruments combining matrix-assisted laser desorption/ionization with tandem time-of-flight analyzers (MALDI-TOF/TOF) due to a charging effect. A thin layer of gold renders the membrane conductive. This allows adequate data acquisition on MALDI-TOF/TOF systems. Therefore, this methodology extends the capacity of the molecular scanner concept to tandem mass spectrometry.

Temperature in nonequilibrium systems with conserved energy.

We study a class of nonequilibrium lattice models which describe local redistributions of a globally conserved energy. A particular subclass can be solved analytically, allowing us to define a temperature T(th) along the same lines as in the equilibrium microcanonical ensemble. The fluctuation-dissipation relation is explicitly found to be linear, but its slope differs from the inverse temperature T(-1)(th). A numerical renormalization group procedure suggests that, at a coarse-grained level, all models behave similarly, leading to a two-parameter description of their macroscopic properties.

Role of evolution by natural selection in population dynamics.

Using a Monte Carlo approach we study the role of inheritance and natural selection in the dynamics of populations. We show that a population subject to inheritance has a much better chance of survival in a given condition than a population where new generations do not inherit genomes of their parents. The dependence of the survival chance on such factors as selection pressure, fecundity, or carrying capacity of the system is much stronger when selection and inheritance are present. We demonstrate, in accordance with biological observations, that in certain conditions evolution can save a population which would perish without it.

Probabilistic ballistic annihilation with continuous velocity distributions.

We investigate the problem of ballistically controlled reactions where particles either annihilate upon collision with probability p, or undergo an elastic shock with probability 1-p. Restricting to homogeneous systems, we provide in the scaling regime that emerges in the long time limit, analytical expressions for the exponents describing the time decay of the density and the root-mean-square velocity, as continuous functions of the probability p and of a parameter related to the dissipation of energy. We work at the level of molecular chaos (nonlinear Boltzmann equation), and using a systematic Sonine polynomials expansion of the velocity distribution, we obtain in arbitrary dimension the first non-Gaussian correction and the corresponding expressions for the decay exponents. We implement Monte Carlo simulations in two dimensions, which are in excellent agreement with our analytical predictions. For p<1, numerical simulations lead to the conjecture that unlike for pure annihilation (p=1), the velocity distribution becomes universal, i.e., does not depend on the initial conditions.

Hydrodynamics of probabilistic ballistic annihilation.

We consider a dilute gas of hard spheres in dimension d> or =2 that upon collision either annihilate with probability p or undergo an elastic scattering with probability 1-p . For such a system neither mass, momentum, nor kinetic energy is a conserved quantity. We establish the hydrodynamic equations from the Boltzmann equation description. Within the Chapman-Enskog scheme, we determine the transport coefficients up to Navier-Stokes order, and give the closed set of equations for the hydrodynamic fields chosen for the above coarse-grained description (density, momentum, and kinetic temperature). Linear stability analysis is performed, and the conditions of stability for the local fields are discussed.