1.
Dalton Trans
; (2): 195-7, 2008 Jan 14.
Article
in English
| MEDLINE
| ID: mdl-18097484
ABSTRACT
The first polyoxometal complex possessing affirmatory mixed molybdenum-tungsten capped Keggin-type structure has been hydrothermally synthesized.
Subject(s)
Arsenic/chemistry , Molybdenum/chemistry , Organometallic Compounds/chemical synthesis , Tungsten/chemistry , Crystallography, X-Ray , Indicators and Reagents , Magnetic Resonance Spectroscopy , Models, Molecular , Molecular Conformation , Organometallic Compounds/chemistry , Oxidation-Reduction
2.
Dalton Trans
; (21): 2115-20, 2007 Jun 07.
Article
in English
| MEDLINE
| ID: mdl-17514331
ABSTRACT
Three organic-inorganic hybrid compounds [Mn(bpy)V(bpy)V(3)O(11)] (bpy = 2,2'-bipyridine) (1), [Cu(bpy)V(2)O(6)] (2) and [Zn(phen)3][V(2)O(6)].10H(2)O (phen = 1,10-phenanthroline) (3) have been synthesized hydrothermally. Single crystal X-ray diffraction analyses revealed that compound 1 is the first example of bpy units coordinating to different transition metals in one molecule. Compound 2 is a new isomer of [Cu(bpy)V(2)O(6)] which was named the gamma-isomer by us. In compound 3, a 2-D water sheet with big holes filled by the "naked" [V(4)O(12)](4-) clusters is found.