1.
Chem Commun (Camb)
; 48(62): 7738-40, 2012 Aug 11.
Article
in English
| MEDLINE
| ID: mdl-22779079
ABSTRACT
CF(3)- or -CF(2)-containing tetrahydroquinolines have been asymmetrically synthesized from the reaction of fluorinated N-arylimines with benzyl N-vinylcarbamate in the presence of a chiral phosphoric acid.
Subject(s)
Hydrocarbons, Fluorinated/chemical synthesis , Phosphoric Acids/chemistry , Quinolines/chemistry , Urethane/analogs & derivatives , Catalysis , Magnetic Resonance Spectroscopy , Molecular Structure , Stereoisomerism , Urethane/chemistry
2.
J Org Chem
; 77(7): 3604-8, 2012 Apr 06.
Article
in English
| MEDLINE
| ID: mdl-22394335
ABSTRACT
Experimental studies showed that Ni(II) N-confused porphyrins, treated with fluoroalkylarylsulfonium salts, can undergo an electrophilic fluoroalkylation at the inner 21-C position, leading to 21-fluoroalkylated Ni(II) N-confused porphyrins.
