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Phys Chem Chem Phys ; 16(16): 7513-20, 2014 Apr 28.
Article in English | MEDLINE | ID: mdl-24626812

ABSTRACT

The auto-oxidation of trans-1,2-disiloxybenzocyclobutene was found to be very efficient, giving endo-peroxide in quantitative yield. Each step of the mechanism of spin-forbidden addition of triplet oxygen O2((3)Σg) was studied by both EPR/spin trapping and theoretical studies.

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